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26 条记录 (耗时 0.022 秒)

    Catalytic composition for the polymerization of olefins and its process of preparation
    21.
    发明授权
    Catalytic composition for the polymerization of olefins and its process of preparation 失效
    用于烯烃聚合的催化组合物及其制备方法

    公开(公告)号：US5264088A

    公开(公告)日：1993-11-23

    申请号：US741621

    申请日：1991-08-07

    申请人： Jean M. Brusson ,  Karel Bujadoux ,  Francis Petit ,  Jean M. Fuchs ,  Andre Mortreux

    发明人： Jean M. Brusson ,  Karel Bujadoux ,  Francis Petit ,  Jean M. Fuchs ,  Andre Mortreux

    IPC分类号： C08F10/00 ,  C25B3/00 ,  C07C2/02

    CPC分类号： C08F10/00

    摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha., .omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organs-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.

    摘要翻译： 制备烯烃聚合催化组合物的方法。 在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。 催化剂组合物包含至少一种钛化合物，至少一种卤化器官 - 铝化合物和至少一种α，ω-二卤代烷烃中的悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物。 钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。

    Process for the asymmetric hydrogenation of carbonyl compounds obtained
    23.
    发明授权
    Process for the asymmetric hydrogenation of carbonyl compounds obtained 失效
    获得的羰基化合物的不对称加氢方法

    公开(公告)号：US5128488A

    公开(公告)日：1992-07-07

    申请号：US515314

    申请日：1990-04-27

    申请人： Andre Mortreux ,  Francis Petit

    发明人： Andre Mortreux ,  Francis Petit

    IPC分类号： C07B41/02 ,  B01J31/22 ,  C07B31/00 ,  C07B53/00 ,  C07B61/00 ,  C07C29/136 ,  C07C67/00 ,  C07C231/12 ,  C07C233/00 ,  C07C233/11 ,  C07C235/36 ,  C07C237/04 ,  C07D307/32 ,  C07D307/33 ,  C07D307/60

    CPC分类号： C07C231/12 ,  B01J31/189 ,  C07B41/02 ,  C07B53/00 ,  C07D307/32 ,  C07D307/33 ,  B01J2231/643 ,  B01J2531/822

    摘要： The asymmetric hydrogenation of carbonyl compounds is carried out in the presence of at least one transition metal complex MZq(M=metal of group VIII of the Periodic Classication; Z=ligand selected among the atoms and the molecules which may complex the metal M; and q=degree of corrdination of M) and of at least one chiral phosphorous-containing ligand having formula (I), wherein R is hydrocarbonated radical (alkyl, cycloalkyl and aryl); R.sup.1 is H, hydrocarbonated radical or PR.sub.2 ; R.sup.2 is H or hydrocarbonated radical R.sup.3,R.sup.4, necessarily different, are H and optionally functionalized hydrocarbonated radicals; R.sup.5 and R.sup.6 are H and optionally functionalized hydrocarbonated radicals; one of the radicals R.sup.3 and R.sup.4 possibly carrying a function - OPR.sub.2 or NPR.sub.2, R.sup.5 and R.sup.6 being in this case H when R.sup.1 is PR.sub.2 ; R.sup.2 and R.sup.3 and the atoms of N and C which cary them respectively forming a heterocycle; or R.sup.2 and R.sup.5, the atoms of N and C which carry them respectively and the intermediate C atom possibly forming a heterocycle. ##STR1##

    摘要翻译： PCT No.PCT / FR87 / 00238 Sec。 371日期：1988年4月1日 102（e）日期1988年4月1日PCT提交1987年6月22日PCT公布。 公开号WO87 / 07889 日期为1987年12月30日。羰基化合物的不对称氢化在至少一种过渡金属络合物MZq（M =元素周期分类的VIII族金属; Z =选自原子和分子中的配体）存在下进行 可以使金属M复合; q = M的修饰度和至少一种具有式（I）的手性含磷配体，其中R是烃基（烷基，环烷基和芳基）; R1是H，烃基或PR2; R2是H或烃基R3，R4必定不同，是H和任选官能化的烃基; R5和R6是H和任选的官能化烃基; R3和R4之一可能具有功能 - OPR2或NPR2，R5和R6在这种情况下为R1，当R1为PR2时; R2和R3以及分别形成杂环的N和C的原子; 或R2和R5分别携带它们的N和C的原子和可能形成杂环的中间体C原子。 （一）

    2-,21-Dinoreburnamenines containing a 15-aminated group
    25.
    发明授权
    2-,21-Dinoreburnamenines containing a 15-aminated group 失效
    2-，21-含有15个氨基的组合

    公开(公告)号：US5081120A

    公开(公告)日：1992-01-14

    申请号：US460965

    申请日：1990-02-23

    申请人： Clemence Francois ,  Jean L. Haesslein ,  Francis Petit ,  Mauricette Degryse

    发明人： Clemence Francois ,  Jean L. Haesslein ,  Francis Petit ,  Mauricette Degryse

    IPC分类号： A61K31/435 ,  A61P25/04 ,  C07D461/00

    CPC分类号： C07D461/00

    摘要： A compound selected from the group consisting of a compound of the formula (I): ##STR1## in which R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen, an alkyl of 1 to 5 carbon atoms, --(CH.sub.2).sub.n --OH in which n is between 2 and 5, an aryl or arylalkyl of 7 to 12 carbon atoms, these two radicals being optionally substituted, ##STR2## in which R.sub.3 is an alkyl of 7 to 12 carbon atoms, these two radicals being optionally substituted, with the proviso that R.sub.1 and R.sub.2 are not both aryl simultaneously, or R.sub.1 and R.sub.2 form, together with the nitrogen atom to which they are linked, a saturated or unsaturated heterocyclic which can contain a second heteroatom chosen from oxygen, sulphur and nitrogen optionally substituted by an alkyl of 1 to 5 carbon atoms, aryl, arylalkyl of 7 to 12 carbon atoms, these radicals being optionally substituted, R.sub.4 and R.sub.5 are individually selected from the group consisting of hydrogen, halogen, alkyl or alkoxy of 1 to 5 carbon atoms, hydroxy, trifluoromethyl or nitro, the said products of formula (I) being in all the possible enantiomeric and diastereoisomeric forms and its non-toxic, pharmaceutically acceptable acid addition salts having an excellent analgesic activity.

    摘要翻译： PCT No.PCT / FR89 / 00335 Sec。 371日期1990年2月23日 102（e）1990年2月23日PCT PCT 1989年6月28日PCT公布。 公开号WO90 / 00171 日本1990年1月11日。一种选自由式（I）化合物组成的组的化合物：其中R 1和R 2分别选自氢，1至5个碳原子的烷基 ， - （CH 2）n -OH，其中n为2至5，7至12个碳原子的芳基或芳烷基，这两个基团任选被取代，其中R 3为7至12个碳原子的烷基 ，这两个基团任选被取代，条件是R 1和R 2不同时为芳基，或者R 1和R 2与它们所连接的氮原子一起形成饱和或不饱和的可以含有选自第二杂原子的杂环 由任选被1至5个碳原子的烷基取代的氧，硫和氮，芳基，7至12个碳原子的芳基烷基，这些基团任选被取代，R 4和R 5分别选自氢，卤素，烷基 或1至5个碳原子的烷氧基 所述式（I）的产物具有所有可能的对映异构体和非对映异构形式及其无毒的药学上可接受的酸加成盐，其具有优异的止痛活性。

    Electrochemical catalytic system, the process for preparation thereof and its application to the production of aldehydes
    26.
    发明授权
    Electrochemical catalytic system, the process for preparation thereof and its application to the production of aldehydes 失效
    电化学催化体系，其制备方法及其在醛类生产中的应用

    公开(公告)号：US4923840A

    公开(公告)日：1990-05-08

    申请号：US341233

    申请日：1989-04-18

    申请人： Andre Mortreux ,  Francis Petit ,  Sylvain Mutez ,  Eric Paumard

    发明人： Andre Mortreux ,  Francis Petit ,  Sylvain Mutez ,  Eric Paumard

    IPC分类号： B01J31/22 ,  C07C45/00 ,  C07C45/50 ,  C07C67/00 ,  C25B3/00 ,  C25B3/04 ,  C25B3/12

    CPC分类号： C25B3/12 ,  C07C45/50 ,  C25B3/00 ,  C25B3/04

    摘要： The catalytic system comprises:at least one platinum complex of formula LPtX.sub.2 in which L is an organic compound containing at least two phosphorus atoms capable of coordinating platinum and X is a halogen atom, andat least organic tin compound comprising at least one Sn--O bond and at least one C--O bond.Application to the production of aldehydes by the hydroformlation of an ethylenically unsaturated organic compound, by reacting the said organic compound, at a temperature of between 10.degree. C. and 300.degree. C. and under a pressure of between 1 and 350 bars, with a mixture of carbon monoxide and hydrogen in the presence of an effective amount of the said catalytic system.

    摘要翻译： 催化体系包括：至少一种式LPtX2的铂络合物，其中L是含有能配位铂的至少两个磷原子的有机化合物，X是卤素原子，并且至少包含至少一种Sn-O 键和至少一个CO键。 通过使烯属不饱和有机化合物的氢化成形，通过使所述有机化合物在10℃至300℃的温度和1至350巴的压力下反应生成醛的应用，其中 在有效量的所述催化体系的存在下，一氧化碳和氢的混合物。