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1.
公开(公告)号:US20110300594A1
公开(公告)日:2011-12-08
申请号:US13131138
申请日:2009-12-11
申请人: Joachim C. Ritter , Sourav Kumar Sengupta , Hasan Dindi , Robert D. Fallon , Ekaterini Korovessi , Andrew C. Eliot , John Joseph Hagedorn
发明人: Joachim C. Ritter , Sourav Kumar Sengupta , Hasan Dindi , Robert D. Fallon , Ekaterini Korovessi , Andrew C. Eliot , John Joseph Hagedorn
IPC分类号: C12P7/44
CPC分类号: C10G3/50 , C10G3/46 , C10G3/54 , C10G2300/1014 , C10G2300/1018 , C10L1/02 , C11C1/002 , C12P7/6409 , Y02E50/13 , Y02P30/20
摘要: This invention provides a process of making a linear dicarboxylic acid of C10, C12, C14, C16 or C18 chain length, the process comprising providing a feed which is a renewable resource, contacting the feed with a catalyst in the presence of hydrogen and at a temperature of about 250° C. to about 425° C. and at a pressure of about 500 psig to about 2500 psig (3450 kPa to about 17,250 kPa) to produce a hydrocarbon product having at least a 5:1 ratio of even-numbered alkanes to odd-numbered alkanes and comprising a linear alkane of Cn chain length; and fermenting at least a portion of the linear alkane of Cn chain length to a linear dicarboxylic acid of Cn chain length, wherein n=10, 12, 14, 16 or 18. The catalyst comprises an oxide, molybdenum, and one or more active metals selected from the group consisting of nickel, cobalt, and mixtures thereof and the catalyst is in sulfided form.
摘要翻译: 本发明提供了制备C 10,C 12,C 14,C 16或C 18链长度的线性二羧酸的方法,该方法包括提供作为可再生资源的进料,在氢气存在下使进料与催化剂接触 温度为约250℃至约425℃,压力为约500psig至约2500psig(3450kPa至约17,250kPa),以产生具有至少5:1比例偶数编号的烃产物 烷烃至奇数烷烃并且包含Cn链长度的直链烷烃; 并将Cn链长度的直链烷烃的至少一部分发酵成C n链长度的线性二羧酸,其中n = 10,12,14,16或18.所述催化剂包含氧化物,钼和一种或多种活性物质 选自镍,钴及其混合物的金属,催化剂为硫化形式。
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2.
公开(公告)号:US08753853B2
公开(公告)日:2014-06-17
申请号:US13131138
申请日:2009-12-11
申请人: Joachim C. Ritter , Sourav Kumar Sengupta , Hasan Dindi , Robert D. Fallon , Ekaterini Korovessi , Andrew C. Eliot , John Joseph Hagedorn
发明人: Joachim C. Ritter , Sourav Kumar Sengupta , Hasan Dindi , Robert D. Fallon , Ekaterini Korovessi , Andrew C. Eliot , John Joseph Hagedorn
IPC分类号: C12P7/44
CPC分类号: C10G3/50 , C10G3/46 , C10G3/54 , C10G2300/1014 , C10G2300/1018 , C10L1/02 , C11C1/002 , C12P7/6409 , Y02E50/13 , Y02P30/20
摘要: This invention provides a process of making a linear dicarboxylic acid of C10, C12, C14, C16 or C18 chain length, the process comprising providing a feed which is a renewable resource, contacting the feed with a catalyst in the presence of hydrogen and at a temperature of about 250° C. to about 425° C. and at a pressure of about 500 psig to about 2500 psig (3450 kPa to about 17,250 kPa) to produce a hydrocarbon product having at least a 5:1 ratio of even-numbered alkanes to odd-numbered alkanes and comprising a linear alkane of Cn chain length; and fermenting at least a portion of the linear alkane of Cn chain length to a linear dicarboxylic acid of Cn chain length, wherein n=10, 12, 14, 16 or 18. The catalyst comprises an oxide, molybdenum, and one or more active metals selected from the group consisting of nickel, cobalt, and mixtures thereof and the catalyst is in sulfided form.
摘要翻译: 本发明提供了制备C 10,C 12,C 14,C 16或C 18链长度的线性二羧酸的方法,该方法包括提供作为可再生资源的进料,在氢气存在下使进料与催化剂接触 温度为约250℃至约425℃,压力为约500psig至约2500psig(3450kPa至约17,250kPa),以产生具有至少5:1比例偶数编号的烃产物 烷烃至奇数烷烃并且包含Cn链长度的直链烷烃; 并将Cn链长度的直链烷烃的至少一部分发酵成C n链长度的线性二羧酸,其中n = 10,12,14,16或18.所述催化剂包含氧化物,钼和一种或多种活性物质 选自镍,钴及其混合物的金属,催化剂为硫化形式。
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公开(公告)号:US08642781B2
公开(公告)日:2014-02-04
申请号:US12870188
申请日:2010-08-27
申请人: David Richard Corbin , Joachim C. Ritter , James A. Schultz , Sourav Kumar Sengupta , Katelyn Rae Walck
发明人: David Richard Corbin , Joachim C. Ritter , James A. Schultz , Sourav Kumar Sengupta , Katelyn Rae Walck
IPC分类号: C07C209/00
CPC分类号: C07C201/08 , C07C205/06
摘要: Aromatic compounds such as o-xylene are selectively nitrated by nitric acid in the presence of polyphosphoric acid and a large pore, acidic zeolite or a large pore, hydrophobic molecular sieve. This is an environmentally friendly, commercially viable, high conversion process for the selective nitration of aromatic compounds in the para position.
摘要翻译: 芳族化合物如邻二甲苯在多磷酸和大孔,酸性沸石或大孔疏水分子筛存在下,被硝酸选择性硝化。 这是一种环保,商业上可行的高转化率方法,用于选择性硝化对位芳族化合物。
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公开(公告)号:US20110054219A1
公开(公告)日:2011-03-03
申请号:US12870188
申请日:2010-08-27
申请人: David Richard Corbin , Joachim C. Ritter , James A. Schultz , Sourav Kumar Sengupta , Katelyn Rae Walck
发明人: David Richard Corbin , Joachim C. Ritter , James A. Schultz , Sourav Kumar Sengupta , Katelyn Rae Walck
IPC分类号: C07C205/06
CPC分类号: C07C201/08 , C07C205/06
摘要: Aromatic compounds such as o-xylene are selectively nitrated by nitric acid in the presence of polyphosphoric acid and a large pore, acidic zeolite or a large pore, hydrophobic molecular sieve. This is an environmentally friendly, commercially viable, high conversion process for the selective nitration of aromatic compounds in the para position.
摘要翻译: 芳族化合物如邻二甲苯在多磷酸和大孔,酸性沸石或大孔疏水分子筛存在下,被硝酸选择性硝化。 这是一种环保,商业上可行的高转化率方法,用于选择性硝化对位芳族化合物。
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公开(公告)号:US20130048136A1
公开(公告)日:2013-02-28
申请号:US13596103
申请日:2012-08-28
CPC分类号: C08G69/265 , C08G69/28 , C08L77/06 , F16L9/12 , F16L11/04
摘要: Disclosed is a copolyamide including at least two repeat units selected from the group consisting of structures (I) to (IV), —C(O)(CH2)10C(O)NH(CH2)nNH— (I); —C(O)(CH2)12C(O)NH(CH2)nNH— (II); —C(O)(CH2)14C(O)NH(CH2)nNH— (II); and —C(O)(CH2)16C(O)NH(CH2)nNH— (IV); and n is an integer selected from 4, 6, 10 or 12; wherein at least one repeat unit is selected from structures (I) and (II); and any one the repeat units may be present up to about 92 mole percent. Also disclosed is a process for providing the copolyamide; and thermoplastic compositions and tubing including the copolyamides.
摘要翻译: 公开了包含选自由结构(I)至(IV),-C(O)(CH 2)10 C(O)NH(CH 2)n NH-(I))组成的组中的至少两个重复单元的共聚酰胺; -C(O)(CH 2)12 C(O)NH(CH 2)n NH-(II); -C(O)(CH 2)14 C(O)NH(CH 2)n NH-(II); 和-C(O)(CH 2)16 C(O)NH(CH 2)n NH-(IV); n为选自4,6,10或12的整数; 其中至少一个重复单元选自结构(I)和(II); 并且任何一个重复单元可以存在达约92摩尔%。 还公开了提供共聚酰胺的方法; 和包括共聚酰胺的热塑性组合物和管。
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公开(公告)号:US08158830B1
公开(公告)日:2012-04-17
申请号:US12336634
申请日:2008-12-17
IPC分类号: C07C209/00
CPC分类号: C07C209/10 , C07C209/36 , Y02P20/125 , C07C211/52 , C07C211/50
摘要: An integrated process is provided for preparing 1,2,4,5-tetraminobenzene and salts thereof, starting in certain embodiments with nitration of 1,3-dihalobenzene. The process design eliminates costly intermediate drying and recrystallization steps. Handling of solid materials with possible skin sensitizing properties and toxicity is avoided, thereby eliminating human and environmental exposure.
摘要翻译: 提供了一种用于制备1,2,4,5-四甲苯基苯及其盐的综合方法,在某些实施方案中,其中1,3-二卤代苯硝化。 该工艺设计消除了昂贵的中间干燥和重结晶步骤。 避免了具有可能的皮肤敏感性和毒性的固体材料的处理,从而消除了人体和环境的暴露。
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公开(公告)号:US08143450B1
公开(公告)日:2012-03-27
申请号:US12337701
申请日:2008-12-18
IPC分类号: C07C211/00
CPC分类号: C07C69/88 , C07C209/36 , C07C209/68 , C07C211/50
摘要: A process is provided for preparing complexes of 1,2,4,5-tetraminobenzene with an aromatic diacid. The process design eliminates costly intermediate drying and recrystallization steps. Handling of solid materials with possible skin sensitizing properties and toxicity is avoided, thereby eliminating human and environmental exposure.
摘要翻译: 提供了一种制备1,2,4,5-四苯基苯与芳族二酸的络合物的方法。 该工艺设计消除了昂贵的中间干燥和重结晶步骤。 避免了具有可能的皮肤敏感性和毒性的固体材料的处理,从而消除了人体和环境的暴露。
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公开(公告)号:US20130204041A1
公开(公告)日:2013-08-08
申请号:US13516748
申请日:2010-12-21
申请人: Joachim C. Ritter
发明人: Joachim C. Ritter
IPC分类号: C07C215/80
CPC分类号: C07C215/80 , C08G73/18
摘要: New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film., and tape and are useful in applications such as protective apparel, aircraft., automotive components, personal electronics, and sports equipment.
摘要翻译: 公开了新的三氨基苯酚组合物和相关化合物,以及它们的制备方法以及从这些化合物制备新的盐和二酸配合物。 由这些组合物制备的聚合物可以制成高强度纤维,膜和胶带,并且可用于诸如防护服,飞机,汽车部件,个人电子和运动器材的应用中。
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9.
公开(公告)号:US20130158296A1
公开(公告)日:2013-06-20
申请号:US13517052
申请日:2010-12-21
申请人: Annalisa Hargis , Joachim C. Ritter
发明人: Annalisa Hargis , Joachim C. Ritter
IPC分类号: C07C209/10
CPC分类号: C07C209/10 , C07C211/52
摘要: A process is provided for the preparation of 1-amino-3-halo-4,6-dinitrobenzene and related compounds by monoamination of dihalodinitrobenzenes by ammonia in the presence of solvent and water. Using glycol as a solvent for the dihalodinitrobenzene and feeding ammonia at a rate at which it is consumed allows for the synthesis of high purity product, such as 1-amino-3-chloro-4,6-dinitrobenzene, at high yields.
摘要翻译: 提供了一种通过在溶剂和水存在下用氨将二卤代硝基苯单胺化制备1-氨基-3-卤代-4,6-二硝基苯及相关化合物的方法。 使用乙二醇作为二卤代硝基苯的溶剂并以其消耗的速率供给氨,可高产率地合成高纯度产物如1-氨基-3-氯-4,6-二硝基苯。
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公开(公告)号:US20130012092A1
公开(公告)日:2013-01-10
申请号:US13636351
申请日:2011-03-22
申请人: Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Huang , Zuohong Yin
发明人: Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Huang , Zuohong Yin
IPC分类号: D04H13/00
CPC分类号: D01F8/16 , D01F1/10 , D04H1/541 , Y10T442/637
摘要: A nonwoven web comprising bicomponent fibers. The fibers have continuous phases each of a first polyarylene sulfide (PAS) component and a polymer component. The polymer component may also be a second polyarylene sulfide. The first polyarylene sulfide component contains a tin or a zinc additive or both, and the first polyarylene sulfide component of any given fiber is at least partially exposed to the external surface of that fiber.
摘要翻译: 包含双组分纤维的非织造纤维网。 纤维具有各自具有第一聚芳硫醚(PAS)组分和聚合物组分的连续相。 聚合物组分也可以是第二聚芳硫醚。 第一聚芳硫醚组分含有锡或锌添加剂或两者,并且任何给定纤维的第一聚芳硫醚组分至少部分地暴露于该纤维的外表面。
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