Method of Producing Porous Metal-Carbon Materials
    2.
    发明申请
    Method of Producing Porous Metal-Carbon Materials 有权
    生产多孔金属碳材料的方法

    公开(公告)号:US20160190601A1

    公开(公告)日:2016-06-30

    申请号:US14825402

    申请日:2015-08-13

    申请人: Powermers Inc.

    摘要: A method for creating a metal-carbon composite. In one embodiment, the method includes the steps of providing a polymer Schiff base transition metal film precursor having a chemical structure of the formula [M(Schiff)]n and a recurring unit and a transition metal selected from the group consisting of nickel, palladium, platinum, cobalt, copper, iron; Schiff is a tetradentate Schiff base ligand selected from the group consisting of Salen (residue of bis(salicylaldehyde)-ethylenediamine), Saltmen (residue of bis(salicylaldehyde)-tetramethylethylenediamine, Salphen (residue of bis-(salicylaldehyde)-o-phenylenediamine), a substituent in a Schiff base is selected from the group consisting of H—, and carbon-containing substituents, preferably CH3—, C2H5—, CH3O—, C2H5O—, and Y is a bridge in a Schiff base depositing the polymer Schiff base transition metal precursor film onto a support substrate; and heating the polymer Schiff base transition metal precursor film and support substrate in a furnace in an inert atmosphere.

    摘要翻译: 一种制备金属 - 碳复合材料的方法。 在一个实施方案中,该方法包括以下步骤:提供具有式[M(Schiff)] n的化学结构的聚合物希夫碱过渡金属膜前体和重复单元和选自镍,钯 ,铂,钴,铜,铁; 席夫是选自Salen(双(水杨醛) - 乙二胺的残基),Saltmen(双(水杨醛) - 四甲基乙二胺的残基,Salphen(双 - (水杨醛) - 苯二胺的残基))的四齿席夫碱配位体, ,席夫碱中的取代基选自H-和含碳取代基,优选CH 3 - ,C 2 H 5 - ,CH 3 O-,C 2 H 5 O-,Y是在席夫碱中的桥,沉积聚合物席夫碱 过渡金属前体膜到支撑衬底上;以及将惰性气氛中的聚合物席夫碱过渡金属前体膜和支撑衬底加热到​​炉中。

    Active Grignard electrode
    7.
    发明授权
    Active Grignard electrode 失效
    主动格氏电极

    公开(公告)号:US4002548A

    公开(公告)日:1977-01-11

    申请号:US590836

    申请日:1975-06-27

    CPC分类号: C25B3/12

    摘要: The method of continuously monitoring the concentration of Grignard reactant in the "Freeport Process" cell for producing organolead compounds which comprises utilizing a reference half cell consisting of an electrode in anhydrous ether solution with a platinum group sample electrode in a solution of process Grignard reactant and adjusting upwardly the concentration of Grignard when it falls below a value of 0.02M. Also included in the invention are preferred reference half cells utilizing lead and zinc in anhydrous solvent selected from glycol diethers, such as diethylether of tetraethylene glycol (DETEG) and optionally tetrahydrofuran (THF) as a stripping solvent.

    摘要翻译: 在“自由口法”细胞中连续监测Grignard反应物浓度的方法,用于生产有机物化合物,其包括将由电极组成的参考半电池在无水乙醚溶液中与铂族样品电极在格氏试剂反应物和 当Grignard低于0.02M值时,向上调整Grignard的浓度。 本发明还包括优选的参考半电池,其使用选自乙二醇二醚的无水溶剂中的铅和锌,例如四乙二醇的二乙醚(DETEG)和任选的四氢呋喃(THF)作为汽提溶剂。

    Electro-chemical synthesis of organonickel compounds
    8.
    发明授权
    Electro-chemical synthesis of organonickel compounds 失效
    有机锡化合物的电化学合成

    公开(公告)号:US3887441A

    公开(公告)日:1975-06-03

    申请号:US36403173

    申请日:1973-05-25

    IPC分类号: C07F15/04 C25B3/12 C25B3/00

    CPC分类号: C25B3/12 C07F15/04

    摘要: A process for the synthesis of organonickel derivatives by electrochemical reduction of a nickel(II) complex followed by addition of a haloorganic compound which yields a different nickel(II) complex. The complexes have utility as catalysts for olefin dimerization.

    摘要翻译: 通过电化学还原镍(II)络合物然后加入产生不同镍(II)络合物的卤代有机化合物来合成有机镍衍生物的方法。 该配合物可用作烯烃二聚化的催化剂。

    Electrolytic formation of organometallic compounds
    10.
    发明授权
    Electrolytic formation of organometallic compounds 失效
    电化学形成有机化合物

    公开(公告)号:US3556960A

    公开(公告)日:1971-01-19

    申请号:US3556960D

    申请日:1968-01-24

    申请人: DOW CHEMICAL CO

    IPC分类号: C25B3/12 B01K1/00

    CPC分类号: C25B3/12

    摘要: A PROCESS FOR THE PREPARATION OF ORGANOMETALLIC COMPOUNDS COMPRISING CONTACTING AN ACTIVATED OLEFIN OR DIARYL-CONTAINING HYDROCARBON WITH AN ELECTRIC CURRENT IN THE PRESENCE OF AN ALKALI OR ALKALINE EARTH METAL SALT ELECTROLYTE, AND A TETRAALKYL SUBSTITUTED UREA, TETRAALKYL SUBSTITUTED THISOUREA, TETRAALKYL SUBSTITUTED SULFONAMIDE OR A HEXAALKYL OR ARYL SUBSTITUTED PHOSPHORAMIDE POLAR SOLVENT.