公开(公告)号：US10786431B2

公开(公告)日：2020-09-29

申请号：US16185828

申请日：2018-11-09

Applicant: CORNING INCORPORATED

Inventor： Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Christopher Lee Timmons ,  Natesan Venkataraman ,  Ronald Luce Verkleeren

IPC: A61J1/14 ,  B65D23/08 ,  C03C17/22 ,  B65D25/14 ,  B65D1/40 ,  C03C17/00 ,  C03C21/00 ,  B65D23/02 ,  C03C17/34 ,  A61J1/06 ,  C03C15/02 ,  B65D1/02 ,  B65D25/34 ,  B32B17/06 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C09D179/08 ,  B65D65/42

Abstract: A delamination resistant glass pharmaceutical container may include a glass body comprising a borosilicate glass having a Type 1 chemical durability according to USP . At least an inner surface of the glass body may have a delamination factor less than or equal to 10. A thermally stable coating may be positioned around at least a portion of the outer surface of the glass body. The thermally stable coating may be an outermost coating on the outer surface of the glass body and the outer surface of the glass body with the thermally stable coating has a coefficient of friction less than or equal to 0.7. The thermally stable coating comprising at least one of a metal nitride coating, a metal oxide coating, a metal sulfide coating, SiO2, diamond-like carbon, graphene, and a carbide coating.

公开(公告)号：US20200268608A1

公开(公告)日：2020-08-27

申请号：US16870657

申请日：2020-05-08

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  B65D65/42 ,  A61J1/00 ,  B65D23/08 ,  C03C17/00 ,  C03C21/00 ,  B65D25/14 ,  C03C17/30 ,  C03C17/32 ,  C09D179/08 ,  C03C17/42 ,  B65D25/34

Abstract: According to embodiments, a method of making a coated pharmaceutical container, may include: forming a glass tube; forming the glass tube into a pharmaceutical container comprising an interior surface and an exterior surface; and applying a coating to the exterior surface. The coating may have a coefficient of friction less than or equal to 0.7 relative to a second pharmaceutical container when tested in a vial-on-vial testing jig under a normal load of 30 N. The coated pharmaceutical container may be thermally stable after depyrogenation at a temperature of at least 260° C. for 30 minutes in air.

公开(公告)号：US20190084875A1

公开(公告)日：2019-03-21

申请号：US16185819

申请日：2018-11-09

Applicant: CORNING INCORPORATED

Inventor： Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Christopher Lee Timmons ,  Natesan Venkataraman ,  Ronald Luce Verkleeren

IPC: C03C17/42 ,  B65D25/14 ,  B65D1/02 ,  B65D25/34 ,  B65D65/42 ,  A61J1/14 ,  B65D23/08 ,  B65D23/02 ,  C03C21/00 ,  C03C17/00 ,  B65D1/40 ,  C03C15/02 ,  C09D179/08 ,  C03C17/32 ,  C03C17/30 ,  B32B17/06 ,  C03C17/34

Abstract: Glass pharmaceutical packages comprising glass containers are disclosed. In embodiments, a coated glass pharmaceutical package includes a glass container formed from one of a borosilicate glass composition that meets Type 1 criteria according to USP or an alkali aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to the ISO 720-1985 testing standard. A lubricous coating may be positioned on at least a portion of the exterior surface of the glass container. The portion of the coated glass pharmaceutical package with the lubricous coating has a coefficient of friction that is at least 20% less than an uncoated glass pharmaceutical package. A horizontal compression strength of the portion of the coated glass pharmaceutical package with the lubricous coating may be at least 10% greater than an uncoated glass pharmaceutical package.

公开(公告)号：US20190076331A1

公开(公告)日：2019-03-14

申请号：US16185493

申请日：2018-11-09

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  B65D65/42 ,  B65D23/08 ,  C09D179/08 ,  B65D25/14 ,  C03C21/00 ,  C03C17/42 ,  C03C17/00 ,  B65D25/34 ,  C03C17/32 ,  C03C17/30 ,  A61J1/00

Abstract: Coated glass pharmaceutical packages are disclosed. According to embodiments, a coated glass pharmaceutical package may include a glass container formed from one of a borosilicate glass composition that meets Type 1 criteria according to USP or an alkali aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to the ISO 720-1985 testing standard. A low-friction coating may be bonded to the exterior surface of the glass container. The low-friction coating may include a polymer. The exterior surface of the glass container with the low-friction coating may have a coefficient of friction of less than or equal to 0.7. The coated glass pharmaceutical package may be thermally stable after depyrogenation in air at a temperature of at least about 260° C. for 30 minutes.

公开(公告)号：US09763852B2

公开(公告)日：2017-09-19

申请号：US13780740

申请日：2013-02-28

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/00 ,  B65D25/14 ,  C03C17/30 ,  A61J1/14 ,  B65D23/08 ,  B65D65/42 ,  C03C17/32 ,  C03C17/42 ,  C03C17/00 ,  C03C21/00 ,  C09D179/08

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Low-friction coatings and glass articles with low-friction coatings are disclosed. According to one embodiment, a coated glass article may include a glass body comprising a first surface and a low-friction coating positioned on at least a portion of the first surface of the glass body. The low-friction coating may include a polymer chemical composition. The coated glass article may be thermally stable at a temperature of at least about 260° C. for 30 minutes. A light transmission through the coated glass article may be greater than or equal to about 55% of a light transmission through an uncoated glass article for wavelengths from about 400 nm to about 700 nm. The low-friction coating may have a mass loss of less than about 5% of its mass when heated from a temperature of 150° C. to 350° C. at a ramp rate of about 10° C./minute.

公开(公告)号：US09744099B2

公开(公告)日：2017-08-29

申请号：US15331113

申请日：2016-10-21

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/00 ,  B65D65/42 ,  B65D23/08 ,  B65D25/14 ,  C03C17/30 ,  C03C17/32 ,  C09D179/08 ,  C03C17/00 ,  C03C17/42 ,  C03C21/00 ,  A61J1/14

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: A coated glass pharmaceutical package may include a body formed from borosilicate glass that meets the Type 1 criteria according to USP . The body may have an interior surface and an exterior surface. A low-friction coating having a thickness of less than 100 microns may be positioned on at least a portion of the exterior surface. The portion of the exterior surface with the low-friction coating may have a coefficient of friction that is at least 20% less than an uncoated glass pharmaceutical package formed from the same glass composition and the coefficient of friction may not increase by more than 30% after undergoing a depyrogenation cycle at a temperature of from 250° C. to 400° C. for a time period of from 30 seconds to 72 hours.

公开(公告)号：US20170174554A1

公开(公告)日：2017-06-22

申请号：US15449761

申请日：2017-03-03

Applicant: CORNING INCORPORATED

Inventor： Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Robert Michael Morena ,  Santona Pal ,  Robert Anthony Schaut

IPC: C03C3/091 ,  C03C21/00 ,  C03C4/20 ,  C03C3/087 ,  C03C4/18

CPC classification number: C03C4/20 ,  A61J1/00 ,  C03C3/087 ,  C03C3/091 ,  C03C4/18 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/26 ,  Y10T428/315

Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % A12O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.

公开(公告)号：US09617183B2

公开(公告)日：2017-04-11

申请号：US14272189

申请日：2014-05-07

Applicant: Corning Incorporated

Inventor： Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Robert Michael Morena ,  Santona Pal ,  Robert Anthony Schaut

IPC: C03C3/085 ,  C03C3/087 ,  C03C3/091 ,  C03C21/00 ,  C03C4/20 ,  C03C4/18 ,  A61J1/00

CPC classification number: C03C3/091 ,  A61J1/00 ,  C03C3/087 ,  C03C4/18 ,  C03C4/20 ,  C03C21/002 ,  C03C2204/00 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/26 ,  Y10T428/315

Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. According to one embodiment, the glass composition may include greater than or equal to about 68 mol. % SiO2 and less than or equal to about 80 mol. % SiO2; greater than or equal to about 3 mol. % and less than or equal to about 13 mol. % alkaline earth oxide; X mol. % Al2O3, wherein X is greater than or equal to about 4 and less than or equal to about 8; Y mol. % alkali oxide, wherein the alkali oxide comprises Na2O in an amount greater than about 8 mol %; and B2O3, wherein a ratio (B2O3 (mol. %)/(Y mol. %−X mol. %) is greater than 0 and less than 0.3. In some embodiments, the glass composition may be free of phosphorous and compounds of phosphorous.

公开(公告)号：US20170087058A1

公开(公告)日：2017-03-30

申请号：US15374338

申请日：2016-12-09

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  C03C17/42 ,  B65D65/42 ,  C03C17/32 ,  C03C21/00 ,  B65D25/34 ,  C03C17/00 ,  C03C17/30

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Glass pharmaceutical packages with coatings are disclosed herein. According to one embodiment, the glass pharmaceutical package includes a glass body enclosing an inner volume and having an exterior surface. A coating may be positioned on at least a portion of the exterior surface of the glass body. The coating may include a coupling agent layer having a first thickness of greater than or equal to 25 nm and less than or equal to 100 nm. A polymer layer having a second thickness of less than 50 nm may be positioned over the coupling agent layer.

公开(公告)号：US09359250B2

公开(公告)日：2016-06-07

申请号：US14288909

申请日：2014-05-28

Applicant: CORNING INCORPORATED

Inventor： Yuhui Jin ,  Ekaterina Aleksandrovna Kuksenkova ,  Santona Pal ,  Mehmet Derya Tetiker

IPC: C03C21/00

CPC classification number: C03C21/001 ,  C03C21/005

Abstract: A substrate ion exchange system, along with methods of maintain such a system, is provided that includes a substrate having an outer region containing a plurality of substrate metal ions, an ion exchange bath that includes a plurality of first metal ions at a first metal ion concentration and a plurality of second metal ions at a second metal ion concentration, and a vessel for containing the ion exchange bath and the substrate. The ion exchange system also includes a temperature sensor coupled to the vessel, and a processor configured to receive a vessel temperature from the sensor and to evaluate the first metal ion concentration based at least in part on a first metal ion consumption rate relationship and the vessel temperature. Further, the first metal ion consumption rate relationship is predetermined.

Abstract translation: 提供了一种衬底离子交换系统以及保持这种系统的方法，其包括具有包含多个衬底金属离子的外部区域的衬底，在第一金属离子处包括多个第一金属离子的离子交换浴 浓度和多个第二金属离子浓度的第二金属离子，以及用于容纳离子交换浴和基底的容器。 离子交换系统还包括耦合到容器的温度传感器，以及处理器，其被配置为从传感器接收容器温度并且至少部分地基于第一金属离子消耗速率关系和容器来评估第一金属离子浓度 温度。 此外，第一金属离子消耗速率关系是预定的。