Process to prepare crosslinked cellulose ethers, crosslinked cellulose ethers obtainable by such process and the use thereof

    公开(公告)号:US09914786B2

    公开(公告)日:2018-03-13

    申请号:US14795314

    申请日:2015-07-09

    申请人: AKZO NOBEL N.V.

    CPC分类号: C08B15/005 C08B5/00

    摘要: The invention relates to a dry or slurry process to prepare phosphate-crosslinked cellulose ethers from a cellulose starting material comprising the steps of adding an alkalizing agent to the cellulose starting material to achieve mercerization, adding an ethehfying agent to the reaction mixture to achieve etherification of the cellulose, and adding a crosslinking agent to the reaction mixture to achieve crosslinking of the cellulose, wherein at least part of the alkalizing agent is added to the cellulose starting material before the etherification and/or crosslinking reactions take place to obtain alkalized cellulose; the crosslinking agent and the etherifying agent are added one after the other in random order or simultaneously; the crosslinking agent is an alkali metal thmetaphosphate; and the crosslinking and etherification steps are performed at an elevated temperature. Additionally, the invention relates to crosslinked cellulose ethers obtainable by the above process having a viscosity and/or water absorption capacity higher than their non-crosslinked equivalents and the use thereof.

    METHOD OF MODIFYING POLYMERS
    3.
    发明申请
    METHOD OF MODIFYING POLYMERS 审中-公开
    改性聚合物的方法

    公开(公告)号:US20160145356A1

    公开(公告)日:2016-05-26

    申请号:US14893751

    申请日:2014-05-26

    摘要: A method of modifying a polymer having hydroxyl groups, selected from the group of polysaccharides and lignin, to give a modified polymer comprising the step of contacting said polymer with at least one organic phosphonate salt in order to chemically modify the polymer, said organic phosphonate salt being in a liquid phase. The method of polymer modification provides novel polymers. Modified polymers obtained from a polymer having been treated with at least one organic phosphonate salt are also disclosed. The modified polymers can be used as such or separated and optionally recovered from the solution, optionally being formed into particular materials or shapes.

    摘要翻译: 一种改性具有选自多糖和木质素的羟基的聚合物的方法,得到改性聚合物,该改性聚合物包括使所述聚合物与至少一种有机膦酸盐接触的步骤,以化学改性聚合物,所述有机膦酸盐 处于液相。 聚合物改性的方法提供了新的聚合物。 还公开了由已经用至少一种有机膦酸盐处理的聚合物获得的改性聚合物。 改性聚合物可以原样使用或分离并任选地从溶液中回收,任选形成特定的材料或形状。

    PHOSPHORIC ACID-ESTERIFIED FINE CELLULOSE FIBER AND METHOD FOR PRODUCING THE SAME
    4.
    发明申请
    PHOSPHORIC ACID-ESTERIFIED FINE CELLULOSE FIBER AND METHOD FOR PRODUCING THE SAME 审中-公开
    磷酸 - 精制纤维素纤维及其制造方法

    公开(公告)号:US20160115249A1

    公开(公告)日:2016-04-28

    申请号:US14891255

    申请日:2014-05-16

    IPC分类号: C08B5/00

    摘要: Objects of the present invention are to provide a phosphoric acid-esterified fine cellulose fiber of which slurry shows superior transparency, and to provide a method for producing a phosphorylated fine cellulose fiber showing superior transparency with good efficiency and high yield. According to the present invention, there is provided a phosphoric acid-esterified fine cellulose fiber, of which 0.2 mass % aqueous dispersion shows a solution haze of 15% or lower.

    摘要翻译: 本发明的目的是提供一种磷酸酯化的细纤维素纤维,其中浆液显示出优异的透明性,并且提供了以高效率和高产率显示出优异的透明性的磷酸化细纤维素纤维的制备方法。 根据本发明,提供了一种磷酸酯化的细纤维素纤维,其中0.2质量%的水分散体显示出15%以下的溶液雾度。

    Cellulose based optical film material and method for forming the same
    6.
    发明授权
    Cellulose based optical film material and method for forming the same 有权
    基于纤维素的光学薄膜材料及其形成方法

    公开(公告)号:US07943761B2

    公开(公告)日:2011-05-17

    申请号:US11550796

    申请日:2006-10-19

    申请人: Chien-Tien Chen

    发明人: Chien-Tien Chen

    摘要: The present invention discloses a cellulose based optical film material with the following structure: wherein R1 is —H or —C(O)R4, R4 is alkyl or aryl; R2 is —C(O)R5, R5 is alkyl or aryl; R3 comprises one of the group consisting of: phosphinate based group, phosphonate based group, phosphonamide based group, phosphate based group, phosphoramide based group, carbamate based group, carbonate based group, and ester based group. Further, this invention also discloses a method for forming the cellulose based optical film material.

    摘要翻译: 本发明公开了具有以下结构的纤维素基光学薄膜材料:其中R1是-H或-C(O)R4,R4是烷基或芳基; R2是-C(O)R5,R5是烷基或芳基; R3包括以下各项之一:次膦酸酯基,膦酸酯基,膦酰胺基,磷酸酯基,磷酰胺基,氨基甲酸酯基,碳酸酯基和酯基。 此外,本发明还公开了一种形成基于纤维素的光学薄膜材料的方法。

    Starch derivatives and other derivatives, production processes therefor, and wound healing applications therefor
    8.
    发明申请
    Starch derivatives and other derivatives, production processes therefor, and wound healing applications therefor 有权
    淀粉衍生物和其他衍生物,其生产工艺及其伤口愈合应用

    公开(公告)号:US20060142242A1

    公开(公告)日:2006-06-29

    申请号:US11289646

    申请日:2005-11-30

    IPC分类号: C08B31/02 A61K31/718

    摘要: Novel phosphate starch derivatives are useful in wound healing. Novel phosphorylated cottons are useful in wound healing. Silver-derivatized wound care products are provided which survive washing and remain part of the wound care product. Silver-derivatized wound care products are provided that have favorable elastase-sequestering activity while advantageously appearing white-colored, without needing to darken to grey or black as usually would occur when working with silver. Also, starch products with outstanding water uptake are provided.

    摘要翻译: 新型磷酸盐淀粉衍生物可用于伤口愈合。 新型磷酸化棉花可用于伤口愈合。 提供银衍生的伤口护理产品,其可在洗涤中存活并保留伤口护理产品的一部分。 提供了银衍生的伤口护理产品,其具有有利的弹性蛋白酶封闭活性,同时有利地出现白色,而不需要像使用银时通常会发生的灰色或黑色变暗。 此外,提供了具有优异吸水性的淀粉产品。

    Biosorbents and process for producing the same
    9.
    发明授权
    Biosorbents and process for producing the same 失效
    生物吸附剂及其生产方法

    公开(公告)号:US06579977B1

    公开(公告)日:2003-06-17

    申请号:US09555540

    申请日:2000-05-31

    IPC分类号: C07H1312

    摘要: A process is disclosed for producing biosorbents by phosphorylation of cellulose-containing materials with phosphoric acid or ammonium phosphate in the presence of urea. Also disclosed are biosorbents with particular good use properties. Biosorbents of this type are used, in particular, for removing heavy metals from aqueous solutions. Proceeding from the disadvantages of the known prior art, purification costs of resultant raw products should be lowered and the formation of unwanted soluble organic polymer phosphates as by-products should be prevented. The biosorbents should have an improved mechanical strength and very good use properties. The disclosed biosorbents contain 5-10 % phosphorus and 1-4 % nitrogen in the form of carbamide groups. The synthesis mixture is mixed with elementary sulphur before starting the reaction in order to produce biosorbents with an increased mechanical strength. The proposed procedure allows reducing the otherwise customary reaction temperatures by about 40° C.

    摘要翻译: 公开了通过在尿素存在下用磷酸或磷酸铵磷酸化含纤维素材料来生产生物吸附剂的方法。 还公开了具有特别良好使用性质的生物吸附剂。 特别是使用这种类型的生物吸附剂来从水溶液中除去重金属。 从已知现有技术的缺点出发,应降低所得原料的净化成本,并且防止作为副产物形成不想要的可溶性有机聚合物磷酸盐。 生物吸附剂应具有改善的机械强度和非常好的使用性能。 所公开的生物吸附剂含有5-10%的磷和1-4%的以氨基酰胺基团形式的氮。 在开始反应之前,将合成混合物与元素硫混合以产生具有增加的机械强度的生物吸附剂。 所提出的方法允许将常规反应温度降低约40℃