公开(公告)号：US07045481B1

公开(公告)日：2006-05-16

申请号：US11103824

申请日：2005-04-12

申请人： Sukesh Parasher ,  Michael Rueter ,  Bing Zhou

发明人： Sukesh Parasher ,  Michael Rueter ,  Bing Zhou

IPC分类号： B01J31/00

CPC分类号： B01J35/0013 ,  B01J23/38 ,  B01J27/053 ,  B01J27/08 ,  B01J29/06 ,  B01J31/1625 ,  B01J37/0219 ,  C01B15/026

摘要： Supported catalysts include a solid support such as silica that is functionalized to have inorganic acid functional groups attached thereto. Active catalyst particles are supported on the functionalized support material. The acid functionalized support material is made by reacting a solid support with an inorganic acid containing agent such as sulfuric acid or para-toluene sulfonic acid. An organic anchoring agent is used to form and anchor catalyst nanoparticles to the acid functionalized support material. The supported catalyst can be sized and shaped for use in any type of reactor, including a fixed bed or fluidized bed reactor. The methods of the present invention also include a process for the direct synthesis of hydrogen peroxide using the supported catalyst.

摘要翻译： 负载型催化剂包括固体载体如二氧化硅，其被官能化以具有连接到其上的无机酸官能团。 活性催化剂颗粒负载在官能化的载体材料上。 酸官能化的载体材料通过使固体载体与无机酸的试剂如硫酸或对甲苯磺酸反应制得。 使用有机锚固剂将催化剂纳米颗粒形成和锚定到酸官能化载体材料上。 负载催化剂的尺寸和形状可用于任何类型的反应器，包括固定床或流化床反应器。 本发明的方法还包括使用负载型催化剂直接合成过氧化氢的方法。

公开(公告)号：US20050025697A1

公开(公告)日：2005-02-03

申请号：US10897493

申请日：2004-07-23

申请人： Michael Rueter ,  Bing Zhou ,  Sukesh Parasher

发明人： Michael Rueter ,  Bing Zhou ,  Sukesh Parasher

IPC分类号： C01B15/029

CPC分类号： C01B15/029

摘要： A process is disclosed for the direct catalytic production of aqueous solutions of hydrogen peroxide from hydrogen and oxygen in the presence of a small amount of one or more water soluble organic additives (about 0.1-10% by weight). Suitable catalysts include nanometer-sized noble metal catalytic crystal particles. The catalyst particles preferably have a controlled surface coordination number of 2 to increase the selectivity of hydrogen peroxide production. The water soluble additive(s) increases catalytic activity causing significant increases in the apparent first order reaction rate constant for the direct production of aqueous hydrogen peroxide.

摘要翻译： 公开了一种在少量一种或多种水溶性有机添加剂（约0.1-10重量％）存在下从氢气和氧气直接催化生产过氧化氢水溶液的方法。 合适的催化剂包括纳米级的贵金属催化晶体颗粒。 催化剂颗粒优选具有受控的表面配位数2，以增加过氧化氢生产的选择性。 水溶性添加剂增加催化活性，导致直接生产过氧化氢水溶液的表观一级反应速率常数显着增加。

公开(公告)号：US20120020872A1

公开(公告)日：2012-01-26

申请号：US12840723

申请日：2010-07-21

申请人： Sukesh Parasher ,  Michael A. Rueter ,  Bing Zhou

发明人： Sukesh Parasher ,  Michael A. Rueter ,  Bing Zhou

IPC分类号： B01J23/44 ,  C01B15/01

CPC分类号： B01J35/0013 ,  B01J21/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J35/002 ,  B01J35/006 ,  B01J35/08 ,  B01J37/0203 ,  B01J37/16 ,  B01J37/18 ,  C01B15/029

摘要： Method for making a direct synthesis hydrogen peroxide catalyst includes (i) mixing together a solvent, a plurality of noble metal catalyst atoms, and a plurality of organic dispersing agent molecules, the organic dispersing agent molecules each including at least one functional group capable of bonding with the noble metal catalyst atoms; (ii) reacting the organic dispersing agent with the catalyst atoms to form complexed catalyst atoms and forming a plurality of catalytic nanoparticles from the complexed catalyst atoms; (iii) supporting the catalytic nanoparticles on a support material; and (iv) reducing the catalyst atoms at a temperature of at least 351° C. to yield a supported and activated direct synthesis hydrogen peroxide catalyst.

摘要翻译： 制备直接合成过氧化氢催化剂的方法包括（i）将溶剂，多种贵金属催化剂原子和多种有机分散剂分子混合在一起，所述有机分散剂分子各自包含至少一个能够键合的官能团 与贵金属催化剂原子; （ii）使有机分散剂与催化剂原子反应以形成络合的催化剂原子并从络合的催化剂原子形成多个催化纳米颗粒; （iii）将催化纳米颗粒负载在载体材料上; 和（iv）在至少351℃的温度下还原催化剂原子，得到负载和活化的直接合成过氧化氢催化剂。

公开(公告)号：US07632775B2

公开(公告)日：2009-12-15

申请号：US10990616

申请日：2004-11-17

申请人： Bing Zhou ,  Sukesh Parasher ,  Michael Rueter

发明人： Bing Zhou ,  Sukesh Parasher ,  Michael Rueter

IPC分类号： B01J25/00 ,  B01J23/40 ,  B01J23/42 ,  C22C38/00 ,  C22C5/04 ,  B01J31/00

CPC分类号： B01J35/0013 ,  B01J21/18 ,  B01J23/8906 ,  B01J37/0211 ,  B01J37/0219 ,  Y10S977/81

摘要： Disclosed are nanoparticles formed from a plurality of two or more different components. The two or more components are dispersed using a dispersing agent such that the nanoparticles have a substantially uniform distribution of the two or more components. The dispersing agents can be poly functional small organic molecules, polymers, or oligomers, or salts of these. The molecules of the dispersing agent bind to the particle atoms to overcome like-component attractions, thereby allowing different and/or dissimilar components to form heterogeneous nanoparticles. In one embodiment, dissimilar components such as iron and platinum are complexed using the dispersing agent to form substantially uniform heterogeneous nanoparticles. Methods are also disclosed for making the multicomponent nanoparticles. The methods include forming suspensions of two or more components complexed with the dispersing agent molecules. The suspensions can also be deposited on a support material and/or anchored to the support.

摘要翻译： 公开了由多个两个或多个不同组分形成的纳米颗粒。 使用分散剂分散两种或更多种组分，使得纳米颗粒具有基本均匀的两种或多种组分的分布。 分散剂可以是多官能的小有机分子，聚合物或低聚物或它们的盐。 分散剂的分子与颗粒原子结合以克服相同分子的吸引力，从而允许不同的和/或不同的组分形成不均匀的纳米颗粒。 在一个实施方案中，使用分散剂使异种组分如铁和铂复合以形成基本均匀的非均相纳米颗粒。 还公开了制备多组分纳米颗粒的方法。 所述方法包括形成与分散剂分子络合的两种或多种组分的悬浮液。 悬浮液也可以沉积在支撑材料上和/或锚固到载体上。

公开(公告)号：US20070219084A1

公开(公告)日：2007-09-20

申请号：US11378877

申请日：2006-03-17

申请人： Sukesh Parasher ,  Cheng Zhang ,  Michael Rueter ,  Bing Zhou

发明人： Sukesh Parasher ,  Cheng Zhang ,  Michael Rueter ,  Bing Zhou

IPC分类号： B01J31/00 ,  B01F3/12 ,  B01F17/00

CPC分类号： B01J35/0013 ,  B01J13/0043 ,  B01J23/40 ,  B01J37/18 ,  B82Y30/00

摘要： Metal-containing colloids are manufactured by reacting a plurality of metal ions and a plurality of organic agent molecules to form metal complexes in a mixture having a pH greater than about 4.25. The metal complexes are reduced for at least 0.5 hour to form stable colloidal nanoparticles. The extended reduction time improves the stability of the colloidal particles as compared to shorter reduction times. The stability of the colloidal particles allows for colloids with higher concentrations of metal to be formed. The concentration of metal in the colloid is preferably at least about 150 ppm by weight.

摘要翻译： 含金属胶体通过使多种金属离子和多种有机试剂分子反应，在pH大于约4.25的混合物中形成金属络合物来制造。 将金属络合物还原至少0.5小时以形成稳定的胶体纳米颗粒。 与较短的还原时间相比，延长的还原时间提高了胶体颗粒的稳定性。 胶体颗粒的稳定性允许形成具有较高浓度金属的胶体。 胶体中金属的浓度优选为至少约150ppm重量。

公开(公告)号：US07144565B2

公开(公告)日：2006-12-05

申请号：US10897493

申请日：2004-07-23

申请人： Michael Rueter ,  Bing Zhou ,  Sukesh Parasher

发明人： Michael Rueter ,  Bing Zhou ,  Sukesh Parasher

IPC分类号： C01B15/029

CPC分类号： C01B15/029

摘要： A process is disclosed for the direct catalytic production of aqueous solutions of hydrogen peroxide from hydrogen and oxygen in the presence of a small amount of one or more water soluble organic additives (about 0.1–10% by weight). Suitable catalysts include nanometer-sized noble metal catalytic crystal particles. The catalyst particles preferably have a controlled surface coordination number of 2 to increase the selectivity of hydrogen peroxide production. The water soluble additive(s) increases catalytic activity causing significant increases in the apparent first order reaction rate constant for the direct production of aqueous hydrogen peroxide.

摘要翻译： 公开了一种在少量一种或多种水溶性有机添加剂（约0.1-10重量％）存在下从氢气和氧气直接催化生产过氧化氢水溶液的方法。 合适的催化剂包括纳米级的贵金属催化晶体颗粒。 催化剂颗粒优选具有受控的表面配位数2，以增加过氧化氢生产的选择性。 水溶性添加剂增加催化活性，导致直接生产过氧化氢水溶液的表观一级反应速率常数显着增加。

公开(公告)号：US07011807B2

公开(公告)日：2006-03-14

申请号：US10618808

申请日：2003-07-14

申请人： Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

发明人： Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

IPC分类号： C01B15/029 ,  C07D301/12 ,  C07D301/03 ,  C07D301/04 ,  C10G45/44

CPC分类号： H01M4/926 ,  H01M4/921

摘要： Supported reactive catalysts having a controlled coordination structure and methods for their production are disclosed. The supported catalysts of the present invention are useful for the preparation of hydrogen peroxide with high selectivity in addition to other chemical conversion reactions. The supported catalyst comprises catalyst particles having top or outer layer of atoms in which at least a portion of the atoms exhibit a controlled coordination number of 2. The catalyst and methods may be used for the concurrent in situ and ex situ conversion of organic compounds. In addition, a process is provided for catalytically producing hydrogen peroxide from hydrogen and oxygen feeds by contacting them with the catalysts of the invention and a suitable organic liquid solvent having a Solvent Selection Parameter (SSP) between 0.14×10−4 and 5.0×10−4.

摘要翻译： 公开了具有受控配位结构的负载型反应催化剂及其制备方法。 除了其它化学转化反应之外，本发明的负载型催化剂可用于制备具有高选择性的过氧化氢。 载体催化剂包含具有顶部或外层原子的催化剂颗粒，其中至少一部分原子表现出受控的配位数2.催化剂和方法可用于有机化合物的原位和非原位转化。 此外，提供了一种通过使它们与本发明的催化剂接触的氢气和氧气进料催化产生过氧化氢的方法以及溶剂选择参数（SSP）在0.14×10 -4之间的合适的有机液体溶剂， SUP>和5.0×10 -4。

公开(公告)号：US20050014635A1

公开(公告)日：2005-01-20

申请号：US10618808

申请日：2003-07-14

申请人： Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

发明人： Bing Zhou ,  Michael Rueter ,  Sukesh Parasher

IPC分类号： B01J31/00 ,  H01M4/92

CPC分类号： H01M4/926 ,  H01M4/921

摘要： Supported reactive catalysts having a controlled coordination structure and methods for their production are disclosed. The supported catalysts of the present invention are useful for the preparation of hydrogen peroxide with high selectivity in addition to other chemical conversion reactions. The supported catalyst comprises catalyst particles having top or outer layer of atoms in which at least a portion of the atoms exhibit a controlled coordination number of 2. The catalyst and methods may be used for the concurrent in situ and ex situ conversion of organic compounds. In addition, a process is provided for catalytically producing hydrogen peroxide from hydrogen and oxygen feeds by contacting them with the catalysts of the invention and a suitable organic liquid solvent having a Solvent Selection Parameter (SSP) between 0.14×10−4 and 5.0×10−4.

摘要翻译： 公开了具有受控配位结构的负载型反应催化剂及其制备方法。 除了其它化学转化反应之外，本发明的负载型催化剂可用于制备具有高选择性的过氧化氢。 载体催化剂包含具有顶部或外层原子的催化剂颗粒，其中至少一部分原子表现出受控的配位数2.催化剂和方法可用于有机化合物的原位和非原位转化。 另外，提供了一种从氢气和氧气进料中催化产生过氧化氢的方法，它们与本发明的催化剂和具有溶剂选择参数（SSP）的合适的有机液体溶剂在0.14×10 -4和5.0×10 <-4>。