Process for preparing novel diamines
    4.
    发明授权
    Process for preparing novel diamines 失效
    制备新型二胺的方法

    公开(公告)号:US5010160A

    公开(公告)日:1991-04-23

    申请号:US430686

    申请日:1989-10-30

    摘要: Polyoxyalkylene diamine reaction products which contain as the principle reaction component, a diamine having the formula: ##STR1## wherein R' independently represents hydrogen or methyl and x is a number having an average value of at least 1 to about 60 and a diisocyanate of the formula: ##STR2## The products of the invention are obtained by reacting an excess of polyoxyalkylene diamine with a diisocyanate in the presence of a polar solvent and have the following general structures: ##STR3## where B is alkyl group from diisocyanates, and R' has the same meaning as above.These products are further used to prepare coatings with improved properties by reacting said amine products with isocyanates prepolymers and epoxy material.

    摘要翻译: 含有作为主要反应组分的聚氧亚烷基二胺反应产物,具有下式的二胺:其中R'独立地表示氢或甲基,x是平均值至少为1至约60的数,和 本发明的产品是通过在极性溶剂存在下使过量的聚氧化烯二胺与二异氰酸酯反应得到的,并具有以下通用结构:其中B是 烷基,二烷基,R'与上述相同。 这些产品进一步用于通过使所述胺产物与异氰酸酯预聚物和环氧材料反应来制备具有改进性能的涂层。

    Purification of polyoxyalkylene glycols
    5.
    发明授权
    Purification of polyoxyalkylene glycols 失效
    聚氧亚烷基二醇的纯化

    公开(公告)号:US4994627A

    公开(公告)日:1991-02-19

    申请号:US494353

    申请日:1990-03-16

    IPC分类号: C07C41/36 C08G65/30

    CPC分类号: C08G65/30 C07C41/36

    摘要: A feedstock selected from the group consisting of polyoxyethylene glycols, polyoxypropylene glycols and monoalkyl ethers thereof having molecular weights of about 200 to about 5,000 and contaminated with more than about 100 ppm of alkali metal or alkaline earth metal ions is purified by bringing said feedstock into contact with a basic ion exchange resin in the presence of about 2 to about 10 wt. % of water, based on the weight of the feedstock at a temperature of about 25.degree. to about 100.degree. C. and a pressure of about 0 to about 100 psig. for a period of time sufficient to lower the impurity level of said ions by at least about 90% to a level of less than about 100 ppm,the basic ion exchange resin being a fully hydrated boron specific basic styrene-divinyl benzene ion exchange resin in the free base form having an apparent density of about 40 to 45 lbs. per cubic foot.

    摘要翻译: 选自分子量为约200至约5,000并且被大于约100ppm的碱金属或碱土金属离子污染的聚氧乙烯二醇,聚氧丙烯二醇和单烷基醚的原料通过使所述原料接触而被纯化 在约2至约10重量%的存在下使用碱性离子交换树脂。 基于在约25℃至约100℃的温度和约0至约100psig的压力下原料的重量的水。 足以使所述离子的杂质水平降低至少约90%至低于约100ppm的水平的时间段,所述碱性离子交换树脂是完全水合的硼特异性碱性苯乙烯 - 二乙烯基苯离子交换树脂, 游离碱形式具有约40至45磅的表观密度。 每立方英尺