公开(公告)号：US09458351B2

公开(公告)日：2016-10-04

申请号：US14115077

申请日：2012-05-03

申请人： Wiebke Becker ,  Katharina Dreger ,  Carmen Flosbach

发明人： Wiebke Becker ,  Katharina Dreger ,  Carmen Flosbach

IPC分类号： C09D163/00 ,  C08G18/62 ,  C08G18/79 ,  C09D175/04 ,  C08G18/22 ,  C08G18/24

CPC分类号： C09D163/00 ,  C08G18/22 ,  C08G18/246 ,  C08G18/6229 ,  C08G18/6254 ,  C08G18/6258 ,  C08G18/792 ,  C09D175/04

摘要： Two-component coating compositions include: A) a cross-linkable binder compound having at least one functional group reactive towards isocyanate groups, B) a cross-linking agent having at least one free isocyanate group and C) a catalyst component comprising C1) a catalyst for the for the curing reaction between the functional groups of component A) and the isocyanate groups of component B), the catalyst C1) being an organo-metal compound, and C2) an oligomeric or polymeric binder compound having a glass transition temperature Tg of ≧about 20° C., measured by DSC (differential scanning calorimetry) at a heating rate of 10 K/min. The glass transition temperature Tg of the binder compound C2) is above the temperature at which the two-component coating composition is applied, preferably about 10° C. above the temperature at which the two-component coating composition is applied.

摘要翻译： 双组分涂料组合物包括：A）具有至少一个对异氰酸酯基团具有反应性的官能团的可交联粘合剂化合物，B）具有至少一个游离异氰酸酯基团的交联剂，和C）包含C1） 用于组分A）的官能团与组分B）的异氰酸酯基团之间的固化反应的催化剂，催化剂C1）是有机金属化合物，和C2）具有玻璃化转变温度Tg的低聚或聚合的粘合剂化合物 通过DSC（差示扫描量热法）以10K / min的加热速率测量。 粘合剂化合物C2）的玻璃化转变温度Tg高于施加双组分涂料组合物的温度，优选在高于施加双组分涂料组合物的温度下约10℃。

公开(公告)号：US08940370B2

公开(公告)日：2015-01-27

申请号：US13202584

申请日：2010-03-01

申请人： Carmen Flosbach ,  Katharina Dreger ,  Fabian Koehn ,  Bernd Schneider

发明人： Carmen Flosbach ,  Katharina Dreger ,  Fabian Koehn ,  Bernd Schneider

IPC分类号： B05D3/00 ,  B05D1/00

CPC分类号： C09D175/04 ,  C08G18/2825 ,  C08G18/792

摘要： A coating process wherein a precoated automotive substrate is OEM top coated with an aqueous two-component polyurethane top coating composition prepared by static mixing a non-aqueous hydrophobic polyisocyanate crosslinker component and an aqueous binder component having a binder solids content comprising at least one water-dilutable hydroxyl-functional binder and 5 to 30 wt.-% of a urethane compound A with at least two terminal urethane groups (—NHC(O)OR; R=hydrocarbyl residue of a monoalcohol) and having a number-average molar mass (Mn) of from 400 to 5,000.

摘要翻译： 一种涂覆方法，其中预涂布的汽车基材是OEM顶部涂覆有水性双组分聚氨酯顶涂料组合物，其通过静态混合非水疏水多异氰酸酯交联剂组分和含有粘合剂固体含量的水性粘合剂组分制备，所述粘合剂固体含量包含至少一种水 - 具有至少两个末端氨基甲酸酯基（-NHC（O）OR; R =一元醇的烃基残基））和具有数均摩尔质量的氨基甲酸酯化合物A和5-30重量％ Mn）为400至5,000。

公开(公告)号：US08685497B2

公开(公告)日：2014-04-01

申请号：US13638973

申请日：2011-05-05

申请人： Carmen Flosbach ,  Gerhard Friederichs

发明人： Carmen Flosbach ,  Gerhard Friederichs

IPC分类号： B05D3/02

CPC分类号： C09D175/14 ,  C08G18/3206 ,  C08G18/6225 ,  C08G18/722 ,  C08L75/04

摘要： A liquid coating composition which contains (i) a resin system crosslinkable under catalysis of a catalyst D and comprising a binder A and, as an optional component, a crosslinker B for the binder A, and (ii) solid particles CD consisting of a physical mixture of 70 to 99 wt.-% of a polyurethane resin C and 1 to 30 wt.-% of a catalyst D immobilized in said polyurethane resin C, wherein the sum of the wt.-% totals 100 wt.-%, and wherein the polyurethane resin C has a melting temperature of 40 to 180° C., measured by DSC at a heating rate of 10 K/min.

摘要翻译： 一种液体涂料组合物，其包含（i）在催化剂D催化下可交联的树脂体系，其包含粘合剂A和作为任选组分的用于粘合剂A的交联剂B，和（ii）由物理 70至99重量％的聚氨酯树脂C和1至30重量％固定在所述聚氨酯树脂C中的催化剂D的混合物，其中重量％总计为100重量％，和 其中聚氨酯树脂C的熔融温度为40〜180℃，通过DSC以10K /分钟的加热速度测定。

公开(公告)号：US20120276296A1

公开(公告)日：2012-11-01

申请号：US13516254

申请日：2010-12-20

申请人： Andreas Fieberg ,  Carmen Flosbach ,  Paul P. Bruylants ,  Jozef Theresia Huybrechts

发明人： Andreas Fieberg ,  Carmen Flosbach ,  Paul P. Bruylants ,  Jozef Theresia Huybrechts

IPC分类号： C09D175/04 ,  B05D3/00 ,  B05D1/38

CPC分类号： C09D175/04 ,  B05D5/06 ,  B05D7/14 ,  B05D7/53 ,  B05D7/532 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/44 ,  C08G18/755 ,  C08K3/013 ,  C08K5/0041 ,  Y10T428/31551 ,  C08G18/32

摘要： The present invention relates to water-based coating composition comprising A) at least one water-dilutable polyurethane binder, B) optionally at least one curing agent, and C) at least one pigment, characterised in that the at least one water-dilutable polyurethane binder is based on at least one polyhydroxyl compound, said polyhydroxyl compound comprises at least 50% by weight of at least one polycarbonate polyol, which is liquid at 20° C., the % by weight are based on the total amount of the polyhydroxyl compound. The invention also relates to the use of the water-based coating composition as base coat composition in a multilayer coating comprising a layer of a base coat composition and a layer of clear coat composition thereon. The water-based coating composition can be used as colour- and/or special effect imparting base coat composition in a multilayer coating comprising a layer of a base coat composition and a layer of a clear coat composition thereon.

摘要翻译： 本发明涉及水性涂料组合物，其包含A）至少一种水可稀释的聚氨酯粘合剂，B）任选的至少一种固化剂，和C）至少一种颜料，其特征在于所述至少一种水可稀释的聚氨酯 粘合剂基于至少一种多羟基化合物，所述多羟基化合物包含至少50重量％的至少一种在20℃下为液体的聚碳酸酯多元醇，其重量百分比是基于多羟基化合物的总量 。 本发明还涉及水性涂料组合物作为底涂层组合物在多层涂层中的用途，其中包括底涂层组合物层和其上的透明涂层组合物层。 水性涂​​料组合物可以在多层涂层中用作赋色和/或特殊效果的底漆和/或特殊效果，所述多层涂层包含底涂层组合物层和其上的透明涂层组合物层。

公开(公告)号：US20110136972A1

公开(公告)日：2011-06-09

申请号：US13058916

申请日：2009-09-03

申请人： Carmen Flosbach ,  Engin Temeltas ,  Kristina Iland

发明人： Carmen Flosbach ,  Engin Temeltas ,  Kristina Iland

IPC分类号： C09D175/00 ,  B05D3/00

CPC分类号： C08G18/798 ,  C08G18/097 ,  C08G18/3206 ,  C08G18/3848 ,  C08G18/73 ,  C08G2150/20

摘要： The present invention provides a powder coating composition comprising at least one hydroxyl functional polyuretdione resin binder, wherein the at least one hydroxyl functional polyuretdione resin binder having a melting temperature of 60 to 180° C., in particular, 80 to 160° C. The powder coating composition according to the invention comprising the specific kind of the polyuretdione resin binder makes it possible to provide desired technological properties, in particular, thin films and high flexibility in combination with an excellent weather resistance of the coating layers.

摘要翻译： 本发明提供一种包含至少一种羟基官能化聚脲二酮树脂粘合剂的粉末涂料组合物，其中所述至少一种羟基官能聚脲二酮树脂粘合剂的熔点为60-180℃，特别是80-160℃。 包含特定种类的聚脲二酮树脂粘合剂的根据本发明的粉末涂料组合物使得可以提供所需的技术性能，特别是薄膜和高柔性以及涂层的优异的耐候性。

公开(公告)号：US20100279016A1

公开(公告)日：2010-11-04

申请号：US12738339

申请日：2008-10-01

申请人： Carmen Flosbach ,  Andrew Hearley ,  Wiebke Becker ,  Juergen Stropp

发明人： Carmen Flosbach ,  Andrew Hearley ,  Wiebke Becker ,  Juergen Stropp

IPC分类号： B05D3/02

CPC分类号： C08G18/282 ,  C09D175/04

摘要： The invention relates to a process for painting substrates comprising the following steps: 1. applying a coating composition to an optionally pre-coated substrate and 2. hardening the applied coating composition, wherein the coating composition comprises: A) at least one binder having functional groups containing active hydrogen, B) at least one polyisocyanate cross-linking agent having free isocyanate groups and C) at least one urethane compound having at least two —O—CO—NH— groups, wherein the urethane compound is substantially free from functional groups which are capable of entering into a cross-linking reaction with components A) and/or B) and wherein the hardening is carried out under conditions such that the component C) does not contribute to the cross-linking of the applied coating composition by chemical reaction.

摘要翻译： 本发明涉及一种用于涂布基材的方法，包括以下步骤：1.将涂料组合物施用到任选预涂的基材上，和2.硬化涂覆的涂料组合物，其中涂料组合物包含：A）至少一种具有官能 含有活性氢的基团，B）至少一种具有游离异氰酸酯基团的多异氰酸酯交联剂，和C）至少一种具有至少两个-O-CO-NH-基团的氨基甲酸酯化合物，其中氨基甲酸酯化合物基本上不含官能团 其能够与组分A）和/或B）进行交联反应，并且其中所述硬化在使得组分C）不有助于通过化学品施用的涂料组合物的交联的条件下进行 反应。

公开(公告)号：US20100056724A1

公开(公告)日：2010-03-04

申请号：US12548716

申请日：2009-08-27

申请人： Carmen Flosbach ,  Katharina Dreger ,  Brenda Carriere

发明人： Carmen Flosbach ,  Katharina Dreger ,  Brenda Carriere

IPC分类号： C08L33/02

CPC分类号： C08F265/04 ,  C09D151/003

摘要： A process for producing aqueous binder lattices comprising: 1) polymerizing at least one olefinically monounsaturated, free-radically polymerizable monomer with at least one olefinically monounsaturated, free-radically polymerizable monomer with at least one acid group in organic solvent or in aqueous emulsion to form an acid functional (meth)acrylic resin, and neutralizing the acid groups of the formed polymer, and 2) polymerizing in aqueous emulsion at least one olefinically unsaturated, polymerizable monomer in the presence of the formed polymer obtained in process step 1).

摘要翻译： 一种用于生产水性粘合剂晶格的方法，包括：1）使至少一种烯属单不饱和的可自由基聚合的单体与至少一种在有机溶剂中或在水乳液中具有至少一个酸基的烯属单不饱和的可自由基聚合的单体聚合以形成 酸性官能（甲基）丙烯酸树脂，并中和形成的聚合物的酸基，和2）在工艺步骤1）中获得的形成的聚合物存在下，在水性乳液中聚合至少一种烯属不饱和的可聚合单体。

公开(公告)号：US20090090629A1

公开(公告)日：2009-04-09

申请号：US12281807

申请日：2007-03-06

申请人： Gabriele Buettner ,  Andreas Fieberg ,  Carmen Flosbach ,  Thomas Grawe ,  Tanja Renkes

发明人： Gabriele Buettner ,  Andreas Fieberg ,  Carmen Flosbach ,  Thomas Grawe ,  Tanja Renkes

IPC分类号： C25D13/06 ,  C08L63/00

CPC分类号： C09D5/448 ,  C08G18/227 ,  C08G18/3206 ,  C08G18/6415 ,  C08G18/73 ,  C08G18/758 ,  C08G18/8054 ,  C08G18/8077 ,  C09D175/12

摘要： CED coating compositions which, apart from water, comprise (i) a resin solids content consisting of at least one film-forming, self- or externally cross-linking CED binder and the optional components: cross-linkers, paste resins, nonionic resins, and (ii) optionally, at least one component selected from the group consisting of pigments, fillers, coating additives and organic solvents, and contain relative to the resin solids content thereof, 1 to 20 wt. % of at least one resin A with functional groups selected from the group consisting of hydroxyl groups, free isocyanate groups and blocked isocyanate groups, wherein the at least one resin A is present as particles with melting temperatures from 40 to 200° C.

摘要翻译： 除了水以外，CED涂料组合物包含（i）由至少一种成膜的，自身或外部交联的CED粘合剂和任选的组分组成的树脂固体含量：交联剂，糊状树脂，非离子树脂， 和（ii）任选的至少一种选自颜料，填料，涂料添加剂和有机溶剂的组分，并且相对于其树脂固体含量含有1至20wt。 至少一种具有选自羟基，游离异氰酸酯基和封端异氰酸酯基团的官能团的至少一种树脂A的％，其中至少一种树脂A以熔点为40至200℃的颗粒存在。

公开(公告)号：US20050205200A1

公开(公告)日：2005-09-22

申请号：US10805719

申请日：2004-03-22

申请人： Carmen Flosbach ,  Peter Frese ,  Phu Nguyen ,  Martin Wulf

发明人： Carmen Flosbach ,  Peter Frese ,  Phu Nguyen ,  Martin Wulf

IPC分类号： B05D1/28 ,  B41M3/12 ,  B41M5/00 ,  B41M5/025 ,  B41M5/52 ,  B41M7/00 ,  B44C1/16 ,  B44C1/17 ,  B44C1/165 ,  B44C1/00

CPC分类号： B41M5/52 ,  B41M5/0256 ,  B41M5/5209 ,  B41M5/5227 ,  B44C1/16

摘要： A process for the production of backing foils provided on one side with an uncured or at most partially cured transparent coating and, on the side of the coating remote from the foil, with an image, the process comprising the successive steps: a) providing a backing foil provided on one side with an uncured or at most partially cured transparent coating of a curable coating composition and b) providing the side of the coating remote from the foil with an image, in particular by printing.

摘要翻译： 一种用于生产背衬箔片的方法，所述背衬箔片在一侧具有未固化或至多部分固化的透明涂层，并且在远离箔片的涂层侧上具有图像，该方法包括以下连续步骤：a）提供 在一侧提供具有可固化涂料组合物的未固化或至多部分固化的透明涂层的背衬箔，以及b）使涂层的远离箔的一侧具有图像，特别是通过印刷。

公开(公告)号：US20050187341A1

公开(公告)日：2005-08-25

申请号：US10782098

申请日：2004-02-19

申请人： Carmen Flosbach ,  Wiebke Becker ,  Stefanie Matten

发明人： Carmen Flosbach ,  Wiebke Becker ,  Stefanie Matten

IPC分类号： C08G18/10 ,  C08G18/32 ,  C08G18/67 ,  C08G18/73 ,  C08G18/81 ,  C09D175/16 ,  C08K3/00 ,  C08L75/00

CPC分类号： C09D175/16 ,  C08G18/10 ,  C08G18/3203 ,  C08G18/672 ,  C08G18/73 ,  C08G18/8175 ,  C08G2150/20

摘要： A process for the production of polyurethane di(meth)acrylates in which 1,6-hexane diisocyanate is reacted, without solvent and without subsequent purification operations, with a diol component and hydroxy-C2-C4-alkyl (meth)acrylate in the molar ratio x:(x−1):2, wherein x means any desired value from 2 to 5 and the diol component is a combination of two to four (cyclo)aliphatic diols with molar masses of 62 to 600 and wherein each of the diols constitutes at least 10 mol % of the diols of the diol component and powder coating compositions having the polyurethane di(meth)acrylates as a binder.

摘要翻译： 制备其中1,6-己二异氰酸酯在无溶剂且无后续纯化操作下与二醇组分和（甲基）丙烯酸羟基-C 2 -C 4烷基酯反应的聚氨酯二（甲基）丙烯酸酯的方法， 比例x：（x-1）：2，其中x表示2至5的任何所需值，二醇组分是摩尔质量为62至600的2至4（环）脂族二醇的组合，并且其中每个二醇 构成二醇组分的二醇的至少10摩尔％和具有聚氨酯二（甲基）丙烯酸酯作为粘合剂的粉末涂料组合物。