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公开(公告)号：US20090171119A1
公开(公告)日：2009-07-02
申请号：US12279200
申请日：2007-02-13
申请人： Andreas Job , Uwe Westeppe , Lars Rodefeld
发明人： Andreas Job , Uwe Westeppe , Lars Rodefeld
IPC分类号： C07C231/10
CPC分类号： C07C231/10 , C07C233/58
摘要： An improved process for preparing menthylamides is provided by reacting menthyl halides with magnesium or lithium and subsequent reaction with an isocyanate, a heterocycle or a carbamoyl chloride.
摘要翻译： 通过使薄荷醇卤化物与镁或锂反应并随后与异氰酸酯，杂环或氨基甲酰氯反应来提供制备薄荷酰胺的改进方法。
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22.发明授权Special dihydroxydiphenyl bicycloalkanes, their production and their use for the production of high molecular weight polycarbonates 失效特殊的二羟基二苯基双环烷烃，它们的生产及其用于生产高分子量聚碳酸酯的用途
公开(公告)号：US5276213A
公开(公告)日：1994-01-04
申请号：US15753
申请日：1993-02-10
申请人： Volker Serini , Uwe Westeppe , Gerd Fengler , Manfred Hajek , Carl Casser , Helmut Waldmann
发明人： Volker Serini , Uwe Westeppe , Gerd Fengler , Manfred Hajek , Carl Casser , Helmut Waldmann
CPC分类号： C07C39/17 , C07C37/20 , C08G64/06 , C07C2102/24 , C07C2102/28
摘要： Dihydroxydiphenyl bicycloalkanes characterized in that they contain 9 to 13 ring C atoms in the bicycloaliphatic component are disclosed. The disclosed compounds were found to be suitable for the preparation of high molecular weight, thermoplastic polycarbonate resins having favorable properties.
摘要翻译： 二羟基二苯基双环烷烃的特征在于它们在双环脂族组分中含有9至13个环C原子。 发现所公开的化合物适用于制备具有良好性能的高分子量热塑性聚碳酸酯树脂。
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公开(公告)号：US5010162A
公开(公告)日：1991-04-23
申请号：US452874
申请日：1989-12-19
申请人： Volker Serini , Dieter Freitag , Uwe Westeppe , Karsten Idel , Ulrich Grigo , Carl Casser , Klaus-Christian Paetz , Manfred Hajek
发明人： Volker Serini , Dieter Freitag , Uwe Westeppe , Karsten Idel , Ulrich Grigo , Carl Casser , Klaus-Christian Paetz , Manfred Hajek
CPC分类号： C08G64/06
摘要： Thermoplastic aromatic polycarbonates having average molecular weights Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, a C.sub.1 -C.sub.12 hydrocarbon radical, halogen andR.sup.5, R.sup.6 and R.sup.7 represent hydrogen, iso-C.sub.3 -C.sub.5 -alkyl,one of the substituents R.sup.5, R.sup.6 or R.sup.7 not being hydrogen, in quantities of from 100 to 1 mol-%, based on the total quantity of difunctional carbonate structural units in the polycarbonate.
摘要翻译： 平均分子量＆gt; Mw至少为10,000的热塑性芳族聚碳酸酯，其含有对应于式（I）的双官能碳酸酯结构单元，其中R 1，R 2，R 3和R 4彼此独立地表示氢，C1- C12烃基，卤素和R5，R6和R7代表氢，异C3-C5-烷基，取代基R5，R6或R7之一不是氢，其量为100至1mol％，基于总计 聚碳酸酯中双官能碳酸酯结构单元的量。
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24.发明授权Dihydroxydiphenyl cycloalkanes, their production and their use for the production of high molecular weight polycarbonates 失效二羟基二苯基环烷烃，它们的生产及其用于生产高分子量聚碳酸酯的用途
公开(公告)号：US4982014A
公开(公告)日：1991-01-01
申请号：US390028
申请日：1989-08-04
申请人： Dieter Freitag , Uwe Westeppe , Claus H. Wulff , Karl-Herbert Fritsch , Carl Casser , Gunther Weymans , Lutz Schrader , Werner Waldenrath
发明人： Dieter Freitag , Uwe Westeppe , Claus H. Wulff , Karl-Herbert Fritsch , Carl Casser , Gunther Weymans , Lutz Schrader , Werner Waldenrath
CPC分类号： B01D71/50 , C07C39/17 , C08G64/06 , C07C2101/14
摘要： Dihydroxydiphenyl cycloalkanes corresponding to the formula ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl and C.sub.7 -C.sub.12 aralkyl,m is an integer of from 4 to 7,R.sup.3 and R.sup.4, individually selectable for each X, independently of one another represent hydrogen or C.sub.1 -C.sub.6 alkylandX represents carbonwith the proviso that, at at least one atom X, both R.sup.3 and R.sup.4 are alkyl, a process for their production, their use for the production of high molecular weight polycarbonates, the polycarbonates made from dihydroxydiphenyl cycloalkane of formula (I) and films made from these polycarbonates.
摘要翻译： 对应于式（I）的二羟基二苯基环烷烃，其中R 1和R 2彼此独立地表示氢，卤素，C 1 -C 8烷基，C 5 -C 6环烷基，C 6 -C 10芳基和C 7 -C 12芳烷基，m是整数 4至7个，每个X独立地各自独立地选择R 3和R 4表示氢或C 1 -C 6烷基，X表示碳，条件是在至少一个原子X，R 3和R 4均为烷基时， 其制备方法，其用于生产高分子量聚碳酸酯，由式（I）的二羟基二苯基环烷烃制成的聚碳酸酯和由这些聚碳酸酯制成的薄膜。
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25.发明授权Impact resistant polyamide moulding compounds modified with silicone graft rubbers 失效用聚硅氧烷接枝橡胶改性的耐冲击聚酰胺模塑料
公开(公告)号：US4945124A
公开(公告)日：1990-07-31
申请号：US294216
申请日：1989-01-09
IPC分类号： C08F285/00 , C08L51/04 , C08L77/00
CPC分类号： C08L51/04 , C08F285/00 , C08L77/00
摘要： This invention relates to polyamides which have been modified with special silicone graft rubbers to render them impact resistant and are tough at low temperatures and have high processing stability even at high temperatures and good surface properties.The moulding compounds, which are distinguished by excellent mechanical properties even at low temperatures, consist of at least 40% by weight of polyamide and special graft rubbers with a multishell core/sheath structure having a silicone-based core.
摘要翻译： 本发明涉及用特殊硅氧烷接枝橡胶改性的聚酰胺，使其具有耐冲击性，并且在低温下是韧性的，即使在高温下也具有高的加工稳定性和良好的表面性能。 即使在低温下也被优异的机械性能区分的成型化合物由至少40重量％的聚酰胺和具有硅酮核的多壳芯/鞘结构的特殊接枝橡胶组成。
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公开(公告)号：US5145911A
公开(公告)日：1992-09-08
申请号：US534094
申请日：1990-06-06
申请人： Thomas Eckel , Dieter Freitag , Uwe Westeppe , Dieter Wittmann
发明人： Thomas Eckel , Dieter Freitag , Uwe Westeppe , Dieter Wittmann
摘要： A thermoplastic molding composition comprising (i) an aromatic polycarbonate having high thermal dimensional stability and based on a substituted dihydroxydiphenylcycloalkane, (ii) other aromatic polycarbonate resin and (iii) graft, particle-type diene rubbers is disclosed. The composition is characterized by its good Izod impact strength. A process for preparing the molding composition and their use for manufacturing molded bodies are also disclosed.
摘要翻译： 公开了一种热塑性模塑组合物，其包含（i）具有高热尺寸稳定性并基于取代的二羟基二苯基环烷烃的芳族聚碳酸酯，（ii）其它芳族聚碳酸酯树脂和（iii）接枝的颗粒型二烯橡胶。 该组合物的特征在于其良好的Izod冲击强度。 还公开了制备模塑组合物的方法及其用于制造模塑体的用途。
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公开(公告)号：US5126404A
公开(公告)日：1992-06-30
申请号：US517084
申请日：1990-05-01
申请人： Thomas Eckel , Dieter Wittmann , Christian Lindner , Uwe Westeppe
发明人： Thomas Eckel , Dieter Wittmann , Christian Lindner , Uwe Westeppe
摘要： Thermoplastic molding composition comprisingA. 5 to 99% by weight (based on A+B) of a polycarbonate based on substituted dihydroxydiphenyl cycloalkanesB. 1 to 95% by weight (based on A+B) of a graft polymer prepared by a special process of5 to 90 parts by weight of a mixture ofB.1.1. 50 to 95 parts by weight styrene, .alpha.-methyl styrene, C.sub.1-4 alkyl- or halogen-nucleus-substituted styrenes, C.sub.1-8 alkyl methacrylates, C.sub.1-8 alkyl acrylates or mixtures thereof andB.1.2. 5 to 50 parts by weight acrylonitrile, methacrylonitrile, C.sub.1-8 alkyl methacrylates, C.sub.1-8 alkyl acrylates, maleic anhydride, C.sub.1-4 alkyl-N-maleic imides, phenyl-N-maleic imides or mixtures thereof onB.2. 10 to 95 parts by weight of a diene rubber having an average particle diameter d50 of from 0.09 to 1 .mu.m and a gel content of more than 50% by weight and optionally at least one other thermoplastic resin which replaces up to 75% by weight of the polycarbonate A.
摘要翻译： 含有5至99重量％（基于A + B）的基于取代的二羟基二苯基环烷烃的聚碳酸酯的热塑性模制组合物.B.1至95重量％（基于A + B）由特殊的 方法为5〜90重量份B.1.1的混合物。 50至95重量份苯乙烯，α-甲基苯乙烯，C 1-4烷基或卤素 - 核取代的苯乙烯，甲基丙烯酸C 1-8烷基酯，丙烯酸C 1-8烷基酯或其混合物和B.1.2。 5至50重量份丙烯腈，甲基丙烯腈，甲基丙烯酸C 1-8烷基酯，丙烯酸C 1-8烷基酯，马来酸酐，C 1-4烷基-N-马来酰亚胺，苯基-N-马来酰亚胺或其在B.2上的混合物。 10至95重量份平均粒径d 50为0.09至1微米且凝胶含量大于50重量％的二烯橡胶和任选的至少一种其它热塑性树脂，其代替75重量％ 的聚碳酸酯A.
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28.发明授权Moulding compounds of polyamides and graft polymers containing tert.-butylacrylate 失效含有叔丁基丙烯酸酯的聚酰胺和聚酰亚胺的成型化合物
公开(公告)号：US5122571A
公开(公告)日：1992-06-16
申请号：US406428
申请日：1989-09-11
CPC分类号： C08L51/003 , C08L77/00
摘要： This invention relates to new thermoplastic moulding compounds of polyamides, graft polymers containing tert.-butylacrylate in the shell and optionally also rubber polymers as impact strength modifiers.
摘要翻译： 本发明涉及聚酰胺的新的热塑性模塑料，在壳中含有丙烯酸叔丁酯的接枝聚合物，以及任选的橡胶聚合物作为冲击强度改性剂。
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29.发明授权Polyester-carbonate based on 1,1-bis-(4-hydroxyphenyl)-alkylcycloalkanes 失效基于1,1-双 - （4-羟基苯基） - 烷基环烷烃的聚酯 - 碳酸酯
公开(公告)号：US5041521A
公开(公告)日：1991-08-20
申请号：US472156
申请日：1990-01-30
申请人： Volker Serini , Dieter Freitag , Ulrich Grigo , Uwe Westeppe
发明人： Volker Serini , Dieter Freitag , Ulrich Grigo , Uwe Westeppe
IPC分类号： C08G63/199 , C08G63/181 , C08G63/19 , C08G63/193 , C08G63/553 , C08G63/64 , C08G63/672 , C08G63/682 , C08G63/688
CPC分类号： C08G63/193 , C08G63/64
摘要： Polyesters and polyester-carbonates based on dihydroxydiphenylcycloalkanes corresponding to the following general formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent hydrogen, a C.sub.1 -C.sub.12 hydrocarbon radical or halogen; m represents an integer of from 4 to 7,R.sup.5, and R.sup.6, may be selected individually for each X and independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andX represents carbon;with the proviso that, on at least one atom X, R.sup.5 and R.sup.6 simultaneously represent alkyl.
摘要翻译： 对应于以下通式的基于二羟基二苯基环烷烃的聚酯和聚酯 - 碳酸酯：其中R 1，R 2，R 3和R 4独立地表示氢，C 1 -C 12烃基或卤素; m表示4〜7的整数，R 5和R 6可以各自独立地为X而独立地表示氢或C1-C6烷基; X表示碳; 条件是在至少一个原子X，R 5和R 6同时表示烷基。
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公开(公告)号：US09023914B2
公开(公告)日：2015-05-05
申请号：US13395950
申请日：2010-08-31
CPC分类号： C08L15/005 , C08C19/02 , C08C19/20 , C08L19/006 , C08L35/00
摘要： A new process is provided for preparing nitrile rubbers by free-radical polymerization in an organic solvent and in the presence of specific modifier substances. This polymerization may be followed by hydrogenation to give likewise new hydrogenated nitrile rubbers, the hydrogenation advantageously taking place likewise in organic solvent. The optionally hydrogenated nitrile rubbers obtained are notable for having fragments of the employed modifier substances in the main polymer chain and/or as end groups. They can be prepared with a wide diversity of molecular weights and polydispersity indices, especially with very low polydispersity indices.
摘要翻译： 提供了一种通过在有机溶剂中和在特定改性剂物质存在下通过自由基聚合来制备丁腈橡胶的新方法。 该聚合之后可以进行氢化，同样提供新的氢化丁腈橡胶，氢化有利地同样存在于有机溶剂中。 所得到的任选氢化的丁腈橡胶在主聚合物链和/或端基中具有使用的改性物质的片段是显着的。 它们可以制备具有广泛的分子量和多分散指数，特别是具有非常低的多分散指数。
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