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公开(公告)号：US20230415126A1
公开(公告)日：2023-12-28
申请号：US18036623
申请日：2021-03-24
发明人： Zhengsong Zhang , Zhijian Yang , Jingang Zhao , Zhenghua Li , Chaohui Chen
IPC分类号： B01J23/14 , C07D407/12 , B01J31/12
CPC分类号： B01J23/14 , C07D407/12 , B01J31/124 , B01J2231/49 , B01J2531/42
摘要： Provided are a supported catalyst and a method for synthesizing a sucrose-6-ester. The supported catalyst includes an active functional component and an inorganic carrier, wherein the active functional component is a compound shown in formula (1), wherein n is a natural number greater than or equal to 2; R is an atom linked to a surface of the inorganic carrier; and one or two of R1, R2, and R3 is/are hydrocarbyl, and the rest are independently any one selected from the group consisting of oxygen, hydroxyl, hydrocarbyloxy, and acetoxy.
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公开(公告)号：US20230338936A1
公开(公告)日：2023-10-26
申请号：US17636297
申请日：2021-08-18
发明人： Di WU , Peilong WU , Yinqiu LU , Jianguo CHEN , Xinwei LIU , Ge SONG , Changwang CAI
CPC分类号： B01J31/185 , B01J31/04 , B01J35/12 , B01J37/04 , C07C67/08 , B01J2231/14 , B01J2531/42
摘要： The present disclosure provides a stannous salt complex catalyst and a method for producing L-lactide by using the same. The catalyst is obtained by reacting stannous salt and phosphite in a solvent, which can effectively inhibit the oxidation of divalent stannous ions to tetravalent tin ions, effectively reduce the conversion rate of meso-lactide, increase the yield of L-lactide, and obtain nearly white L-lactide. In the crude lactide produced after the depolymerization reaction, the content of L-lactide is more than or equal to 95 %; the content of meso-lactide is less than or equal to 3.8 %, while ensuring that the color of the residual liquid is close to milky white.
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公开(公告)号：US09994516B2
公开(公告)日：2018-06-12
申请号：US15339176
申请日：2016-10-31
IPC分类号： C07C271/28 , C07C69/757 , C07C69/74 , C07C67/30 , C07C69/753 , C07C269/02 , C08J9/28 , C08F122/26 , C08F122/10 , C08F222/26 , C08F222/10
CPC分类号： C07C271/28 , B01J31/2208 , B01J2531/42 , C07C67/30 , C07C69/74 , C07C69/753 , C07C69/757 , C07C269/02 , C07C2602/42 , C08F122/10 , C08F122/26 , C08F222/10 , C08F222/1006 , C08F222/26 , C08F2222/1066 , C08G2101/0091 , C08J9/28 , C08J2205/026 , C08J2335/02
摘要： Novel urethane-acrylate (UAC) Star monomers and polyurethane-acrylate (PUAC) aerogel polymers derived therefrom are described herein, along with other novel, related monomers and polymers. Also described herein are processes for preparing the UAC Star monomers, the PUAC aerogel polymers, and the other related monomers and polymers. The PUAC and related polymers herein are useful in various applications including in structural and thermal insulation.
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4.发明授权Catalyst systems based on phenolate complexes for immortal ring-opening polymerization of cyclic esters and carbohydrates 有权基于酚盐配合物的催化剂体系，用于环状酯和碳水化合物的不间断开环聚合公开(公告)号：US09512267B2
公开(公告)日：2016-12-06
申请号：US14342281
申请日：2012-08-31
IPC分类号： C08G63/08 , C08G63/82 , C08G63/83 , C08G63/85 , C08G64/02 , C08G63/64 , C08G64/18 , C08G64/38
CPC分类号： C08G63/823 , B01J31/1805 , B01J31/2226 , B01J31/2243 , B01J2231/14 , B01J2531/42 , B01J2531/48 , C08G63/08 , C08G63/64 , C08G63/83 , C08G63/85 , C08G64/02 , C08G64/18 , C08G64/38
摘要： A method can include immortal ring-opening homopolymerisation of cyclic carbonates or cyclic esters in the presence of a catalytic system, or sequential two-step ring-opening block copolymerisation of one or more cyclic monomers selected from cyclic carbonates or cyclic esters in the presence of the catalytic system. The catalytic system can include a phenolate supported metallic complex. The catalytic system can also include an alcohol or a primary amine containing aliphatic and/or aromatic moieties. The alcohol or primary amine can be present in a molar ratio with respect to the metallic complex that is larger than 1.
摘要翻译： 一种方法可以包括在催化体系存在下环状碳酸酯或环状酯的永生开环均聚，或在选自环状碳酸酯或环状酯的一种或多种环状单体的存在下，连续两步开环嵌段共聚合 催化系统。 催化体系可以包括苯酚盐负载的金属络合物。 催化体系还可以包括含有脂族和/或芳族部分的醇或伯胺。 相对于大于1的金属络合物，醇或伯胺可以以摩尔比存在。
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5.发明申请FLEXIBLE TO RIGID NANOPOROUS POLYURETHANE-ACRYLATE (PUAC) TYPE MATERIALS FOR STRUCTURAL AND THERMAL INSULATION APPLICATIONS 有权柔性尼龙聚氨酯（PUAC）类型材料，用于结构和热绝缘应用公开(公告)号：US20150266983A1
公开(公告)日：2015-09-24
申请号：US14208892
申请日：2014-03-13
IPC分类号： C08F122/10 , B01J31/22 , C07C269/00 , C08F222/10 , C07C269/04
CPC分类号： C07C271/28 , B01J31/2208 , B01J2531/42 , C07C67/30 , C07C69/74 , C07C69/753 , C07C69/757 , C07C269/02 , C07C2602/42 , C08F122/10 , C08F122/26 , C08F222/10 , C08F222/1006 , C08F222/26 , C08F2222/1066 , C08G2101/0091 , C08J9/28 , C08J2205/026 , C08J2335/02
摘要： Novel urethane-acrylate (UAC) Star monomers and polyurethane-acrylate (PUAC) aerogel polymers derived therefrom are described herein, along with other novel, related monomers and polymers. Also described herein are processes for preparing the UAC Star monomers, the PUAC aerogel polymers, and the other related monomers and polymers. The PUAC and related polymers herein are useful in various applications including in structural and thermal insulation.
摘要翻译： 本文描述了衍生自其的新型聚氨酯 - 丙烯酸酯（UAC）星形单体和聚氨酯 - 丙烯酸酯（PUAC）气凝胶聚合物，以及其它新颖的相关单体和聚合物。 本文还描述了制备UAC Star单体，PUAC气凝胶聚合物和其它相关单体和聚合物的方法。 本文中的PUAC和相关聚合物可用于各种应用，包括结构和绝热。
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公开(公告)号：US20130225722A1
公开(公告)日：2013-08-29
申请号：US13882560
申请日：2011-11-13
申请人： Willy Paar , Johann Billiani
发明人： Willy Paar , Johann Billiani
CPC分类号： B01J31/06 , B01J31/0212 , B01J31/04 , B01J31/08 , B01J31/122 , B01J31/26 , B01J2531/42 , B01J2531/46 , B01J2531/54 , C08G59/68 , C09D163/00
摘要： The invention relates to an emulsifiable catalyst composition which comprises at least one of metal salts, metal complexes, and acids, and at least one amphiphilic compound which is a graft copolymer based on oils or diene homo-and copolymers that bear graft branches derived from olefinically unsaturated monomers, and an average, per molecule, of at least one cationic group or cationogenic group that forms cations when contacted with an acid, to a process for its preparation, and a method of use thereof as catalyst in aqueous coating compositions.
摘要翻译： 本发明涉及一种可乳化催化剂组合物，其包含金属盐，金属络合物和酸中的至少一种，以及至少一种两亲化合物，其是基于油或二烯同聚物和共聚物的接枝共聚物，所述共聚物具有衍生自烯属的接枝分枝 不饱和单体和平均每分子中的至少一个阳离子基团或与酸接触时形成阳离子的阳离子基团，其制备方法及其在水性涂料组合物中用作催化剂的方法。
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公开(公告)号：US08178464B2
公开(公告)日：2012-05-15
申请号：US11526462
申请日：2006-09-25
发明人： Alan D. McInnes
CPC分类号： C09D175/02 , B01J31/0237 , B01J31/122 , B01J2231/14 , B01J2531/42 , B01J2531/44 , C08G18/0895 , C08G18/10 , C08G18/165 , C08G18/307
摘要： Isocyanate prepolymer catalysts and processes for rapidly curing isocyanate prepolymers are disclosed herein. Substrates coated with the isocyanate prepolymers are treated with a drying agent and water, which combine to form a hydrated catalyst complex. Co-catalysts, such as organo tins, may be used to further enhance the curing rate.
摘要翻译： 本文公开了异氰酸酯预聚物催化剂和快速固化异氰酸酯预聚物的方法。 用异氰酸酯预聚物涂覆的基材用干燥剂和水处理，其结合形成水合催化剂络合物。 可以使用诸如有机罐的助催化剂来进一步提高固化速率。
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公开(公告)号：US07767612B2
公开(公告)日：2010-08-03
申请号：US10432510
申请日：2001-11-21
申请人： Andrew Martin Bellamy , Charles Mark Lindall , Calum Harry McIntosh , Martin Graham Partridge , John Armstrong Young , Steven Charles Davies
发明人： Andrew Martin Bellamy , Charles Mark Lindall , Calum Harry McIntosh , Martin Graham Partridge , John Armstrong Young , Steven Charles Davies
CPC分类号： B01J31/26 , B01J31/0212 , B01J31/0239 , B01J31/04 , B01J31/122 , B01J31/223 , B01J2231/14 , B01J2231/49 , B01J2531/31 , B01J2531/42 , B01J2531/46 , B01J2531/48 , B01J2531/52 , C08G63/183 , C08G63/80 , C08G63/85 , C08G63/87 , D01F6/62 , D04H1/42
摘要： A catalyst composition for producing polyesters comprises: a) an organometallic compound obtained by reacting an orthoester or condensed orthoester of titanium, zirconium or aluminum, an alcohol containing at least two hydroxyl groups, a 2-hydroxy carboxylic acid and a base; and b) at least one compound comprising germanium, antimony or tin. Polyesters obtained by esterification reaction in the presence of the catalyst compositions according to the present invention exhibit improved melt properties and are particularly suitable for production of textile and commercial fibers, films and rigid packaging.
摘要翻译： 用于制备聚酯的催化剂组合物包括：a）通过钛，锆或铝的原酸酯或缩合原酸酯，含有至少两个羟基的醇，2-羟基羧酸和碱反应而获得的有机金属化合物; 和b）至少一种包含锗，锑或锡的化合物。 在根据本发明的催化剂组合物的存在下通过酯化反应获得的聚酯表现出改进的熔体性质，并且特别适用于生产纺织品和商业纤维，膜和刚性包装。
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公开(公告)号：US20100152477A1
公开(公告)日：2010-06-17
申请号：US12709109
申请日：2010-02-19
CPC分类号： B01J31/12 , B01J2231/42 , B01J2231/49 , B01J2531/42
摘要： Supported heterogeneous organotin catalysts of the formula X1, X2, or X3: wherein Z is a spacer group; Y is an insoluble phenyl-group containing copolymer; R1, R2, R3, R5, and R6 are independently selected from halogen, alkyl, alkylene, phenyl, vinyl, allyl, naphthyl, aralkyl, and Z; and R4 is alkyl, alkylene, phenyl, vinyl, allyl, naphthyl, or aralkyl.
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公开(公告)号：US20080275262A1
公开(公告)日：2008-11-06
申请号：US11596885
申请日：2005-05-18
IPC分类号： C07F7/22
CPC分类号： C07C68/06 , B01J31/0212 , B01J2531/42 , C07F7/2224 , C08G64/00 , C07C69/96
摘要： A process for the production of alkyltin alkoxides which comprises subjecting at least one alkyltin compound selected from among organotin compounds having tin-oxygen-tin linkages as the starting compound and a hydroxyl compound as the reactant to dehydration to obtain an alkyltin alkoxide corresponding to the starting compound and the reactant, characterized by continuously feeding the starting compound and the reactant into a reactor, discharging a water-containing low boiling point component from the reactor, and continuously withdrawing a reaction fluid containing an alkyltin alkoxide as the bottom from the reactor.
摘要翻译： 制备烷基锡醇盐的方法，其包括使选自具有锡 - 氧 - 锡键的有机锡化合物中的至少一种烷基锡化合物作为起始化合物和羟基化合物作为反应物进行脱水以获得对应于起始的烷基锡醇盐 化合物和反应物，其特征在于将起始化合物和反应物连续进料到反应器中，从反应器中排出含水低沸点组分，并从反应器中连续抽出含有烷基锡醇盐作为底部的反应流体。
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