Abstract:
A method of separating and selectively removing hydrogen contaminant from hydrogen-containing product and by-product process streams is disclosed. Separation and removal occur when certain Cd-exchanged zeolite rho compositions are placed in contact with a hydrogen-containing process stream. A hydrogen-encapsulated zeolite rho composition is formed by practice of the method.
Abstract:
The present invention relates to the selectivity of production of methylamines from methanol and/or dimethylether and ammonia using at catalytic amount of acidic molecular sieve.
Abstract:
When small amounts of zeolite or titanosilicates are added to thermotropic liquid crystalline aromatic polyester, poly(ester-amide) or poly(ester-imide) compositions, the compositions become less flammable. In many cases addition of the zeolite or titanosilicates does not significantly affect other properties of the composition, which may be used as molding resins, for instance to make parts useful in the electrical, electronic or automotive industry.
Abstract:
Novel Cd-exchanged rho compositions and compositions of zeolite rho encapsulated with hydrogen made therefrom are disclosed. The Cd-exchanged zeolite rho compositions are useful in separating and selectively removing hydrogen from hydrogen-containing process streams and storing the separated hydrogen therein. Encapsulation of hydrogen can be accomplished in large amounts even at pressures of 1 atmosphere.
Abstract:
A method for converting trans-cis nepetalactone to cis-trans nepetalactone using molecular sieves. The molecular sieves may, for example, have a pH in water of at least about 9, and/or may be activated prior to use by heating.
Abstract:
Aromatic compounds such as o-xylene are selectively nitrated by nitric acid in the presence of polyphosphoric acid and a large pore, acidic zeolite or a large pore, hydrophobic molecular sieve. This is an environmentally friendly, commercially viable, high conversion process for the selective nitration of aromatic compounds in the para position.
Abstract:
The present invention relates to the use of hydrotalcites as catalysts for the polymerization of unsubstituted or substituted trimethylene carbonate.
Abstract:
The invention concerns nanoporous carbon membranes which have been synthesized by pyrolysis of selected polymers on porous substrates to produce thin mixed matrix carbon film with pores for separation of small molecules.
Abstract:
A process is provided to separate 1,3-propanediol, glycerol, or a mixture of 1,3-propanediol and glycerol from a biological mixture using a molecular sieve.
Abstract:
A process that can be used for sulfonating, sulfating, or sulfamating an organic compound is disclosed. The process can comprise, consist essentially of, or consist of, contacting the organic compound with sulfur trioxide under a condition sufficient to effect the sulfonation, sulfation, or sulfamation of the organic compound. The organic compound can be an aromatic compound, alcohol, carbohydrate, amine, amide, protein, or combinations of two or more thereof. The sulfur trioxide can be present in a complex comprising an inorganic support such as zeolite, silicalite, silica, titanosilicate, borosilicate, clay, aluminophosphate, and combinations of two or more thereof.