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    Process for preparring linear alpha olefins
    21.
    发明申请
    Process for preparring linear alpha olefins 失效
    制备直链α-烯烃的方法

    公开(公告)号：US20060014989A1

    公开(公告)日：2006-01-19

    申请号：US11179459

    申请日：2005-07-12

    申请人： Eric Johannes De Boer ,  Harry Van Der Heijden ,  Inge Oosterveld ,  Arie Van Zon

    发明人： Eric Johannes De Boer ,  Harry Van Der Heijden ,  Inge Oosterveld ,  Arie Van Zon

    IPC分类号： C07C2/00

    CPC分类号： C07C2/08 ,  C07C1/327 ,  C07C5/2575 ,  C07C2523/755 ,  C07C2527/128 ,  C07C2531/14 ,  C07C11/02

    摘要： A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i) reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin; and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.

    摘要翻译： 制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下二聚具有n个碳原子的直链α-烯烃以产生线性内烯烃 具有2n个碳原子; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化， 从所述三烷基铝化合物置换烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是由所述直链内烯烃的异构化衍生的直链烷基; 和（b）（ii）任选地在置换催化剂存在下使所述烷基铝化合物与α-烯烃反应，以使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

    Process for producing linear alpha olefins
    22.
    发明申请
    Process for producing linear alpha olefins 审中-公开
    生产线性α-烯烃的方法

    公开(公告)号：US20050014983A1

    公开(公告)日：2005-01-20

    申请号：US10883600

    申请日：2004-07-01

    申请人： Eric De Boer ,  Harry Van Der Heijden ,  Eric Kragtwijk ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    发明人： Eric De Boer ,  Harry Van Der Heijden ,  Eric Kragtwijk ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    IPC分类号： B01J31/12 ,  B01J31/14 ,  B01J31/18 ,  C07C2/32 ,  C08F4/70 ,  C08F10/00 ,  C07C2/26 ,  B01J31/00

    CPC分类号： C07C2/32 ,  B01J31/143 ,  B01J31/1815 ,  B01J2231/20 ,  B01J2531/842 ,  B01J2531/845 ,  C07C2531/14 ,  C08F10/00 ,  C08F4/7042

    摘要： A process for the production of alpha-olefins comprising reacting ethylene under oligomerization conditions in the presence of a mixture comprising: (a) a metal salt based on Fe(II), Fe(III), Co(II) or Co(III); (b) a pyridine bis-imine ligand; and (c) a co-catalyst which is the reaction product of water with one or more organometallic aluminium compounds, wherein the one or more organometallic aluminium compounds is selected from: (i) βδ-branched compounds of formula (I): Al(CH2—CR1R2—CH2—CR4R5R6)xR3yHz; (ii) βγ-branched compounds of formula (II) Al(CH2—CR1R2—CR4R5R6)xR3yHz and mixtures thereof; wherein when the metal salt and the bis-arylimine pyridine ligand are mixed together they are soluble in aliphatic or aromatic hydrocarbon solvent.

    摘要翻译： 一种制备α-烯烃的方法，包括在低聚条件下，在混合物存在下使乙烯反应，所述混合物包含：（a）基于Fe（II），Fe（III），Co（II）或Co（III）的金属盐， ; （b）吡啶双亚胺配体; 和（c）作为水与一种或多种有机金属铝化合物的反应产物的助催化剂，其中所述一种或多种有机金属铝化合物选自：（i）式（I）的betadelta支化化合物：Al CH2-CR 1 R 2 -CH2-CR 4 R 5 R 6）xR 3Hz; （ⅱ）式（Ⅱ）bet ma ma ma branched branched branched）Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz Hz;;;;;;;;;;;;;; 其中当将金属盐和双芳基亚胺吡啶配体混合在一起时，它们可溶于脂族或芳族烃溶剂。

    Catalytic trimerization and tetramerization of olefinic monomers
    24.
    发明申请
    Catalytic trimerization and tetramerization of olefinic monomers 有权

    公开(公告)号：US20060235250A1

    公开(公告)日：2006-10-19

    申请号：US11398777

    申请日：2006-04-06

    申请人： Eric Johannes De Boer ,  Harry Van Der Heijden ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    发明人： Eric Johannes De Boer ,  Harry Van Der Heijden ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    IPC分类号： B01J31/00

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/10 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/02 ,  C07C11/107

    摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I); (R1)(R2)P—X—P(R3)(R4)   (I) wherein X is a bivalent organic bridging group; R1 and R3 are independently selected from, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, with the proviso that when R1 and R3 are aromatic groups they do not contain a polar substituent at any of the ortho-positions; R2 and R4 are independently selected from optionally substituted aromatic groups, each R2 and R4 bearing a polar substituent on at least one of the ortho-positions; and c) a second ligand having the general formula (II); (R1′)(R2′)P—X′—P(R3′)(R4′)   (II) wherein X′ is a bridging group of the formula —N(R5′)—, wherein R5′ is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; and R1′, R2′, R3′ and R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups of which at least one of R1′, R2′, R3′ and R4′ is substituted with a polar substituent, or R1′, R2′, R3′ and R4′ are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups, wherein any substituents on one or more of R1′, R2′, R3′ and R4′ are non-polar. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.

    CATALYTIC TRIMERIZATION AND TETRAMERIZATION OF OLEFINIC MONOMERS
    27.
    发明申请
    CATALYTIC TRIMERIZATION AND TETRAMERIZATION OF OLEFINIC MONOMERS 失效
    烯烃单体的催化三聚和四聚体

    公开(公告)号：US20070299290A1

    公开(公告)日：2007-12-27

    申请号：US11770520

    申请日：2007-06-28

    申请人： Eric De Boer ,  Harry Van Der Heijden ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    发明人： Eric De Boer ,  Harry Van Der Heijden ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    IPC分类号： C07C2/08 ,  B01J31/00

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J31/2409 ,  B01J2231/20 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2540/10 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/02 ,  C07C11/107

    摘要： A catalyst precursor composition comprising a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I): (R1)(R2)P—X—P(R3)(R4)  (I) where X is a bivalent organic bridging group, R1 and R3 are hydrocarbyl groups, and R2 and R4 are aromatic groups; and c) a second ligand having the general formula (II): (R1′)(R2′)P—X′—P(R3′)(R4′)  (II) where X′ is a bridging group containing nitrogen and R1′, R2″, R3′ and R4′ are hydrocarbyl groups. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst.

    摘要翻译： 一种催化剂前体组合物，其包含a）铬，钼或钨的源; b）具有通式（I）的第一配体：<？in-line-formula description =“In-line formula”end =“lead”？>（R 1 SUP） （2）PXP（R 3）（R 4）（I）<βin-line-formula description =“In-line Formulas”end = “尾”→>其中X是二价有机桥基，R 1和R 3是烃基，R 2和R 2， SUP> 4是芳基; 和（c）具有通式（II）的第二配位体：<？in-line-formula description =“In-line formula”end =“lead”→（R 1> （二）'P-X'-P（R 3'）（R 4'）（II）<β在线式 描述=“在线公式”end =“tail”？>其中X'是含有氮和R 1'的桥连基团，R 2“，R” SUP 3'和R 4'是烃基。 本发明还涉及包含本发明的催化剂前体组合物和助催化剂的催化剂体系。

    CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS
    28.
    发明申请
    CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
    烯烃单体低级化的催化方法

    公开(公告)号：US20070185357A1

    公开(公告)日：2007-08-09

    申请号：US11561816

    申请日：2006-11-20

    申请人： Eric De Boer ,  Harry Van Der Heijden ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    发明人： Eric De Boer ,  Harry Van Der Heijden ,  Quoc On ,  Johan Smit ,  Arie Van Zon

    IPC分类号： C07C2/34 ,  C07C2/26

    CPC分类号： B01J31/188 ,  B01J31/143 ,  B01J2531/62 ,  B01J2531/64 ,  B01J2531/66 ,  C07C2/36 ,  C07C2531/24 ,  C07F9/46

    摘要： A process for the simultaneous trimerization and tetramerization of olefinic monomers, wherein the process comprises contacting at least one olefinic monomer with a catalyst system comprising: a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I); (R1)2P-X-P(R1)m(R2)n  (I) wherein: X is a bridging group of the formula —N(R3)—; the R1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and c) a cocatalyst.

    摘要翻译： 烯烃单体的同时三聚和四聚的方法，其中所述方法包括使至少一种烯属单体与催化剂体系接触，所述催化剂体系包括：a）铬，钼或钨的来源; b）具有通式（I）的配体; <？in-line-formula description =“In-line Formulas”end =“lead”？>（R＆lt; 1＆gt;）2 PXP（R＆lt; 1＆ （I）（I）<？in-line-formula description =“In-line Formulas”end = “尾”→其中：X是式-N（R 3 O 3） - 的桥基; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R“2”独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，它在任何邻位不含极性取代基; 和c）助催化剂。