摘要:
The present invention relates to a method for one-pot synthesis of ionic liquid with fluoroalkyl group, more particularly to a method for one-pot synthesis of ionic liquid with fluoroalkyl group represented by the following Chemical Formula 1 by adding and reacting a nitrogen-containing compound, a Brønsted acid of the formula YH and a fluoroolefin compound of the formula CFR1═CR2R3 in a single reactor: wherein represents a nitrogen-containing compound; Y− represents an anion of the Brønsted acid; and R1, R2 and R3, which may be same or different, represent hydrogen, fluorine, C1-C10 alkyl or C1-C10 fluoroalkyl having from 1 to 23 fluorine atoms.
摘要:
The present invention relates to a process for removing acetylenes from olefins by using an ionic liquid-based solution, and particularly to a process for removing a small amount of acetylenes contained in olefins by using an ionic liquid-based solution where copper halide (CuX, X=halogen atom) is dissolved. In an ionic liquid-based solution used in the present invention, copper halide (CuX) is stabilized by ionic liquid, thus preventing monovalent copper ion (Cu+) from being oxidized into divalent copper ion (Cu2+), maintaining the superior activity of monovalent copper ion (Cu+) in removing acetylene for a long period of time, and remarkably increasing the selective removal of acetylene-based compounds. Moreover, an ionic liquid-based solution used in the present invention may serve as an extracting solution as well as an absorbent, thereby facilitating the operation and reducing equipment cost in comparison to the conventional extracting agent used in a slurry phase.
摘要翻译:本发明涉及通过使用离子型液体溶液从烯烃中除去炔烃的方法,特别涉及通过使用离子液体基溶液除去烯烃中所含的少量乙炔的方法,其中卤化铜(CuX, X =卤素原子)溶解。 在本发明中使用的离子型液体溶液中,通过离子液体使卤化铜(CuX)稳定化,防止了一价铜离子(Cu +)被氧化为二价铜离子(Cu 2+),保持了一价铜的优异活性 离子(Cu +)长时间除去乙炔,显着增加乙炔类化合物的选择性去除。 此外,本发明中使用的离子性液体溶液可以用作提取溶液和吸收剂,从而与浆料相中使用的常规萃取剂相比,有助于操作和降低设备成本。
摘要:
Provided is a method for preparing a cellulose phosphite compound, more particularly a method for preparing a cellulose phosphite compound whereby cellulose is phosphorylated using an ionic liquid comprising an amine-based cation and a phosphite-based anion.Thus prepared cellulose phosphite compound has a good solubility in water and is highly valuable as concentration control agent, medicine, biomembrane, or the like.
摘要:
A sulfur dioxide absorbent comprising an ionic liquid comprised of alkyl ether-substituted imidazolium cation and an alkanesulfonate anion moieties possesses a high thermal/chemical stability, high SO2 absorption rate and low regeneration temperature, and is useful for an effective separation of SO2 from a combustion exhaust gas mixture or the like.
摘要:
The present invention relates to a method of purifying olefin, the method comprising removing a small amount of acetylenic compounds contained in olefin by using pyrrolidinium-based or piperidinium-based ionic liquid mixtures comprising copper (I) halide. According to the method of the present invention, copper (I) halide is stabilized by pyrrolidinium-based or piperidinium-based ionic liquids, suppressing the oxidation of Cu(I) into Cu(II), whereby the capacity of removing acetylenic compounds can be maintained for a long time and the selective removal rate of acetylenic compounds to olefin can be significantly improved. In addition, since the ionic liquid mixtures comprising copper (I) halide used in the method of the present invention can be applied to both absorption and extraction processes, it can effectively remove acetylenic compounds from olefin in a more simple and economical way compared to the existing adsorption and membrane separation processes.
摘要:
The present invention relates to a facilitated transport membrane for separation of alkene hydrocarbons from hydrocarbon mixtures, comprising a porous support and a solid polymer electrolyte consisting of a transition metal salt and a polymer having phthalic structure, in which the electrolyte is in solid state at its operating temperature. The facilitated transport membrane is prepared by forming a solid polymer electrolyte consisting of a transition metal salt and a polymer on a porous support. The transition metal salt can selectively and reversibly form a complex with alkene hydrocarbons and the polymer can dissociate the transition metal salt. In particular, the polymer matrix allows the transition metal salt to be well dissociated because it has a phthalic structure capable of being coordinated to a transition metal ion.
摘要:
This invention relates to a method for preparing cycloaliphatic diamines by hydrogenating an aromatic diamines in the presence of a supported ruthenium catalyst. The catalyst is pre-treated with oxygen or air to increase the rate of the reaction and decrease the amount of higher boiler by-products.
摘要:
The present invention relates to a method of purifying olefin, the method comprising removing a small amount of acetylenic compounds contained in olefin by using pyrrolidinium-based or piperidinium-based ionic liquid mixtures comprising copper (I) halide. According to the method of the present invention, copper (I) halide is stabilized by pyrrolidinium-based or piperidinium-based ionic liquids, suppressing the oxidation of Cu(I) into Cu(II), whereby the capacity of removing acetylenic compounds can be maintained for a long time and the selective removal rate of acetylenic compounds to olefin can be significantly improved. In addition, since the ionic liquid mixtures comprising copper (I) halide used in the method of the present invention can be applied to both absorption and extraction processes, it can effectively remove acetylenic compounds from olefin in a more simple and economical way compared to the existing adsorption and membrane separation processes.
摘要:
The present invention relates to a carbon dioxide absorbent, an ionic liquid obtained by reacting amide and an organic acid and a method of using the same. The amidium-based ionic liquid of the present invention has excellent CO2 absorption capability, which is hardly reduced even with repeated use, is easy to synthesize and has low manufacturing cost thus being useful as a CO2 absorbent.
摘要:
The present invention relates to a carbon dioxide absorbent, an ionic liquid obtained by reacting amide and an organic acid and a method of using the same. The amidium-based ionic liquid of the present invention has excellent CO2 absorption capability, which is hardly reduced even with repeated use, is easy to synthesize and has low manufacturing cost thus being useful as a CO2 absorbent.