Process for the synthesis of ethers of aromatic acids
    21.
    发明授权
    Process for the synthesis of ethers of aromatic acids 失效
    合成芳香族醚的方法

    公开(公告)号:US08207374B2

    公开(公告)日:2012-06-26

    申请号:US12518201

    申请日:2007-12-18

    申请人: Joachim C. Ritter

    发明人: Joachim C. Ritter

    IPC分类号: C07C51/367 C07C65/21

    CPC分类号: C07C51/367 C07C65/21

    摘要: Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper.

    摘要翻译: 芳族酸的醚由含有铜(I)或铜(II)源和与铜配位的二酮配体的反应混合物中的卤代芳族酸生成。

    PROCESS FOR MAKING LINEAR DICARBOXYLIC ACIDS FROM RENEWABLE RESOURCES
    22.
    发明申请
    PROCESS FOR MAKING LINEAR DICARBOXYLIC ACIDS FROM RENEWABLE RESOURCES 失效
    从可再生能源制造线性二羧酸的方法

    公开(公告)号:US20110300594A1

    公开(公告)日:2011-12-08

    申请号:US13131138

    申请日:2009-12-11

    IPC分类号: C12P7/44

    摘要: This invention provides a process of making a linear dicarboxylic acid of C10, C12, C14, C16 or C18 chain length, the process comprising providing a feed which is a renewable resource, contacting the feed with a catalyst in the presence of hydrogen and at a temperature of about 250° C. to about 425° C. and at a pressure of about 500 psig to about 2500 psig (3450 kPa to about 17,250 kPa) to produce a hydrocarbon product having at least a 5:1 ratio of even-numbered alkanes to odd-numbered alkanes and comprising a linear alkane of Cn chain length; and fermenting at least a portion of the linear alkane of Cn chain length to a linear dicarboxylic acid of Cn chain length, wherein n=10, 12, 14, 16 or 18. The catalyst comprises an oxide, molybdenum, and one or more active metals selected from the group consisting of nickel, cobalt, and mixtures thereof and the catalyst is in sulfided form.

    摘要翻译: 本发明提供了制备C 10,C 12,C 14,C 16或C 18链长度的线性二羧酸的方法,该方法包括提供作为可再生资源的进料,在氢气存在下使进料与催化剂接触 温度为约250℃至约425℃,压力为约500psig至约2500psig(3450kPa至约17,250kPa),以产生具有至少5:1比例偶数编号的烃产物 烷烃至奇数烷烃并且包含Cn链长度的直链烷烃; 并将Cn链长度的直链烷烃的至少一部分发酵成C n链长度的线性二羧酸,其中n = 10,12,14,16或18.所述催化剂包含氧化物,钼和一种或多种活性物质 选自镍,钴及其混合物的金属,催化剂为硫化形式。

    Process for the synthesis of dihalodinitrobenzenes
    24.
    发明授权
    Process for the synthesis of dihalodinitrobenzenes 失效
    合成二卤代硝基苯的方法

    公开(公告)号:US08003831B1

    公开(公告)日:2011-08-23

    申请号:US12335959

    申请日:2008-12-16

    申请人: Joachim C. Ritter

    发明人: Joachim C. Ritter

    IPC分类号: C07C205/00

    CPC分类号: C07C201/08 C07C205/12

    摘要: A process is provided for the preparation of 1,3-dihalo-4,6-dinitrobenzene by the nitration of 1,3-dihalobenzene. The direct isolation of highly pure 1,3-dihalo-4,6-dinitrobenzene is accomplished without a water or ice quench, and involves the use of at least one equivalent of SO3 during the reaction, slow crystallization, and isolation of product from a cold crystal slurry.

    摘要翻译: 提供了通过硝化1,3-二卤代苯制备1,3-二卤代-4,6-二硝基苯的方法。 高纯度的1,3-二卤代-4,6-二硝基苯的直接分离是在没有水或冰骤冷的情况下完成的,并且涉及在反应期间使用至少一当量的SO 3,缓慢的结晶和从 冷结晶浆。

    Process for the synthesis of ethers of aromatic acids
    25.
    发明授权
    Process for the synthesis of ethers of aromatic acids 失效
    合成芳香族醚的方法

    公开(公告)号:US07943723B2

    公开(公告)日:2011-05-17

    申请号:US12518167

    申请日:2007-12-18

    申请人: Joachim C. Ritter

    发明人: Joachim C. Ritter

    IPC分类号: C08G64/00 C08G63/02

    摘要: The inventions disclosed herein include processes for the preparation of an ether of an aromatic acid, processes for the preparation of products into which such an ether can be converted, the use of such processes, and the products obtained and obtainable by such processes. A key feature of the processes described is the use of a solvent comprising an alcohol ROH and an alcoholate RO−M+.

    摘要翻译: 本文公开的发明包括制备芳族酸醚的方法,制备可以转化这种醚的产物的方法,这些方法的使用以及通过这些方法获得和获得的产物。 所述方法的关键特征是使用包含醇ROH和醇化物RO-M +的溶剂。

    PROCESS FOR THE SYNTHESIS OF 2,6-DIAMINO-3,5-DINITROTOLUENE
    26.
    发明申请
    PROCESS FOR THE SYNTHESIS OF 2,6-DIAMINO-3,5-DINITROTOLUENE 失效
    2,6-二氨基-3,5-哌啶酮的合成方法

    公开(公告)号:US20100160678A1

    公开(公告)日:2010-06-24

    申请号:US12634767

    申请日:2009-12-10

    IPC分类号: C07C63/26 C07C209/10

    摘要: An improved process is provided for the preparation of 2,6-diamino-3,5-dinitrotoluene by amination of 2,6-dichloro-3,5-dinitrotoluene. The presence of water unexpectedly results in a highly pure product, free of glycol ether impurities. This product can be used to make highly pure 2,3,5,6-tetraaminotoluene, which in turn can be used to make high molecular weight polybenzimidazoles for high strength fibers.

    摘要翻译: 提供了通过2,6-二氯-3,5-二硝基甲苯的胺化制备2,6-二氨基-3,5-二硝基甲苯的改进方法。 水的存在意外地导致高纯度的产品,不含二醇醚杂质。 该产品可用于制备高纯度的2,3,5,6-四氨基甲苯,其又可用于制备用于高强度纤维的高分子量聚苯并咪唑。