公开(公告)号：US11358131B2

公开(公告)日：2022-06-14

申请号：US17404082

申请日：2021-08-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius ,  Eric D. Schwerdtfeger ,  Mitchell D. Refvik ,  Mark L. Hlavinka

IPC: B01J31/02 ,  B01J31/34 ,  B01J37/02 ,  B01J35/10 ,  B01J21/08 ,  B01J21/12 ,  B01J21/06 ,  B01J31/04

Abstract: A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

公开(公告)号：US20210387172A1

公开(公告)日：2021-12-16

申请号：US17404083

申请日：2021-08-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius ,  Eric D. Schwerdtfeger ,  Mitchell D. Refvik ,  Mark L. Hlavinka

IPC: B01J31/02 ,  B01J31/34 ,  B01J37/02 ,  B01J35/10 ,  B01J21/08 ,  B01J21/12 ,  B01J21/06 ,  B01J31/04

Abstract: A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

公开(公告)号：US10722874B2

公开(公告)日：2020-07-28

申请号：US16774891

申请日：2020-01-28

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius ,  Eric D. Schwerdtfeger ,  Mitchell D. Refvik ,  Mark L. Hlavinka

IPC: B01J21/08 ,  B01J27/24 ,  B01J31/38 ,  B01J31/02 ,  B01J31/34 ,  B01J37/02 ,  B01J35/10

Abstract: A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

公开(公告)号：US10543480B2

公开(公告)日：2020-01-28

申请号：US15953930

申请日：2018-04-16

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius ,  Eric D. Schwerdtfeger ,  Mitchell D. Refvik ,  Mark L. Hlavinka

IPC: B01J21/08 ,  B01J21/12 ,  B01J23/26 ,  B01J27/24 ,  B01J31/02 ,  B01J31/34 ,  B01J35/10 ,  B01J37/02

Abstract: A pre-catalyst composition comprising a) a silica support comprising silica wherein an amount of silica ranges from about 70 wt. % to about 95 wt. % based upon a total weight of the silica support, b) a chromium-containing compound wherein an amount of chromium ranges from about 0.1 wt. % to about 5 wt. % based upon the amount of silica, c) a titanium-containing compound wherein an amount of titanium ranges from about 0.1 wt. % to about 20 wt. % based upon the amount of silica, d) a carboxylic acid wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid ranges from about 1:1 to about 1:10, and e) a nitrogen-containing compound with a molecular formula containing at least one nitrogen atom wherein an equivalent molar ratio of titanium-containing compound to nitrogen-containing compound ranges from about 1:0.5 to about 1:10.

公开(公告)号：US20150344752A1

公开(公告)日：2015-12-03

申请号：US14821835

申请日：2015-08-10

Applicant: Chevron Phillips Chemical Company LP

Inventor： Michael S. Matson ,  Colin Cameron ,  Alastair Robert Marrion ,  Anthony Colin Wright ,  Mitchell D. Refvik ,  Eric J. Netemeyer

IPC: C09J175/04 ,  C09J163/00

CPC classification number: C09J175/04 ,  C07C319/04 ,  C07C321/06 ,  C07C321/10 ,  C07C321/22 ,  C07C2601/14 ,  C07C2601/18 ,  C07C2601/20 ,  C09J11/06 ,  C09J163/00 ,  C09J201/00

Abstract: The present invention discloses processes for forming polythiol compositions from olefinic hydrocarbons such as cyclooctadiene, cyclododecatriene, and trivinylcyclohexane. The polythiol compositions produced from these processes, including the sulfur-containing compounds of these compositions, also are described.

Abstract translation: 本发明公开了由烯烃如环辛二烯，环十二碳三烯和三乙烯基环己烷形成多硫醇组合物的方法。 还描述了由这些方法制备的多硫醇组合物，包括这些组合物的含硫化合物。

公开(公告)号：US09133370B2

公开(公告)日：2015-09-15

申请号：US13891224

申请日：2013-05-10

Applicant: Chevron Phillips Chemical Company LP

Inventor： Michael S. Matson ,  Colin Cameron ,  Alastair Robert Marrion ,  Anthony Colin Wright ,  Mitchell D. Refvik ,  Eric J. Netemeyer

IPC: C08G75/10 ,  C08G75/14 ,  C08G75/16 ,  C09J11/06 ,  C07C319/04 ,  C07C321/06 ,  C07C321/10 ,  C07C321/22 ,  C08G75/00

CPC classification number: C09J175/04 ,  C07C319/04 ,  C07C321/06 ,  C07C321/10 ,  C07C321/22 ,  C07C2601/14 ,  C07C2601/18 ,  C07C2601/20 ,  C09J11/06 ,  C09J163/00 ,  C09J201/00

Abstract: The present invention discloses processes for forming polythiol compositions from olefinic hydrocarbons such as cyclooctadiene, cyclododecatriene, and trivinylcyclohexane. The polythiol compositions produced from these processes, including the sulfur-containing compounds of these compositions, also are described.

Abstract translation: 本发明公开了由烯烃如环辛二烯，环十二碳三烯和三乙烯基环己烷形成多硫醇组合物的方法。 还描述了由这些方法制备的多硫醇组合物，包括这些组合物的含硫化合物。

公开(公告)号：US12036542B2

公开(公告)日：2024-07-16

申请号：US18358088

申请日：2023-07-25

Applicant: Chevron Phillips Chemical Company LP ,  The Shepherd Chemical Company

Inventor： Carlos A. Cruz ,  Mitchell D. Refvik ,  Max P. McDaniel ,  Mark Scott

IPC: B01J37/00 ,  B01J35/40 ,  B01J35/61

CPC classification number: B01J37/0045 ,  B01J35/40 ,  B01J35/61

Abstract: Methods for modifying a catalyst system component are disclosed in which a feed mixture containing a fluid and from 1 to 15 wt. % of a catalyst system component is introduced into an inlet of a hydrocyclone, an overflow stream containing from 0.1 to 5 wt. % solids and an underflow stream containing from 10 to 40 wt. % solids are discharged from the hydrocyclone, and the underflow stream is spray dried to form a modified catalyst component. Often, from 4 to 20 wt. % of the catalyst system component in the feed mixture has a particle size of less than or equal to 20 μm, or less than or equal to 10 μm.

公开(公告)号：US11801502B2

公开(公告)日：2023-10-31

申请号：US17942228

申请日：2022-09-12

Applicant: Chevron Phillips Chemical Company LP ,  The Shepherd Chemical Company

Inventor： Mark Scott ,  Evan Merk ,  Carlos A. Cruz ,  Mitchell D. Refvik ,  Max P. McDaniel

IPC: B01J37/00 ,  B01J35/02 ,  B01J35/10

CPC classification number: B01J37/0045 ,  B01J35/023 ,  B01J35/1004

Abstract: Methods for modifying a catalyst system component are disclosed in which a feed mixture containing a fluid and from 1 to 15 wt. % of a catalyst system component is introduced into an inlet of a hydrocyclone, an overflow stream containing from 0.1 to 5 wt. % solids and an underflow stream containing from 10 to 40 wt. % solids are discharged from the hydrocyclone, and the underflow stream is spray dried to form a modified catalyst component. Often, from 4 to 20 wt. % of the catalyst system component in the feed mixture has a particle size of less than or equal to 20 μm, or less than or equal to 10 μm.

公开(公告)号：US20230173474A1

公开(公告)日：2023-06-08

申请号：US18102236

申请日：2023-01-27

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius ,  Eric D. Schwerdtfeger ,  Mitchell D. Refvik ,  Mark L. Hlavinka

IPC: B01J31/02 ,  B01J31/34 ,  B01J37/02 ,  B01J35/10 ,  B01J21/08 ,  B01J21/12 ,  B01J21/06 ,  B01J31/04

CPC classification number: B01J31/0209 ,  B01J31/34 ,  B01J37/024 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1047 ,  B01J21/08 ,  B01J21/12 ,  B01J21/063 ,  B01J31/04

Abstract: A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

公开(公告)号：US11583841B2

公开(公告)日：2023-02-21

申请号：US17747212

申请日：2022-05-18

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius ,  Eric D. Schwerdtfeger ,  Mitchell D. Refvik ,  Mark L. Hlavinka

IPC: B01J23/86 ,  B01J31/02 ,  B01J31/34 ,  B01J37/02 ,  B01J35/10 ,  B01J21/08 ,  B01J21/12 ,  B01J21/06 ,  B01J31/04

Abstract: A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.