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    PROCESS FOR MAKING LINEAR DICARBOXYLIC ACIDS FROM RENEWABLE RESOURCES
    1.
    发明申请
    PROCESS FOR MAKING LINEAR DICARBOXYLIC ACIDS FROM RENEWABLE RESOURCES 失效
    从可再生能源制造线性二羧酸的方法

    公开(公告)号：US20110300594A1

    公开(公告)日：2011-12-08

    申请号：US13131138

    申请日：2009-12-11

    申请人： Joachim C. Ritter ,  Sourav Kumar Sengupta ,  Hasan Dindi ,  Robert D. Fallon ,  Ekaterini Korovessi ,  Andrew C. Eliot ,  John Joseph Hagedorn

    发明人： Joachim C. Ritter ,  Sourav Kumar Sengupta ,  Hasan Dindi ,  Robert D. Fallon ,  Ekaterini Korovessi ,  Andrew C. Eliot ,  John Joseph Hagedorn

    IPC分类号： C12P7/44

    CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10L1/02 ,  C11C1/002 ,  C12P7/6409 ,  Y02E50/13 ,  Y02P30/20

    摘要： This invention provides a process of making a linear dicarboxylic acid of C10, C12, C14, C16 or C18 chain length, the process comprising providing a feed which is a renewable resource, contacting the feed with a catalyst in the presence of hydrogen and at a temperature of about 250° C. to about 425° C. and at a pressure of about 500 psig to about 2500 psig (3450 kPa to about 17,250 kPa) to produce a hydrocarbon product having at least a 5:1 ratio of even-numbered alkanes to odd-numbered alkanes and comprising a linear alkane of Cn chain length; and fermenting at least a portion of the linear alkane of Cn chain length to a linear dicarboxylic acid of Cn chain length, wherein n=10, 12, 14, 16 or 18. The catalyst comprises an oxide, molybdenum, and one or more active metals selected from the group consisting of nickel, cobalt, and mixtures thereof and the catalyst is in sulfided form.

    摘要翻译： 本发明提供了制备C 10，C 12，C 14，C 16或C 18链长度的线性二羧酸的方法，该方法包括提供作为可再生资源的进料，在氢气存在下使进料与催化剂接触 温度为约250℃至约425℃，压力为约500psig至约2500psig（3450kPa至约17,250kPa），以产生具有至少5:1比例偶数编号的烃产物 烷烃至奇数烷烃并且包含Cn链长度的直链烷烃; 并将Cn链长度的直链烷烃的至少一部分发酵成C n链长度的线性二羧酸，其中n = 10,12,14,16或18.所述催化剂包含氧化物，钼和一种或多种活性物质 选自镍，钴及其混合物的金属，催化剂为硫化形式。

    Process for making linear dicarboxylic acids from renewable resources
    2.
    发明授权
    Process for making linear dicarboxylic acids from renewable resources 失效
    从可再生资源制造线性二羧酸的方法

    公开(公告)号：US08753853B2

    公开(公告)日：2014-06-17

    申请号：US13131138

    申请日：2009-12-11

    申请人： Joachim C. Ritter ,  Sourav Kumar Sengupta ,  Hasan Dindi ,  Robert D. Fallon ,  Ekaterini Korovessi ,  Andrew C. Eliot ,  John Joseph Hagedorn

    发明人： Joachim C. Ritter ,  Sourav Kumar Sengupta ,  Hasan Dindi ,  Robert D. Fallon ,  Ekaterini Korovessi ,  Andrew C. Eliot ,  John Joseph Hagedorn

    IPC分类号： C12P7/44

    CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10L1/02 ,  C11C1/002 ,  C12P7/6409 ,  Y02E50/13 ,  Y02P30/20

    摘要： This invention provides a process of making a linear dicarboxylic acid of C10, C12, C14, C16 or C18 chain length, the process comprising providing a feed which is a renewable resource, contacting the feed with a catalyst in the presence of hydrogen and at a temperature of about 250° C. to about 425° C. and at a pressure of about 500 psig to about 2500 psig (3450 kPa to about 17,250 kPa) to produce a hydrocarbon product having at least a 5:1 ratio of even-numbered alkanes to odd-numbered alkanes and comprising a linear alkane of Cn chain length; and fermenting at least a portion of the linear alkane of Cn chain length to a linear dicarboxylic acid of Cn chain length, wherein n=10, 12, 14, 16 or 18. The catalyst comprises an oxide, molybdenum, and one or more active metals selected from the group consisting of nickel, cobalt, and mixtures thereof and the catalyst is in sulfided form.

    摘要翻译： 本发明提供了制备C 10，C 12，C 14，C 16或C 18链长度的线性二羧酸的方法，该方法包括提供作为可再生资源的进料，在氢气存在下使进料与催化剂接触 温度为约250℃至约425℃，压力为约500psig至约2500psig（3450kPa至约17,250kPa），以产生具有至少5:1比例偶数编号的烃产物 烷烃至奇数烷烃并且包含Cn链长度的直链烷烃; 并将Cn链长度的直链烷烃的至少一部分发酵成C n链长度的线性二羧酸，其中n = 10,12,14,16或18.所述催化剂包含氧化物，钼和一种或多种活性物质 选自镍，钴及其混合物的金属，催化剂为硫化形式。

    Producing short chain perfluoroalkyl iodides
    6.
    发明授权
    Producing short chain perfluoroalkyl iodides 有权
    生产短链全氟烷基碘化物

    公开(公告)号：US08258354B2

    公开(公告)日：2012-09-04

    申请号：US12796020

    申请日：2010-06-08

    申请人： Stephen Ernest Jacobson ,  Sourav Kumar Sengupta ,  John Joseph Hagedorn ,  Liza Lopez

    发明人： Stephen Ernest Jacobson ,  Sourav Kumar Sengupta ,  John Joseph Hagedorn ,  Liza Lopez

    IPC分类号： C07C17/361 ,  C07C17/26 ,  C07C19/08

    CPC分类号： A61B5/0803 ,  C07C17/361 ,  C07C19/16

    摘要： An improved process for producing perfluoroalkyl iodides of formula (I) F(CF2CF2)n—I  (I) wherein n is an integer from 2 to 3, wherein the improvement comprises contacting at least one perfluoroalkyl iodide of formula (II) and at least one perfluoroalkyl iodide of formula (III) F(CF2CF2)m—I  (II) F(CF2CF2)p—I  (III) wherein m is an integer greater than or equal to 3, and p is an integer equal to or lower than 2, at a) a molar ratio of formula (III) to formula (II) of from about 1:1 to about 6:1, b) a residence time of from about 1 to about 9 seconds, and c) a temperature of from about 450° C. to about 495° C.

    摘要翻译： 一种制备式（I）F（CF 2 CF 2）n -I（I）的全氟烷基碘化物的改进方法，其中n是2至3的整数，其中改进包括使式（II）的至少一种全氟烷基碘和至少 一种式（III）的全氟烷基碘F（CF 2 CF 2）m -I（II）F（CF 2 CF 2）p -I（III）其中m是大于或等于3的整数，p是等于或低于 2，a）式（III）与式（II）的摩尔比为约1:1至约6:1，b）约1至约9秒的停留时间，和c） 约450℃至约495℃

    PRODUCING SHORT CHAIN PERFLUOROALKYL IODIDES
    7.
    发明申请
    PRODUCING SHORT CHAIN PERFLUOROALKYL IODIDES 有权
    生产短链全氟烷基碘

    公开(公告)号：US20110301390A1

    公开(公告)日：2011-12-08

    申请号：US12796020

    申请日：2010-06-08

    申请人： Stephen Ernest Jacobson ,  Sourav Kumar Sengupta ,  John Joseph Hagedorn ,  Liza Lopez

    发明人： Stephen Ernest Jacobson ,  Sourav Kumar Sengupta ,  John Joseph Hagedorn ,  Liza Lopez

    IPC分类号： C07C17/361

    CPC分类号： A61B5/0803 ,  C07C17/361 ,  C07C19/16

    摘要： An improved process for producing perfluoroalkyl iodides of formula (I) F(CF2CF2)n—I  (I) wherein n is an integer from 2 to 3, wherein the improvement comprises contacting at least one perfluoroalkyl iodide of formula (II) and at least one perfluoroalkyl iodide of formula (III) F(CF2CF2)m—I  (II) F(CF2CF2)p—I  (III) wherein m is an integer greater than or equal to 3, and p is an integer equal to or lower than 2, at a) a molar ratio of formula (III) to formula (II) of from about 1:1 to about 6:1, b) a residence time of from about 1 to about 9 seconds, and c) a temperature of from about 450° C. to about 495° C.

    摘要翻译： 一种制备式（I）F（CF 2 CF 2）n -I（I）的全氟烷基碘化物的改进方法，其中n是2至3的整数，其中改进包括使式（II）的至少一种全氟烷基碘和至少 一种式（III）的全氟烷基碘F（CF 2 CF 2）m -I（II）F（CF 2 CF 2）p -I（III）其中m是大于或等于3的整数，p是等于或低于 2，a）式（III）与式（II）的摩尔比为约1:1至约6:1，b）约1至约9秒的停留时间，和c） 约450℃至约495℃

    FLUOROALKYLALKOXYLATES
    8.
    发明申请
    FLUOROALKYLALKOXYLATES 审中-公开
    氟代烷基氧化物

    公开(公告)号：US20120255651A1

    公开(公告)日：2012-10-11

    申请号：US13081560

    申请日：2011-04-07

    申请人： CHERYL LYNN IACONELLI ,  Kenneth Gene Moloy ,  Sheng Peng ,  Sourav Kumar Sengupta

    发明人： CHERYL LYNN IACONELLI ,  Kenneth Gene Moloy ,  Sheng Peng ,  Sourav Kumar Sengupta

    IPC分类号： B23K35/22 ,  C09G1/00 ,  C09D11/00 ,  C09K13/00 ,  C09J11/06 ,  A62D1/00 ,  C09K3/00 ,  C11D17/00 ,  C09D7/12

    CPC分类号： C11D1/004

    摘要： Disclosed is a method of altering the surface behavior of a liquid by adding to the liquid a compound of a Formula (1): Rf—O—(CF2)x(CH2)y—O-(QO)z—H   (1) Wherein Rf is a linear or branched perfluoroalkyl having 1 to 6 carbon atoms, optionally interrupted by one to three ether oxygen atoms, x is an integer of 1 to 6; y is an integer of 1 to 6; Q is a linear 1,2-alkylene group of the formula CmH2m where m is an integer of 2 to 10; and z is an integer of 1 to 30.

    摘要翻译： 公开了通过向液体中加入式（1）的化合物：Rf-O-（CF 2）x（CH 2）y -O-（QO）z -H（1）来改变液体的表面行为的方法， 其中Rf是具有1至6个碳原子的直链或支链全氟烷基，任选被一至三个醚氧原子间隔，x是1至6的整数; y为1〜6的整数， Q是式CmH2m的线性1,2-亚烷基，其中m是2至10的整数; z为1〜30的整数。