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28 条记录 (耗时 0.027 秒)

    Aryl arenesulfonates and a method of lubrication using the aryl arenesulfonates
    21.
    发明授权
    Aryl arenesulfonates and a method of lubrication using the aryl arenesulfonates 失效
    芳基磺酰基芳基磺酸盐和使用芳基芳烃磺酸盐的润滑方法

    公开(公告)号：US5340489A

    公开(公告)日：1994-08-23

    申请号：US996548

    申请日：1992-12-24

    申请人： Bassam S. Nader ,  Chester E. Pawloski

    发明人： Bassam S. Nader ,  Chester E. Pawloski

    IPC分类号： C10M105/72 ,  C10M135/10

    CPC分类号： C10M105/72 ,  C10M2219/044 ,  C10N2230/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/12 ,  C10N2240/121

    摘要： A method for lubricating inorganic surfaces which comprises applying an aryl arenesulfonate between two inorganic surfaces in an amount sufficient to decrease the friction between the two surfaces, wherein the aryl arenesulfonate is of the formula ASO.sub.3 A, ASO.sub.3 BSO.sub.3 A, or (ASO.sub.3).sub.3 B wherein A is independently in each occurrence phenyl or substituted phenyl, wherein when A is substituted phenyl the phenyl can be substituted by halo, a ketone substituted by an aromatic group or alkyl group, alkyl, polyhaloalkyl, alkoxy, polyhaloalkoxy, aryl, aralkyl, haloaryl, aryloxy, polyhaloaryloxy, polyhaloalkylaryl, or polyhaloalkylaryloxy, and wherein B is benzene or two benzene rings connected by a divalent bridging group selected from the group consisting of C(CH.sub.3).sub.2, O, OCH.sub.2, OCH.sub.2 CH.sub.2, OCH.sub.2 CH.sub.2 O, C(CF.sub.3).sub.2, S, SO.sub.2, CO, and 9,9'-fluorene.

    摘要翻译： 一种用于润滑无机表面的方法，其包括在两个无机表面之间施加足够的量的芳族芳烃磺酸芳基酯以减少两个表面之间的摩擦，其中芳基芳烃磺酸盐具有式ASO3A，ASO3BSO3A或（ASO3）3B，其中A独立地 在每次出现苯基或取代的苯基时，其中当A为取代苯基时，苯基可被卤素取代，被芳基或烷基取代的酮，烷基，多卤代烷基，烷氧基，多卤代烷氧基，芳基，芳烷基，卤代芳基，芳氧基，多卤代芳基 ，多卤代烷基芳基或多卤代烷氧基，并且其中B是苯或通过选自C（CH 3）2，O，OCH 2，OCH 2 CH 2，OCH 2 CH 2 O，C（CF 3）2，S，SO 2的二价桥连基团连接的两个苯环） ，CO和9,9'-芴。

    Oxidation-resistant cyclophosphazene fluid including triarylphosphine or phosphine oxide
    22.
    发明授权
    Oxidation-resistant cyclophosphazene fluid including triarylphosphine or phosphine oxide 失效
    包含三芳基膦或氧化膦的抗氧化环磷腈流体

    公开(公告)号：US5194652A

    公开(公告)日：1993-03-16

    申请号：US891378

    申请日：1992-05-29

    申请人： Bassam S. Nader

    发明人： Bassam S. Nader

    IPC分类号： C07F9/6581 ,  C10M169/04

    CPC分类号： C10M169/04 ,  C07F9/65814 ,  C10M2223/003 ,  C10M2223/023 ,  C10M2223/04 ,  C10M2223/0405 ,  C10M2223/042 ,  C10M2223/0495 ,  C10M2223/06 ,  C10M2223/0603 ,  C10M2223/061 ,  C10M2223/083 ,  C10M2223/103 ,  C10N2240/08

    摘要： The oxidation resistance of a cyclophosphazene-based fluid (such as a lubricant or a hydraulic fluid) can be improved by the addition to the fluid of an oxidation-inhibiting amount of an aryl phosphine or phosphine oxide. The aryl phosphine or phosphine oxide is preferably present in an amount of about 0.01 to about 5 percent by weight. The aryl phosphine or phosphine oxide can be (a) a symmetric triarylphosphine of formula R.sub.3 P, wherein R is 4-trifluoromethyl phenyl, 3-trifluoromethyl phenyl, 3-trifluoromethoxy phenyl, 3-(3-trifluoromethylphenoxy) phenyl, 3-(perfluoro-2, 5-dimethyl-3, 6-dioxanonyl) phenyl or 1-naphthyl; (b) an oxide of any of these symmetric triarylphosphines; or (c) 1, 3-bis(diphenylphosphino) benzene. The cyclophosphazene fluid component is preferably a (fluorinated phenoxy) (3-perfluoroalkylphenoxy)-cyclic phosphazene of the general formula (I): ##STR1## wherein n is 3 to 7, inclusive; wherein R is individually in each occurrence fluorinated phenoxy or 3-perfluoroalkylphenoxy; and wherein the ratio of fluorinated phenoxy to 3-perfluoroalkylphenoxy is about 1:5 to 1:1 inclusive. Although useful as antioxidants in other fluids such as polyphenyl ethers, perfluorinated aliphatic polyethers and polyol esters, the antioxidant activity of the defined aryl phosphines and phosphine oxides in cyclophosphazene fluids is unexpected because of the significant difference in the pathways of oxidative degradation between the cyclophosphazenes and these other fluids.

    摘要翻译： 通过添加到氧化抑制量的芳基膦或氧化膦的流体，可以改善环磷腈系流体（如润滑剂或液压油）的抗氧化性。 芳基膦或氧化膦优选以约0.01至约5重量％的量存在。 芳基膦或氧化膦可以是（a）式R3P的对称三芳基膦，其中R是4-三氟甲基苯基，3-三氟甲基苯基，3-三氟甲氧基苯基，3-（3-三氟甲基苯氧基）苯基，3-（全氟 - 2,5-二甲基-3,6-二恶烷基）苯基或1-萘基; （b）这些对称三芳基膦中的任何一种的氧化物; 或（c）1,3-双（二苯基膦基）苯。 环磷腈流体组分优选为通式（I）的（氟化苯氧基）（3-全氟烷基苯氧基） - 环磷腈：其中n为3至7，包括端值; 其中R各自单独出现氟化苯氧基或3-全氟烷基苯氧基; 并且其中氟化苯氧基与3-全氟烷基苯氧基的比例为约1:5至1:1。 尽管在其他流体如聚苯醚，全氟化脂族聚醚和多元醇酯中的抗氧化剂是有用的，但是定义的芳基膦和氧化膦在环磷腈流体中的抗氧化活性是出人意料的，因为环磷腈与环氧磷腈之间的氧化降解途径有显着的差异 这些其他液体。

    High temperature lubricants containing cesium, robidium, and lithium salts
    26.
    发明授权
    High temperature lubricants containing cesium, robidium, and lithium salts 失效
    含有铯，溴化锂和锂盐的高温润滑剂

    公开(公告)号：US5456848A

    公开(公告)日：1995-10-10

    申请号：US5700

    申请日：1993-01-19

    申请人： Bassam S. Nader ,  Ted A. Morgan

    发明人： Bassam S. Nader ,  Ted A. Morgan

    IPC分类号： C10M169/04 ,  C10M113/16

    CPC分类号： C10M169/04 ,  C10M2201/062 ,  C10M2201/085 ,  C10M2207/14 ,  C10M2207/141 ,  C10M2207/142 ,  C10M2209/1013 ,  C10M2209/1023 ,  C10M2211/044 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

    摘要： In one respect, this invention is a lubricating composition which comprises a polyaryl ether lubricating fluid and an additive which is (a) cesium carbonate, (b) cesium phosphate, or (c) a benzoate of cesium, rubidium, or lithium wherein the additive is present in the lubricating composition in an amount effective to produce an antioxidative effect in the lubricating composition. In another respect, this invention is a process for reducing the rate of oxidation in a polyaryl ether lubricating fluid which comprises adding an additive wherein the additive is (a) cesium carbonate, (b) cesium phosphate, or (c) a benzoate of cesium, rubidium, or lithium to the polyaryl ether lubricating fluid in an amount effective to produce an antioxidative effect in the lubricating composition.

    摘要翻译： 在一个方面，本发明是一种润滑组合物，其包含聚芳基醚润滑流体和添加剂，其为（a）碳酸铯，（b）铯磷酸盐或（c）铯，铷或锂的苯甲酸盐，其中添加剂 以有效地在润滑组合物中产生抗氧化作用的量存在于润滑组合物中。 在另一方面，本发明是降低聚芳基醚润滑流体中的氧化速率的方法，其包括添加添加剂，其中添加剂是（a）碳酸铯，（b）磷酸铯或（c）铯的苯甲酸酯 ，铷或锂，以有效地在润滑组合物中产生抗氧化作用。