摘要:
A process for recovering bitumem from oil-in-water (O/W) emulsions is disclosed wherein water soluble demulsifiers are used. These demulsifiers are water soluble polyethers prepared by the reaction between certain diepoxides and poly(ethyleneoxy) glycols. To resolve the bituminous petroleum emulsions, the process is carried out between 25.degree. and 160.degree. C. wherein the demulsifier of the invention is contacted with the bituminous emulsion.
摘要:
Covers compounds of the formula ##STR1## where R" is lower alkyl, R is hydrogen or lower alkyl and Y is selected from the group consisting of CN, CONH.sub.2, CO.sub.2 R', CONR'.sub.2 and COR' where R' independently is hydrogen, lower alkyl or aryl. Also covers a method of producing a polyurethane by utilizing said above compounds as catalysts in reacting an organic polyisocyanate with an organic polyester polyol or polyether polyol in the presence of said catalyst.
摘要:
Covers novel urethane-modified polyisocyanurate rigid foams comprising the reaction product obtained by bringing together in the presence of a blowing agent an aromatic polyisocyanate, an isocyanurate group formation catalyst, and a polyol comprising a specific alkylene oxide adduct of aniline. The novel foams are useful in preparing rigid foam material such as panels, slabs, or sprayed foam surfaces.
摘要:
Disclosed is a one-step method for preparing N-alkylpiperazines which eliminates the initial preparation and isolation of piperazine which comprises reacting a carbonyl compound and an amine in the presence of hydrogen over a metallic hydrogenation-dehydrogenation catalyst from Group VIII of the Periodic Table such as, for example, nickel, copper, cobalt, chromium, palladium, platinum or ruthenium, alone or in combination with other Group VIII metals or transition metals selected from the group consisting of manganese, iron, zinc, copper and chromium.
摘要:
Diamidopolyamines are prepared by reacting glutamic acid with two moles, per mole of glutamic acid, of a defined class of diamines, including oxyethyelene diamines, oxypropylenediamines, oxyethylene/propylene diamines, oxypropylene triamines, 1,2-diaminocyclohexane and isophorone diamine, whereby each of the carboxyl groups of the glutamic acid will react with an amine group of the amine reactant to thereby provide primary amine terminated amidopolyamines containing, internally, the unreacted primary amine group of the glutamic acid.
摘要:
Amidamines of the following formula are described: ##STR1## where R is independently hydrogen or lower alkyl of 1 to 4 carbon atoms;R' is an alkyl group if k is 1, or an alkylene group if k is greater than 1; where R' has 2 to 18 carbon atoms;R" is independently lower alkylene of 2 to 4 carbon atoms;R'" is independently straight or branched lower alkylene of 2 to 6 carbon atoms;x is independently 1 to 200;y is independently 1 to 300;z is independently 1 to 200;p is independently 2 to 11; andk is from 1 to 8; where the x and z groups may be distributed in blocks or randomly.These compositions are made by reacting a cyclic lactam with an etheramine. Incorporation of increasing quantities of the polyetherpolyamine did not decrease the crystalline melting point (T.sub.m) of the resulting copolymer. The polyamidopolyfunctional amines (poly(amide-ether-amide) triblock copolymers) have a relatively low modulus and retain higher use temperatures than current polyetheramide segment block copolymers. The polyamidopolyether amines may be further interconnected through reaction with dicarboxylic acids, esters and the like.
摘要:
An epoxy resin curative composition that provides cured epoxy resins exhibiting improved properties is disclosed. The curative composition comprises a mixture of 1-isopropyl-2-aryl imidazole and 1-isopropyl-2-aryl imidazoline.
摘要:
Polyamide reaction products comprising: a dicarboxylic acid and a diamine component comprising a mixture of poly(oxytetramethylene) diamines and oligomers of said poly(oxytetramethylene) diamines,said mixture containing from about 85 to about 99.5 wt. % of said poly(oxytetramethylene) diamines and, correspondingly, from about 15 to about 0.5 wt. % of said oligomers,said poly(oxytetramethylene) diamines having the formula: ##STR1## wherein n represents 0 or a positive number having a value of 1 to about 30,said oligomers having the formula: ##STR2## wherein n represents 0 or a positive number having a value of 1 to about 30.
摘要:
An extractive distillation agent consisting essentially of sulfolane is fed to an extractive distillation column used for the distillation of propylene oxide contaminated with water to obtain an overhead distillate fraction consisting of essentially anhydrous propylene oxide, and a heavier bottoms distillation fraction containing substantially all of the sulfolane and water introduced into the distillation column.
摘要:
Disclosed is a coating composition with improved stability which comprises an isocyanate which has been chemically blocked and a curing agent comprising an N,N'-dialkylalkylenediamine.