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1.发明授权Partially alkylated triamines and higher polyamines as curing agents in polyurethane manufacture by reaction injection molding 失效部分烷基化三胺和较高的多胺作为聚氨酯制造中的固化剂通过反应注射成型
公开(公告)号：US4736009A
公开(公告)日：1988-04-05
申请号：US946731
申请日：1986-12-29
CPC分类号： C08G18/6529 , C08G18/3243 , C08G2120/00
摘要： Partially alkylated polyamines which may be viewed as low molecular weight polymers of x-amino-y-methylenephenyl are effective curing agents in combination with other polyamines and polyols in reaction injection molding for diverse class of polyisocyanates. Alkylation may range from 5 up to 100 percent to afford polyamines with a board spectrum of cure times, as well as to give elastomers with an interesting and useful diversity of properties. Such polyamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： 可以被视为x-氨基-y-亚甲基苯基的低分子量聚合物的部分烷基化多胺是在多种类的多异氰酸酯的反应注射成型中与其它多胺和多元醇组合的有效固化剂。 烷基化可以为5至100％，以提供具有固化时间的板光谱的多胺，以及赋予弹性体具有有趣和有用的多样性。 这种多胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要看作聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是 被视为具有氨基甲酸酯和尿素段的弹性体。
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2.发明授权N-N'-dialkylphenylenediamines as curing agents in polyurethane and polyurea manufacture by reaction injection molding 失效N-N'-二烷基苯二胺作为聚氨酯和聚脲的固化剂通过反应注射成型制备
公开(公告)号：US4806616A
公开(公告)日：1989-02-21
申请号：US130838
申请日：1987-12-09
CPC分类号： C08G18/6529 , C08G18/325 , C08G2120/00
摘要： N,N'-dialkyl- and diaylphenylenediamines are effective curing agents in combination with other polyamines and polyols in reaction injection molding for a diverse class of polyisocyanates. The diamines provide a broad spectrum of cure times, as well as giving elastomers an interesting and useful diversity of properties. Such polyamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： N，N'-二烷基和二亚苯基二胺是在多种多异氰酸酯的反应注射成型中与其它多胺和多元醇组合的有效固化剂。 二胺提供广泛的固化时间，以及赋予弹性体一种有趣和有用的多样性。 这种多胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要看作聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是 被视为具有氨基甲酸酯和尿素段的弹性体。
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3.发明授权Alkylated triamines and higher polyamines as curing agents in polyurethane manufacture 失效烷基化三胺和较高的多胺作为聚氨酯制造中的固化剂
公开(公告)号：US4709003A
公开(公告)日：1987-11-24
申请号：US836872
申请日：1986-03-06
CPC分类号： C08G18/10
摘要： Largely alkylated polyamines which may be viewed as low molecular weight polymers of x-amino-y-methylenephenyl are effective curing agents for a diverse class of urethane prepolymers. The resulting polyurethanes are thermosetting polymers with excellent compression set and tensile strength. Because the properties of the resulting polyurethane vary only slightly near the optimum stoichiometry of curing agent-prepolymer, the use of the curing agents of this invention presents the advantage of being very tolerant of operator mixing error.
摘要翻译： 可被视为x-氨基-y-亚甲基苯基的低分子量聚合物的大量烷基化多胺是用于各种类型的氨基甲酸酯预聚物的有效固化剂。 所得聚氨酯是具有优异的压缩永久变形和拉伸强度的热固性聚合物。 由于所得聚氨酯的性质在固化剂 - 预聚物的最佳化学计量附近仅略微变化，所以使用本发明的固化剂具有非常容忍操作者混合误差的优点。
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4.发明授权N,N'-dialkylphenylenediamines as curing agents in polyurethane and polyurea manufacture by reaction injection molding 失效N，N'-二烷基苯二胺作为聚氨酯和聚脲的固化剂通过反应注射成型制备
公开(公告)号：US4948861A
公开(公告)日：1990-08-14
申请号：US265098
申请日：1988-10-31
CPC分类号： C08G18/6529 , C08G18/325 , C08G2120/00
摘要： N,N'-dialkyl- and diarylphenylenediamines are effective curing agents in combination with other polyamines and polyols in reaction injection molding for a diverse class of polyisocyanates. The diamines provide a broad spectrum of cure times, as well as giving elastomers an interesting and useful diversity of properties. Such polyamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： N，N'-二烷基 - 和二芳基苯二胺是在多种多异氰酸酯的反应注射成型中与其它多胺和多元醇组合的有效固化剂。 二胺提供广泛的固化时间，以及赋予弹性体一种有趣和有用的多样性。 这种多胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要看作聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是 被视为具有氨基甲酸酯和尿素段的弹性体。
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5.发明授权Alkylated triamines and higher polyamines as curing agents in polyurethane manufacture by reaction injection molding 失效烷基化三胺和高级多胺作为聚氨酯制造中的固化剂通过反应注射成型
公开(公告)号：US4847347A
公开(公告)日：1989-07-11
申请号：US149292
申请日：1988-01-28
CPC分类号： C08G18/3243 , C08G18/6529 , C08G2120/00
摘要： Alkylated polyamines which may be viewed as low molecular weight polymers of x-amino-y-methylenephenyl are effective curing agents in combination with other polyamines and polyols in reaction injection molding for a diverse class of polyisocyantates. Alkylation may range from 5 up to 100 percent to afford polyamines with a broad spectrum of cure times, as well as to give elastomers with an interesting and useful diversity of properties. Such polyamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： 可被视为x-氨基-y-亚甲基苯基的低分子量聚合物的烷基化多胺是用于多种类型的多异氰酸酯的反应注射成型中的有效固化剂与其它多胺和多元醇的组合。 烷基化可以在5至100％的范围内提供具有广谱固化时间的多胺，以及赋予具有有趣和有用的多样性的弹性体。 这种多胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要看作聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是 被视为具有氨基甲酸酯和尿素段的弹性体。
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6.发明授权Chlorofluorocarbon-free flexible polyurethane foams and method of making with blowing efficiency enhancers 失效不含氟碳氟化合物的柔性聚氨酯泡沫和吹塑效率增强剂的制备方法
公开(公告)号：US5166185A
公开(公告)日：1992-11-24
申请号：US533981
申请日：1990-06-06
CPC分类号： C08G18/6685 , C08G18/3243 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： N,N'-di-sec-alkenyl-or-di-sec-alkyl-substituted methylene diphenyl diamines are effective curing agents for making polyurethane foams from MDI-based polyisocyanates. The diamines are especially advantageous since foams of lower density having lower hardness can be obtained without utilizing chlorofluorocarbous (CFC's) and without sacrificing tensile strength, tear strength, SAG or compression set values.
摘要翻译： N，N'-二仲链烯基或二仲烷基取代的亚甲基二苯基二胺是用于制备基于MDI的多异氰酸酯的聚氨酯泡沫的有效固化剂。 二胺是特别有利的，因为可以在不使用氯氟碳（CFC））的情况下获得具有较低硬度的较低密度的泡沫，并且不牺牲拉伸强度，撕裂强度，SAG或压缩永久变形值。
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公开(公告)号：US06642344B1
公开(公告)日：2003-11-04
申请号：US10054268
申请日：2002-01-22
申请人： David W. House , Ray V. Scott, Jr.
发明人： David W. House , Ray V. Scott, Jr.
IPC分类号： C08G5968
CPC分类号： C08G59/5026 , C08G59/56
摘要： A method for making flexible epoxy resins by curing an epoxide and a bis-phenol with an aliphatic secondary diamine having the structural formula (I) or (II): where R1 and R2 are each individually an alkyl, alkenyl, aryl, or arylalkyl group having from about 1 to about 20 carbon atoms, and R3 and R4 are each individually an alkyl or alkenyl group having from about 1 to about 20 carbon atoms, or hydrogen.
摘要翻译： 通过用具有结构式（I）或（II）的脂肪族二胺固化环氧化物和双酚制备柔性环氧树脂的方法：其中R 1和R 2各自独立地为烷基，烯基，芳基或芳基烷基 具有约1至约20个碳原子，并且R 3和R 4各自独立地为具有约1至约20个碳原子的烷基或烯基或氢。
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8.发明授权Bis(N-alkylaminocyclohexyl)methanes as curing agents for polyurethanes and polyureas 失效双（N-烷基氨基环己基）甲烷作为聚氨酯和聚脲的固化剂
公开(公告)号：US5312886A
公开(公告)日：1994-05-17
申请号：US122946
申请日：1993-09-20
CPC分类号： C08G18/3234 , C08G18/6529 , C08G2120/00
摘要： Bis(N-alkylaminocyclohexyl)methanes are excellent chain extenders in the formation of polyurethane and polyurea polymers, both elastomers and coatings, from both monomeric polyisocyanates and isocyanate-terminated prepolymers. Our chain extenders may be used alone or in combination with other polyamines and with polyols. A broad spectrum of polymeric material can be formed with a range of diverse properties.
摘要翻译： 双（N-烷基氨基环己基）甲烷是从单体多异氰酸酯和异氰酸酯封端的预聚物形成聚氨酯和聚脲聚合物弹性体和涂层的优异的增链剂。 我们的增链剂可以单独使用或与其他多胺和多元醇组合使用。 可以形成具有多种不同性质的广泛的聚合物材料。
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公开(公告)号：US4783517A
公开(公告)日：1988-11-08
申请号：US39242
申请日：1987-04-17
申请人： Ray V. Scott, Jr. , David W. House
发明人： Ray V. Scott, Jr. , David W. House
CPC分类号： C08G18/7831 , C08G18/325
摘要： The polyureas resulting from curing polyfunctional isocyanates having at least three isocyanate groups with a N,N'-dialkylmethylenedianiline are broadly useful as coatings on the surface of objects made of metal, wood, glass, or plastic. The diamine N,N'-di(2-butyl)4,4'-methylenedianiline is a particularly useful diamine. Biurets are an especially desirable class of polyisocyanates for the polyureas of this invention, particularly those arising from polymethylene diisocyanates and aromatic diisocyanates.
摘要翻译： 由具有至少三个异氰酸酯基的多官能异氰酸酯与N，N'-二烷基亚甲基二苯胺固化产生的聚脲可广泛用作金属，木材，玻璃或塑料制成的物体表面上的涂层。 二胺N，N'-二（2-丁基）4,4'-亚甲基二苯胺是特别有用的二胺。 对于本发明的聚脲，特别是由聚亚甲基二异氰酸酯和芳族二异氰酸酯衍生的那些聚异氰酸酯是一种特别理想的聚异氰酸酯类。
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公开(公告)号：US4663201A
公开(公告)日：1987-05-05
申请号：US855991
申请日：1986-04-25
申请人： David W. House , Ray V. Scott, Jr.
发明人： David W. House , Ray V. Scott, Jr.
CPC分类号： C08G18/7831 , C08G18/325
摘要： The polyurea resulting from curing polyfunctional isocyanates having at least three groups with a N,N'-dialkylmethylenedianiline are broadly useful as coatings on the surface of objects made of metal, wood, glass, or plastic. Such coatings may be made based on either a 1-pack system or 2-pack system. The diamine N,N'-di(2-butyl)4,4'-methylenedianiline is a particularly useful diamine. Biurets are an especially desirable class of polyisocyanates for the polyureas of this invention.
摘要翻译： 具有至少三个具有N，N'-二烷基亚甲基二苯胺的基团的多官能异氰酸酯所产生的聚脲广泛用作金属，木材，玻璃或塑料制成的物体表面上的涂层。 这样的涂层可以基于1包装系统或2包装系统制成。 二胺N，N'-二（2-丁基）4,4'-亚甲基二苯胺是特别有用的二胺。 对于本发明的聚脲，缩二脲是特别令人满意的多异氰酸酯类。
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