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公开(公告)号:US06746800B1
公开(公告)日:2004-06-08
申请号:US09914653
申请日:2001-08-31
IPC分类号: H01L458
CPC分类号: H01M10/0525 , H01M4/131 , H01M4/133 , H01M4/1391 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/058 , H01M2004/021
摘要: A nonaqueous electrolyte secondary battery characterized as using a mixture of a first oxide and a second oxide for its positive electrode material. The first oxide is a spinel oxide consisting substantially of lithium, manganese, a metal other than manganese, and oxygen. The second oxide is different in composition from the first oxide and consists substantially of lithium, nickel, cobalt, a metal other than nickel and cobalt, and oxygen.
摘要翻译: 特征在于使用第一氧化物和第二氧化物的混合物作为其正极材料的非水电解质二次电池。 第一氧化物是基本上由锂,锰,除锰以外的金属和氧组成的尖晶石氧化物。 第二氧化物的组成与第一氧化物不同,并且基本上由锂,镍,钴,除了镍和钴以外的金属以及氧组成。
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公开(公告)号:US06444369B1
公开(公告)日:2002-09-03
申请号:US09720094
申请日:2000-12-21
申请人: Maruo Kamino , Ryuji Ohshita , Hiroshi Nakajima , Makoto Uesugi , Toshiyuki Nohma , Koji Nishio
发明人: Maruo Kamino , Ryuji Ohshita , Hiroshi Nakajima , Makoto Uesugi , Toshiyuki Nohma , Koji Nishio
IPC分类号: H01M614
CPC分类号: H01M4/505 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2300/0085
摘要: The battery of this invention includes a positive electrode including a gelled polymeric electrolyte (A) and using spinel type lithium manganese oxide as an active material; a negative electrode; a gelled polymeric electrolyte (B) in the shape of a film or sheet also serving as a separator, and both the gelled polymeric electrolyte (A) and the gelled polymeric electrolyte (B) are made from a polymer of poly(alkylene oxide) series impregnated with a liquid electrolyte. Since the battery includes the positive electrode using the specific gelled polymeric electrolyte (A), a contact area between the positive electrode active material and the gelled polymeric electrolyte is large, so as to attain large initial discharge capacity (at high rate discharge in particular). Also, since the battery includes the specific gelled polymeric electrolyte (B) as the electrolyte, manganese included in the spinel type lithium manganese oxide is minimally eluted, and hence, the discharge capacity is minimally degraded during charge-discharge cycles due to elution of manganese, resulting in attaining good charge-discharge cycle performance.
摘要翻译: 本发明的电池包括含有胶凝聚合物电解质(A)和使用尖晶石型锂锰氧化物作为活性材料的正电极; 负极; 胶状聚合物电解质(B)为薄膜或片材形状,也用作隔膜,凝胶状高分子电解质(A)和凝胶状聚合物电解质(B)均由聚(环氧烷)系列 用液体电解质浸渍。 由于电池包括使用特定凝胶状高分子电解质(A)的正极,所以正极活性物质与凝胶状聚合物电解质之间的接触面积大,以达到大的初始放电容量(特别是高倍率放电) 。 此外,由于电池包含作为电解质的特定凝胶状聚合物电解质(B),所以尖晶石型锂锰氧化物中所含的锰被最小程度地洗脱,因此在充放电循环中由于锰的洗脱而导致的放电容量最小化 ,从而获得良好的充放电循环性能。
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公开(公告)号:US20050008939A1
公开(公告)日:2005-01-13
申请号:US10915601
申请日:2004-08-11
申请人: Taeko Ota , Ryuji Ohshita , Maruo Kamino
发明人: Taeko Ota , Ryuji Ohshita , Maruo Kamino
IPC分类号: H01M4/66 , H01M4/134 , H01M4/38 , H01M4/40 , H01M4/70 , H01M6/16 , H01M10/05 , H01M10/0566 , H01M10/40
CPC分类号: H01M4/0438 , H01M4/0404 , H01M4/0419 , H01M4/0423 , H01M4/0426 , H01M4/0428 , H01M4/0452 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/386 , H01M4/661 , H01M4/70 , H01M10/052 , H01M10/0567 , H01M2004/021 , H01M2300/0025
摘要: A lithium secondary battery comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the positive electrode or the negative electrode is an electrode obtained by depositing a thin film of active material capable of lithium storage and release on a current collector, the thin film is divided into columns by gaps formed therein in a manner to extend in its thickness direction and the columnar portions are adhered at their bottoms to the current collector, and the nonaqueous electrolyte contains at least one selected from phosphate ester, phosphite ester, borate ester and carboxylic ester having a fluoroalkyl group.
摘要翻译: 一种锂二次电池,其包含正极,负极和非水电解质,其中所述正极或负极是通过在集电体上沉积能够锂储存和释放的活性材料的薄膜而获得的电极, 薄膜通过在其厚度方向上延伸形成的间隙被分成列,柱状部分在其底部附着到集电体上,非水电解质含有选自磷酸酯,亚磷酸酯,硼酸酯中的至少一种 具有氟代烷基的酯和羧酸酯。
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公开(公告)号:US06800400B2
公开(公告)日:2004-10-05
申请号:US10124727
申请日:2002-04-18
申请人: Taeko Ota , Ryuji Ohshita , Maruo Kamino
发明人: Taeko Ota , Ryuji Ohshita , Maruo Kamino
IPC分类号: H01M616
CPC分类号: H01M4/0438 , H01M4/0404 , H01M4/0419 , H01M4/0423 , H01M4/0426 , H01M4/0428 , H01M4/0452 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M4/386 , H01M4/661 , H01M4/70 , H01M10/052 , H01M10/0567 , H01M2004/021 , H01M2300/0025
摘要: A lithium secondary battery comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein the positive electrode or the negative electrode is an electrode obtained by depositing a thin film of active material capable of lithium storage and release on a current collector, the thin film is divided into columns by gaps formed therein in a manner to extend in its thickness direction and the columnar portions are adhered at their bottoms to the current collector, and the nonaqueous electrolyte contains at least one selected from phosphate ester, phosphite ester, borate ester and carboxylic ester having a fluoroalkyl group.
摘要翻译: 一种锂二次电池,其包含正极,负极和非水电解质,其中所述正极或负极是通过在集电体上沉积能够锂储存和释放的活性材料的薄膜而获得的电极, 薄膜通过在其厚度方向上延伸形成的间隙被分成列,柱状部分在其底部附着到集电体上,非水电解质含有选自磷酸酯,亚磷酸酯,硼酸酯中的至少一种 具有氟代烷基的酯和羧酸酯。
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公开(公告)号:US09935339B2
公开(公告)日:2018-04-03
申请号:US13993965
申请日:2011-12-16
申请人: Satoshi Yoshida , Eiji Okutani , Hideyuki Inomata , Ryuji Ohshita
发明人: Satoshi Yoshida , Eiji Okutani , Hideyuki Inomata , Ryuji Ohshita
IPC分类号: H01M10/0587 , H01M2/22 , H01M2/34 , H01M2/26
CPC分类号: H01M10/0587 , H01M2/22 , H01M2/263 , H01M2/34
摘要: [Problem] To provide a rectangular nonaqueous electrolyte secondary battery for which the generation of a magnetic field due to current during use is suppressed and the danger of internal shorts between the positive electrode tab and negative electrode tab is reduced. [Solution] The positive electrode tab and negative electrode tab are both disposed at the beginning side of a winding for wound electrodes. An outer housing and sealing plate are welded in a state with the positive electrode tab sandwiched at a mating part of the outer housing and sealing plate. The negative electrode tab is electrically connected to a negative electrode terminal provided on the sealing plate. The positive electrode tab and negative electrode tab are divided by a space of 2-12 mm in the direction of battery width.
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公开(公告)号:US20130260203A1
公开(公告)日:2013-10-03
申请号:US13993965
申请日:2011-12-16
申请人: Satoshi Yoshida , Eiji Okutani , Hideyuki Inomata , Ryuji Ohshita
发明人: Satoshi Yoshida , Eiji Okutani , Hideyuki Inomata , Ryuji Ohshita
IPC分类号: H01M10/0587
CPC分类号: H01M10/0587 , H01M2/22 , H01M2/263 , H01M2/34
摘要: [Problem] To provide a rectangular nonaqueous electrolyte secondary battery for which the generation of a magnetic field due to current during use is suppressed and the danger of internal shorts between the positive electrode tab and negative electrode tab is reduced. [Solution] The positive electrode tab and negative electrode tab are both disposed at the beginning side of a winding for wound electrodes. An outer housing and sealing plate are welded in a state with the positive electrode tab sandwiched at a mating part of the outer housing and sealing plate. The negative electrode tab is electrically connected to a negative electrode terminal provided on the sealing plate. The positive electrode tab and negative electrode tab are divided by a space of 2-12 mm in the direction of battery width.
摘要翻译: [问题]提供一种矩形非水电解质二次电池,其在使用期间由于电流产生磁场而被抑制,并且正极片和负电极片之间的内部短路的危险降低。 [解决方案]正电极片和负电极片均设置在用于缠绕电极的绕组的起始侧。 在外壳和密封板的外壳和密封板的配合部分处于正电极片的状态下焊接外壳和密封板。 负极接线片电连接到设置在密封板上的负极端子。 正电极片和负电极片沿电池宽度方向分隔2-12mm的空间。
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公开(公告)号:US20110212362A1
公开(公告)日:2011-09-01
申请号:US13035311
申请日:2011-02-25
IPC分类号: H01M10/056
CPC分类号: H01M2/1653 , H01M2/145 , H01M4/131 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/4235 , H01M2300/0037
摘要: The object of the present invention is to provide a non-aqueous electrolyte secondary cell that excels in safety against overcharging and shows only a small increase in thickness during continuous charge. This object can be achieved by adopting the following configuration: a separator is used that is made of a microporous polyolefin membrane having an average pore diameter of 0.07 to 0.09 μm; a non-aqueous electrolyte contains 0.5 to 3.0 mass % of 1,3-dioxane, 0.05 to 0.3 mass % of adiponitrile, and 0.5 to 3.0 mass % of cyclohexylbenzene and/or tert-amylbenzene relative to the mass of the non-aqueous electrolyte; and preferably the non-aqueous electrolyte further contains 0.5 to 5.0 mass % of a vinylene carbonate and 0.1 to 2.0 mass % of 2-propyn-1-yl 2-(methylsulfonyloxy) propionate.
摘要翻译: 本发明的目的是提供一种在过充电时安全性优异的非水电解质二次电池,并且在连续充电期间仅显示出小的厚度增加。 该目的可以通过以下结构实现:使用由平均孔径为0.07〜0.09μm的微孔聚烯烃膜制成的隔膜; 相对于非水电解质的质量,非水电解质含有0.5〜3.0质量%的1,3-二恶烷,0.05〜0.3质量%的己二腈,0.5〜3.0质量%的环己基苯和/或叔戊基苯 ; 优选非水电解质还含有0.5〜5.0质量%的碳酸亚乙烯酯和0.1〜2.0质量%的2-丙炔-1-基甲基磺酰氧基丙酸酯。
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公开(公告)号:US07368203B2
公开(公告)日:2008-05-06
申请号:US10670384
申请日:2003-09-26
CPC分类号: H01M4/131 , H01M4/13 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/4235 , H01M2004/021 , Y02E60/122
摘要: The present invention provides a non-aqueous electrolyte secondary cell that has good high-temperature cycle characteristics and good high-temperature standing resistance, and that is highly safe enough to prevent overcharge. The non-aqueous electrolyte secondary cell of the invention utilizes a non-aqueous electrolyte that includes a vinylene carbonate derivative, a cyclic sulfite derivative, and both/either of a phenylcycloalkane derivative and/or an alkylbenzene derivative having a quaternary carbon directly bonded to a benzene ring.
摘要翻译: 本发明提供一种非水电解质二次电池,其具有良好的高温循环特性和良好的耐高温稳定性,并且足够高以防止过充电。 本发明的非水电解质二次电池使用非水电解质,其包括碳酸亚乙烯酯衍生物,环状亚硫酸酯衍生物,和苯基环烷烃衍生物和/或具有与碳直接键合的季碳的烷基苯衍生物 苯环。
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公开(公告)号:US07704640B2
公开(公告)日:2010-04-27
申请号:US11362225
申请日:2006-02-27
申请人: Keisuke Ooga , Masato Iwanaga , Hideyuki Inomata , Ryuji Ohshita
发明人: Keisuke Ooga , Masato Iwanaga , Hideyuki Inomata , Ryuji Ohshita
IPC分类号: H01M4/58
CPC分类号: H01M10/4235 , H01M4/1391 , H01M10/0567 , H01M2004/021 , H01M2004/028
摘要: A non-aqueous electrolyte secondary cell excellent in cycle characteristics is provided. This purpose is achieved by the following structure. A non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a non-aqueous electrolyte having a non-aqueous solvent and an electrolytic salt. The positive electrode active material has a lithium-cobalt compound oxide having added therein at least zirconium. The non-aqueous electrolyte has LiBF4 at from 0.05 to 1.0 mass % of a total mass of the non-aqueous electrolyte and unsaturated cyclic carbonate at from 1.0 to 4.0 mass %. The true density ratio of the positive electrode is 0.72 or greater, the true density ratio being represented by formula 1 shown below: (Formula 1) True density ratio=active material apparent density of electrode active material layer÷true density of active material.
摘要翻译: 提供循环特性优异的非水电解质二次电池。 该目的通过以下结构实现。 非水电解质二次电池具有具有正极活性物质的正极,具有负极活性物质的负极和具有非水溶剂和电解质盐的非水电解质。 正极活性物质具有至少添加有锆的锂 - 钴复合氧化物。 非水电解质的LiBF 4的含量为0.05〜1.0质量%,非水电解质和不饱和环状碳酸酯的总质量为1.0〜4.0质量%。 正极的真密度比为0.72以上,真密度比由下式1表示:(式1)真密度比=活性物质活性物质表观密度÷活性物质的真密度。
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公开(公告)号:US07476469B2
公开(公告)日:2009-01-13
申请号:US10451846
申请日:2002-01-17
申请人: Taeko Ota , Hiroyuki Fujimoto , Ryuji Ohshita , Maruo Kamino
发明人: Taeko Ota , Hiroyuki Fujimoto , Ryuji Ohshita , Maruo Kamino
CPC分类号: H01M4/13 , H01M4/0402 , H01M4/0404 , H01M4/0419 , H01M4/0421 , H01M4/0426 , H01M4/0428 , H01M4/0483 , H01M4/131 , H01M4/139 , H01M4/386 , H01M4/64 , H01M4/66 , H01M4/661 , H01M4/669 , H01M10/052 , H01M10/0569 , H01M2004/025 , H01M2300/0037 , H01M2300/004
摘要: A rechargeable lithium battery including a positive electrode, a negative electrode and a nonaqueous electrolyte, said positive or negative electrode being an electrode which has, on a current collector, a thin film of active material that stores and releases lithium, the thin film of active material being divided into columns by gaps formed therein in a manner to extend in its thickness direction, and the columnar portions being at their bottoms adhered to the current collector, the rechargeable lithium battery being characterized in that the nonaqueous electrolyte includes a mixed solvent consisting of two or more different solvents and containing at least ethylene carbonate and/or vinylene carbonate as its constituent.
摘要翻译: 一种包括正极,负极和非水电解质的可再充电锂电池,所述正极或负极是在集电体上具有储存和释放锂的活性材料薄膜的电极,所述活性薄膜 材料通过在其厚度方向上延伸的方式被形成在其中的间隙分成列,并且柱状部分在其底部附着在集电器上,可再充电锂电池的特征在于非水电解质包括由 两种或更多种不同的溶剂,并且至少含有碳酸亚乙酯和/或碳酸亚乙烯酯作为其成分。
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