Method for the removal of acetylenes from olefins using ionic liquid-based solution
    22.
    发明授权
    Method for the removal of acetylenes from olefins using ionic liquid-based solution 有权
    使用离子液体溶液从烯烃中除去乙炔的方法

    公开(公告)号:US08110716B2

    公开(公告)日:2012-02-07

    申请号:US12250143

    申请日:2008-10-13

    IPC分类号: C07C7/148

    摘要: The present invention relates to a process for removing acetylenes from olefins by using an ionic liquid-based solution, and particularly to a process for removing a small amount of acetylenes contained in olefins by using an ionic liquid-based solution where copper halide (CuX, X=halogen atom) is dissolved. In an ionic liquid-based solution used in the present invention, copper halide (CuX) is stabilized by ionic liquid, thus preventing monovalent copper ion (Cu+) from being oxidized into divalent copper ion (Cu2+), maintaining the superior activity of monovalent copper ion (Cu+) in removing acetylene for a long period of time, and remarkably increasing the selective removal of acetylene-based compounds. Moreover, an ionic liquid-based solution used in the present invention may serve as an extracting solution as well as an absorbent, thereby facilitating the operation and reducing equipment cost in comparison to the conventional extracting agent used in a slurry phase.

    摘要翻译: 本发明涉及通过使用离子型液体溶液从烯烃中除去炔烃的方法,特别涉及通过使用离子液体基溶液除去烯烃中所含的少量乙炔的方法,其中卤化铜(CuX, X =卤素原子)溶解。 在本发明中使用的离子型液体溶液中,通过离子液体使卤化铜(CuX)稳定化,防止了一价铜离子(Cu +)被氧化为二价铜离子(Cu 2+),保持了一价铜的优异活性 离子(Cu +)长时间除去乙炔,显着增加乙炔类化合物的选择性去除。 此外,本发明中使用的离子性液体溶液可以用作提取溶液和吸收剂,从而与浆料相中使用的常规萃取剂相比,有助于操作和降低设备成本。

    PREPARATION METHOD FOR CELLULOSE PHOSPHITE COMPOUNDS
    23.
    发明申请
    PREPARATION METHOD FOR CELLULOSE PHOSPHITE COMPOUNDS 审中-公开
    纤维素磷酸盐化合物的制备方法

    公开(公告)号:US20110196139A1

    公开(公告)日:2011-08-11

    申请号:US12909475

    申请日:2010-10-21

    IPC分类号: C07H1/02

    CPC分类号: C08B5/00 C08B1/003

    摘要: Provided is a method for preparing a cellulose phosphite compound, more particularly a method for preparing a cellulose phosphite compound whereby cellulose is phosphorylated using an ionic liquid comprising an amine-based cation and a phosphite-based anion.Thus prepared cellulose phosphite compound has a good solubility in water and is highly valuable as concentration control agent, medicine, biomembrane, or the like.

    摘要翻译: 提供一种制备亚磷酸纤维素化合物的方法,更具体地说,涉及使用包含胺类阳离子和亚磷酸盐类阴离子的离子液体使纤维素磷酸化的亚磷酸纤维素化合物的制造方法。 如此制备的亚磷酸纤维素化合物在水中的溶解度好,作为浓度调节剂,药物,生物膜等是非常有价值的。

    Method of Purifying Olefins Using Pyrrolidinium-Based or Piperidinium-Based Ionic Liquids Comprising Copper (I) Halide
    25.
    发明申请
    Method of Purifying Olefins Using Pyrrolidinium-Based or Piperidinium-Based Ionic Liquids Comprising Copper (I) Halide 有权
    使用包含铜(I)卤化物的基于吡咯烷鎓或铱基离子液体来净化烯烃的方法

    公开(公告)号:US20110092758A1

    公开(公告)日:2011-04-21

    申请号:US12698615

    申请日:2010-02-02

    IPC分类号: C07C7/148 C09K3/00

    摘要: The present invention relates to a method of purifying olefin, the method comprising removing a small amount of acetylenic compounds contained in olefin by using pyrrolidinium-based or piperidinium-based ionic liquid mixtures comprising copper (I) halide. According to the method of the present invention, copper (I) halide is stabilized by pyrrolidinium-based or piperidinium-based ionic liquids, suppressing the oxidation of Cu(I) into Cu(II), whereby the capacity of removing acetylenic compounds can be maintained for a long time and the selective removal rate of acetylenic compounds to olefin can be significantly improved. In addition, since the ionic liquid mixtures comprising copper (I) halide used in the method of the present invention can be applied to both absorption and extraction processes, it can effectively remove acetylenic compounds from olefin in a more simple and economical way compared to the existing adsorption and membrane separation processes.

    摘要翻译: 本发明涉及一种纯化烯烃的方法,该方法包括通过使用包含卤化铜(I)的吡咯烷鎓基或哌啶鎓基离子液体混合物除去少量烯烃中所含的炔属化合物。 根据本发明的方法,通过吡咯烷鎓基或哌啶鎓离子液体来稳定卤化铜(I),抑制Cu(I)氧化为Cu(II),从而除去炔属化合物的能力可以为 维持了很长时间,可以显着提高炔属化合物对烯烃的选择性去除率。 此外,由于在本发明方法中使用的包含卤化铜(I)的离子液体混合物可以同时应用于吸收和萃取过程中,所以它可以以比较简单和经济的方式从烯烃中有效地除去炔属化合物 现有的吸附和膜分离过程。

    Facilitated transport membranes comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure
    26.
    发明授权
    Facilitated transport membranes comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure 失效
    便利的运输膜包括多孔载体和由过渡金属盐和具有邻苯二甲酸结构的聚合物组成的固体聚合物电解质

    公开(公告)号:US07179321B2

    公开(公告)日:2007-02-20

    申请号:US10822258

    申请日:2004-04-09

    IPC分类号: B01D53/22

    摘要: The present invention relates to a facilitated transport membrane for separation of alkene hydrocarbons from hydrocarbon mixtures, comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure, in which the electrolyte is in solid state at its operating temperature. The facilitated transport membrane is prepared by forming a solid polymer electrolyte consisting of a transition metal salt and a polymer on a porous support. The transition metal salt can selectively and reversibly form a complex with alkene hydrocarbons and the polymer can dissociate the transition metal salt. In particular, the polymer matrix allows the transition metal salt to be well dissociated because it has a phthalic structure capable of being coordinated to a transition metal ion.

    摘要翻译: 本发明涉及用于从烃混合物中分离烯烃的促进的输送膜,包括多孔载体和由过渡金属盐和具有邻苯二甲酸结构的聚合物组成的固体聚合物电解质,其中电解质在其固态 工作温度 通过在多孔载体上形成由过渡金属盐和聚合物组成的固体聚合物电解质来制备便利的输送膜。 过渡金属盐可以选择性地和可逆地与烯烃形成络合物,聚合物可以离解过渡金属盐。 特别地,聚合物基质允许过渡金属盐被很好的解离,因为它具有能与过渡金属离子配位的邻苯二甲酸结构。

    Method of purifying olefins using pyrrolidinium-based or piperidinium-based ionic liquids comprising copper (I) halide
    28.
    发明授权
    Method of purifying olefins using pyrrolidinium-based or piperidinium-based ionic liquids comprising copper (I) halide 有权
    使用包含卤化铜(I)的吡咯烷鎓基或哌啶鎓基离子液体来纯化烯烃的方法

    公开(公告)号:US08143470B2

    公开(公告)日:2012-03-27

    申请号:US12698615

    申请日:2010-02-02

    IPC分类号: C07C7/156

    摘要: The present invention relates to a method of purifying olefin, the method comprising removing a small amount of acetylenic compounds contained in olefin by using pyrrolidinium-based or piperidinium-based ionic liquid mixtures comprising copper (I) halide. According to the method of the present invention, copper (I) halide is stabilized by pyrrolidinium-based or piperidinium-based ionic liquids, suppressing the oxidation of Cu(I) into Cu(II), whereby the capacity of removing acetylenic compounds can be maintained for a long time and the selective removal rate of acetylenic compounds to olefin can be significantly improved. In addition, since the ionic liquid mixtures comprising copper (I) halide used in the method of the present invention can be applied to both absorption and extraction processes, it can effectively remove acetylenic compounds from olefin in a more simple and economical way compared to the existing adsorption and membrane separation processes.

    摘要翻译: 本发明涉及一种纯化烯烃的方法,该方法包括通过使用包含卤化铜(I)的吡咯烷鎓基或哌啶鎓基离子液体混合物除去少量烯烃中所含的炔属化合物。 根据本发明的方法,通过吡咯烷鎓基或哌啶鎓离子液体来稳定卤化铜(I),抑制Cu(I)氧化为Cu(II),从而除去炔属化合物的能力可以为 维持了很长时间,可以显着提高炔属化合物对烯烃的选择性去除率。 此外,由于在本发明方法中使用的包含卤化铜(I)的离子液体混合物可以同时应用于吸收和萃取过程中,所以它可以以比较简单和经济的方式从烯烃中有效地除去炔属化合物 现有的吸附和膜分离过程。