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    Process for the preparation of triethylenediamine (TEDA)
    22.
    发明授权
    Process for the preparation of triethylenediamine (TEDA) 有权
    三亚乙基二胺（TEDA）的制备方法

    公开(公告)号：US06562971B2

    公开(公告)日：2003-05-13

    申请号：US09765625

    申请日：2001-06-26

    申请人： Matthias Frauenkron ,  Bernd Stein

    发明人： Matthias Frauenkron ,  Bernd Stein

    IPC分类号： C07D295023

    CPC分类号： C07D487/08 ,  Y02P20/582

    摘要： A process for the preparation of triethylenediamine (TEDA) by reaction of ethylenediamine (EDA) in the presence of a zeolite catalyst, wherein the zeolite catalyst comprises one or more metals M in oxidation states II, III or IV as oxides, and for M=Al, has an SiO2/M2O3 molar ratio of greater than 1400:1, for M=metal in oxidation state II or M=two or more metals in oxidation state II, has an SiO2/MO molar ratio of greater than 100:1, for M=metal in oxidation state III or M=two or more metals in oxidation state III, has an SiO2/M2O3 molar ratio of greater than 100:1 and for M=metal in oxidation state IV or M=two or more metals in oxidation state IV, has an SiO2/MO2 molar ratio of greater than 10:1, and the reaction temperature is from 250 to 500° C.

    摘要翻译： 在沸石催化剂存在下，通过乙二胺（EDA）反应制备三亚乙基二胺（TEDA）的方法，其中沸石催化剂包含一种或多种氧化态为II，III或IV的氧化物的金属M，M = Al， 对于M =氧化态II的金属或M =氧化态II的两种或多种金属，SiO 2 / M 2 O 3的摩尔比大于1400:1，对于M =氧化态III或M =氧化态III中的两种或更多种金属的金属，具有大于100：1的SiO 2 / M 2 O 3摩尔比，M =氧化态IV或M =处于氧化态的二种或更多种金属IV ，SiO 2 / MO 2摩尔比大于10:1，反应温度为250-500℃。

    Direct Amination of Hydrocarbons
    24.
    发明申请
    Direct Amination of Hydrocarbons 审中-公开
    碳氢化合物的直接胺化

    公开(公告)号：US20080146846A1

    公开(公告)日：2008-06-19

    申请号：US11722774

    申请日：2005-12-20

    申请人： Harald Dialer ,  Matthias Frauenkron ,  Holger Evers ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Frank Rosowski ,  Frederik Van Laar ,  Joachim-Thierry Anders ,  Sven Crone ,  Wolfgang Mackenroth

    发明人： Harald Dialer ,  Matthias Frauenkron ,  Holger Evers ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Frank Rosowski ,  Frederik Van Laar ,  Joachim-Thierry Anders ,  Sven Crone ,  Wolfgang Mackenroth

    IPC分类号： C07C209/02

    CPC分类号： C07C209/02 ,  B01J23/755 ,  B01J23/76 ,  B01J23/885 ,  B01J23/8892 ,  B01J23/8933 ,  B01J23/94 ,  B01J27/24 ,  B01J27/28 ,  B01J37/03 ,  B01J37/04 ,  B01J38/08 ,  B01J38/18 ,  Y02P20/584 ,  C07C211/46

    摘要： The invention relates to a process for preparing nitrogen-containing catalysts, comprising: a) preparation of an oxidic species comprising the following components: at least one metal M selected from groups Ib to VIIb and VIII of the Periodic Table of the Elements, it being possible for the same metal to be present in different oxidation states; if appropriate one or more promoters P selected from groups Ib to VIIb and VIII of the Periodic Table of the Elements, the lanthanides, and from groups IIIa to VIa of the Periodic Table of the Elements, excluding oxygen and sulfur; if appropriate one or more elements R selected from hydrogen, alkali metals and alkaline earth metals; if appropriate one or more elements Q selected from chloride and sulfate; oxygen, the molar proportion of oxygen being determined by the valency and frequency of the elements in the oxidic species other than other oxygen; b) reaction of the oxidic species with an amine component selected from ammonia, primary and secondary amines and ammonium salts, the nitrogen-containing catalyst being formed with the formation of water, and to nitrogen-containing catalysts preparable by this process. The invention further relates to a process for aminating hydrocarbons using the inventive nitrogen-containing catalyst and to the use of an oxidic species in a process for the direct amination of hydrocarbons.

    摘要翻译： 本发明涉及一种制备含氮催化剂的方法，包括：a）制备包含以下组分的氧化物质：至少一种选自元素周期表Ib至VIIb和VIII族的金属M，它是 可能使相同的金属以不同的氧化态存在; 如果合适的话，可以选择元素周期表Ib-VIIb和VIII族中的一种或多种助催化剂P，元素周期表IIIa至VIa族，不包括氧和硫; 如果合适，则选自氢，碱金属和碱土金属的一种或多种元素R; 如果适当，选自氯化物和硫酸盐的一种或多种元素Q; 氧，氧的摩尔比例由氧化物中除了其它氧以外的元素的化合价和频率决定; b）氧化物质与选自氨，伯胺和仲胺和铵盐的胺组分的反应，形成水的含氮催化剂，以及可通过该方法制备的含氮催化剂。 本发明还涉及使用本发明的含氮催化剂胺化烃的方法以及在直接胺化烃的方法中使用氧化物质的方法。

    Work-up of the mother liquor obtained in the preparation of high-purity triethylenediamine
    25.
    发明授权
    Work-up of the mother liquor obtained in the preparation of high-purity triethylenediamine 有权
    在制备高纯三乙二胺时得到的母液的处理

    公开(公告)号：US07345173B2

    公开(公告)日：2008-03-18

    申请号：US10138337

    申请日：2002-05-06

    申请人： Ortmund Lang ,  Bernd Rumpf ,  Matthias Frauenkron ,  Dirk Funhoff ,  Thomas Manderbach ,  Bernd Stein

    发明人： Ortmund Lang ,  Bernd Rumpf ,  Matthias Frauenkron ,  Dirk Funhoff ,  Thomas Manderbach ,  Bernd Stein

    IPC分类号： C07D487/00

    CPC分类号： C07D487/08

    摘要： In a process for the purification of triethylenediamine (TEDA) in which TEDA is vaporized and the gaseous TEDA is passed into a liquid solvent and is subsequently crystallized from this, the mother liquor obtained after the TEDA has been crystallized is extracted with an extractant which is immiscible or only slightly miscible with the solvent of the mother liquor and in which TEDA is readily soluble, and the TEDA-depleted mother liquor obtained after extraction and/or the TEDA-enriched extractant which has been used for the extraction are/is returned to the process.

    摘要翻译： 在其中TEDA蒸发并将气态TEDA进入液体溶剂并随后从其中结晶的三亚乙基二胺（TEDA）的纯化方法中，在TEDA结晶后获得的母液用萃取剂萃取，萃取剂为 不混溶或仅与母液的溶剂轻微混溶，其中TEDA易溶，并且在萃取后获得的TEDA贫化母液和/或用于萃取的富含TEDA的萃取剂返回至 的过程。

    Method of selectively synthesizing triethylenediamine
    28.
    发明授权
    Method of selectively synthesizing triethylenediamine 失效
    选择性合成三亚乙基二胺的方法

    公开(公告)号：US06958397B2

    公开(公告)日：2005-10-25

    申请号：US10482644

    申请日：2002-07-04

    申请人： Matthias Frauenkron ,  Bernd Stein ,  Ortmund Lang

    发明人： Matthias Frauenkron ,  Bernd Stein ,  Ortmund Lang

    IPC分类号： B01J29/40 ,  C07B61/00 ,  C07D487/08

    CPC分类号： C07D487/08 ,  B01J29/40 ,  B01J2229/42

    摘要： The present invention describes a process for the preparation of triethylenediamine by reacting piperazine over a zeolite catalyst which, in addition to SiO2, contains an oxide of at least one further divalent, trivalent or tetravalent metal M, wherein the zeolite has a molar Si/M ratio of >100. In particular, a zeolite of the ZSM-5 type is used. The use of the zeolites permits suppression of the undesired formation of the byproduct 2-ethylpiperazine and hence considerable simplification of the working-up, in combination with high piperazine conversions and a small excess of water.

    摘要翻译： 本发明描述了一种通过哌嗪在沸石催化剂上反应制备三亚乙基二胺的方法，该沸石催化剂除SiO 2外还含有至少另外一种二价，三价或四价金属M的氧化物，其中 沸石的Si / M摩尔比> 100。 特别地，使用ZSM-5型的沸石。 沸石的使用允许抑制副产物2-乙基哌嗪的不期望的形成，因此相当简化的加工，加上高哌嗪转化率和少量过量的水。