Oxygen-consuming chlor alkali cell configured to minimize peroxide formation
    24.
    发明授权
    Oxygen-consuming chlor alkali cell configured to minimize peroxide formation 失效
    耗氧氯碱池被配置为最小化过氧化物形成

    公开(公告)号:US07083708B2

    公开(公告)日:2006-08-01

    申请号:US10631073

    申请日:2003-07-31

    IPC分类号: C25B9/10

    摘要: Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth. When the cathode was positioned against the cation exchange membrane with the catalyst side away from the membrane, electrolysis of sodium chloride to chlorine and caustic (sodium hydroxide) proceeded with minimal peroxide formation.

    摘要翻译: 耗氧的零间隙氯碱电池被配置成使过氧化物形成最小化。 电池包括将电池分成包括阳极的阳极室和包括氧气扩散阴极的阴极室的离子交换膜。 阴极包括单片导电石墨化碳布。 催化剂和聚四氟乙烯仅附着在布的一侧。 当阴极靠近阳离子交换膜而使催化剂侧远离膜时,氯化钠电解为氯和苛性碱(氢氧化钠)进行了最小的过氧化物形成。

    Oxygen-consuming chlor alkali cell configured to minimize peroxide formation
    25.
    发明申请
    Oxygen-consuming chlor alkali cell configured to minimize peroxide formation 失效
    耗氧氯碱池被配置成使过氧化物形成最小化

    公开(公告)号:US20050026005A1

    公开(公告)日:2005-02-03

    申请号:US10631073

    申请日:2003-07-31

    摘要: Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth. When the cathode was positioned against the cation exchange membrane with the catalyst side away from the membrane, electrolysis of sodium chloride to chlorine and caustic (sodium hydroxide) proceeded with minimal peroxide formation.

    摘要翻译: 耗氧的零间隙氯碱电池被配置成使过氧化物形成最小化。 电池包括将电池分成包括阳极的阳极室和包括氧气扩散阴极的阴极室的离子交换膜。 阴极包括单片导电石墨化碳布。 催化剂和聚四氟乙烯仅附着在布的一侧。 当阴极靠近阳离子交换膜而使催化剂侧远离膜时,氯化钠电解为氯和苛性碱(氢氧化钠)进行了最小的过氧化物形成。

    Conducting polymer for high power ultracapacitor
    26.
    发明授权
    Conducting polymer for high power ultracapacitor 失效
    高功率超级电容器用导电聚合物

    公开(公告)号:US06383640B1

    公开(公告)日:2002-05-07

    申请号:US09653615

    申请日:2000-08-31

    IPC分类号: B32B900

    摘要: In accordance with the purposes of the present invention, as embodied and broadly described herein, the present invention is directed to an electrode having a conducting polymer active material for use in an ultracapacitor. The conducting polymer active material is electropolymerized onto a carbon paper substrate from a mixed solution of a dimer of (3,3′ bithiophene) (BT) and a monomer that is selected from the group of thiophenes derived in the 3-position, having an aryl group attached to thiophene in the 3-position or having aryl and alkly groups independently attached to thiophene in the 3 and 4 positions.

    摘要翻译: 根据本发明的目的,如本文所体现和广泛描述的,本发明涉及一种具有用于超级电容器的导电聚合物活性材料的电极。 将导电聚合物活性材料从(3,3'二噻吩)(BT)的二聚体和选自3-位衍生的噻吩类的单体的混合溶液中电聚合到碳纸基材上,具有 在3-位上连接到噻吩上的芳基或在3和4位独立地连接到噻吩上的芳基和烷基。

    Catalyzed enzyme electrodes
    27.
    发明授权
    Catalyzed enzyme electrodes 失效
    催化酶电极

    公开(公告)号:US5227042A

    公开(公告)日:1993-07-13

    申请号:US883746

    申请日:1992-05-15

    IPC分类号: C12Q1/00

    摘要: An enzyme electrode is prepared with a composite coating on an electrical conductor. The composite coating is formed from a casting solution of a perfluorosulfonic acid polymer, an enzyme, and a carbon supported catalyst. The solution may be cast directly on the conductor surface or may be formed as a membrane and applied to the surface. The perfluorosulfonic acid ionomer formed from the casting solution provides an insoluble biocompatible protective matrix for the enzyme and acts to retain the enzyme for long term availability in the electrode structure. The carbon supported catalyst provides catalytic sites throughout the layer for the oxidation of hydrogen peroxide from the enzyme reactions. The carbon support then provides a conductive path for establishing an electrical signal to the electrical conductor. In one embodiment, the electrical conductor is a carbon cloth that permits oxygen or other gas to be introduced to the perfluorosulfonic polymer to promote the enzyme reaction independent of oxygen in the solution being tested.

    摘要翻译: 用电导体上的复合涂层制备酶电极。 复合涂层由全氟磺酸聚合物,酶和负载碳的催化剂的流延溶液形成。 溶液可以直接浇铸在导体表面上,或者可以形成为膜并施加到表面上。 由浇铸溶液形成的全氟磺酸离聚物为酶提供了不溶的生物相容性保护基质,并且用于保留酶在电极结构中的长期可利用性。 碳载体催化剂在整个层中提供催化位点,用于从酶反应中氧化过氧化氢。 碳载体然后提供用于向电导体建立电信号的导电路径。 在一个实施方案中,电导体是碳布,其允许将氧气或其它气体引入全氟磺酸聚合物以促进酶反应,而与所测溶液中的氧无关。