Photoreactive polymer and method for preparing the same
    22.
    发明授权
    Photoreactive polymer and method for preparing the same 有权
    光反应性聚合物及其制备方法

    公开(公告)号:US08329841B2

    公开(公告)日:2012-12-11

    申请号:US13327022

    申请日:2011-12-15

    摘要: The present invention relates to a photoreactive polymer that comprises a multi-cyclic compound in a main chain, and a polymerization method thereof. Since the photoreactive polymer according to the present invention comprises a multi-cyclic compound having a high glass transition temperature as a main chain, the thermal stability is excellent, and since the mobility of the main chain is relatively high as compared to that of an additional polymer, a photoreactive group can be freely moved in the main chain of the polymer. Accordingly, it is possible to overcome a slow photoreactive rate that is considered a disadvantage of a polymer material used to prepare an alignment film for known liquid crystal display devices.

    摘要翻译: 本发明涉及在主链中包含多环化合物的光反应性聚合物及其聚合方法。 由于根据本发明的光反应性聚合物包含具有高玻璃化转变温度作为主链的多环化合物,因此热稳定性优异,并且由于主链的迁移率与附加的相比高, 聚合物,光反应性基团可以在聚合物的主链中自由移动。 因此,可以克服被认为是用于制备用于已知液晶显示装置的取向膜的聚合物材料的缺点的缓慢的光反应速率。

    Method for polymerizing cycloolefin polymer containing polar functional groups and electronic devices employing the polymerized cycloolefins
    28.
    发明授权
    Method for polymerizing cycloolefin polymer containing polar functional groups and electronic devices employing the polymerized cycloolefins 有权
    聚合包含极性官能团的环烯烃聚合物的方法和使用聚合环烯烃的电子器件

    公开(公告)号:US07718744B2

    公开(公告)日:2010-05-18

    申请号:US10502185

    申请日:2003-12-03

    摘要: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.

    摘要翻译: 公开了一种制备含有极性官能团的环烯烃聚合物的方法,包括:制备催化剂混合物,其包括i)含有具有与金属键合的含氧离子的配体的第10族过渡金属的预催化剂; ii)第一助催化剂,其是含有第15族元素的有机化合物; 和iii)能够提供阴离子并与预催化剂的金属弱配位的第二助催化剂; 将含有极性官能团的降冰片烯系化合物的单体溶液在有机溶剂和催化剂混合物的存在下,在80〜200℃的温度下进行加成聚合反应, 溶剂为50-800重量%,基于单体溶液中所含单体的总重量,聚合物的产物收率基于单体的总重量为50重量%以上。

    PHOTOREACTIVE EXO-RICH NORBORNENE POLYMER AND METHOD FOR PREPARING THE SAME
    29.
    发明申请
    PHOTOREACTIVE EXO-RICH NORBORNENE POLYMER AND METHOD FOR PREPARING THE SAME 有权
    光催化超高斯诺酮聚合物及其制备方法

    公开(公告)号:US20100121005A1

    公开(公告)日:2010-05-13

    申请号:US12450303

    申请日:2008-03-21

    IPC分类号: C08F132/08 C08F4/00

    CPC分类号: C08F32/08 C08F8/00

    摘要: The present invention relates to a norbornene polymer that comprises a norbornene monomer having a photoreactive functional group, and a method of manufacturing the same. The norbornene polymer comprises at least 50 mol % of exo isomers among the norbornene monomers having the photoreactive functional group. Since the norbornene polymer according to the present invention comprises at least 50 mol % of exo isomers among the norbornene monomers having the photoreactive functional group, a molecular weight is significantly increased while the yield is not reduced during the manufacturing of the polymer. In views of the three dimensional structure, stability is ensured because the polymer has a planar structure in which the photoreactive groups between the molecules are close to each other. Therefore, the distance between the photoreactive groups is reduced, thus increasing the photoreaction rate.

    摘要翻译: 本发明涉及包含具有光反应性官能团的降冰片烯单体的降冰片烯聚合物及其制造方法。 降冰片烯聚合物包含具有光反应性官能团的降冰片烯单体中的至少50摩尔%的外来异构体。 由于根据本发明的降冰片烯聚合物在具有光反应性官能团的降冰片烯单体中包含至少50mol%的外部异构体,所以在聚合物的制造过程中分子量显着增加,而收率没有降低。 从三维结构的观点来看,确保了稳定性,因为聚合物具有其中分子之间的光反应基团彼此接近的平面结构。 因此,光反应基团之间的距离减小,从而增加光反应速率。