摘要:
Hydrothermal conversion method for manufacturing a hydrocarbon conversion catalyst useful in hydrogenative processes, said catalyst comprising a hydrogenating component and a novel synthetic layered crystalline clay-type aluminosilicate mineral, preferably in an intimate admixture with an amorphous cogel comprising silica and alumina, said method comprising subjecting to conditions of elevated temperature and pressure in a reaction zone a hydrogel or hydrogel slurry, said slurry comprising water, a component selected from fluorine and compounds of fluorine, and an amorphous cogel starting material comprising silica and alumina, until a substantial amount of said synthetic mineral is formed, preferably in an intimate admixture with a substantial amount of unreacted amorphous cogel comprising silica and alumina, incorporating in the reaction zone product a component comprising a hydrogenating metal, and drying and calcining the resulting composite to produce said catalyst.
摘要:
MEDTHOD OF ACTIVATING A CATALYST COMPOSITE COMPRISING A CRYSTALLINE ZEOLITIC MOLECULAR SIEVE, A GEL MATRIX COMPRISING SILICA-ALUMINA, AND A RHENIUM OR RHENIUM COMPOUND HYDROGENATING COMPONENT, SAID MOLECULAR SIEVE BEING IN PARTICULATE FORM AND BEING DISPERSED IN SAID GEL MATRIX, WHICH METHOD COMPRISES HEATING SAID CATALYST COMPOSITE IN AN OXYGEN-CONTAINING AS STREAM AT 1200* TO 1600*F. FOR 0.25 TO 48 HOURS, AND THE CATALYST COMPOSITE SO ACTIVATED.
摘要:
Method of producing a multicomponent hydrocarbon conversion catalyst comprising coprecipitating a mixture of at least three different metal compounds at a pH of 5.5 to 8, at least one of said compounds being a compound of palladium, at least one of said compounds being a metal chloride, reducing the chloride content of the coprecipitate to below about 0.25 percent of the total weight thereof, drying the coprecipitate, and heat treating the dried coprecipitate by contact with an oxygen-containing gas at 850* to 1,600* F. for 0.25 to 48 hours.
摘要:
The disclosure relates to a process for producing jet fuel from a hydrocarbon feedstock boiling at least partly above the jet fuel range, which comprises: A. Contacting the feedstock in a first zone, at elevated temperature and pressure and in the presence of hydrogen, with a catalyst comprising a crystalline zeolitic molecular sieve dispersed in a nonzeolitic hydrocracking catalyst matrix; B. Operating the first zone at conditions to obtain between 10 and 35 percent conversion of the feedstock to material boiling in the jet fuel range and withdrawing a first zone effluent comprising partially converted feedstock; C. Passing at least a portion of the first zone effluent from the first zone to a second zone; D. Contacting said portion of the first zone effluent in the second zone, at elevated temperature and pressure and in the presence of hydrogen, with an amorphous catalyst comprising metals or compounds of metals selected from Group VI or VIII or both of these groups, and a siliceous cracking component; and E. Operating the second zone at conditions to obtain between 10 and 45 percent conversion of said portion of the first zone effluent to material boiling in the jet fuel range. Preferably, the first and second zones are contained in one common reactor vessel.