摘要:
A method of improving performance of electrochemical gas sensors includes cycling potentials applied to one or more of the electrodes of the respective sensor(s) to improve performance of a different electrode. In a process for treating a reference electrode, potentials can be applied to working and, or counter electrodes so as to modify the environment in the vicinity of the reference electrode. An apparatus can carry out the method automatically.
摘要:
A liquid electrolyte composition obtainable by combining a first component comprising bistrifluoromethanesulfonimide and/or an analogue thereof with a second component comprising a dialkyl sulfone, diaryl sulfone, alkyl aryl sulfone, alkyl acyl sulfone, boric acid, alkyl boronic acid, aryl boronic acid, dialkyl phosphite, trialkyl phosphite, dialkyl phosphate, trialkyl phosphate, alkylene carbonate, alkanoic lactone, preferably alkanoic γ-lactone an analogue of any of these, or mixtures thereof, wherein any of the alkyl, aryl of alkenyl groups may be substituted or unsubstituted. The liquid electrolyte is used in an electrochemical gas sensor.
摘要:
A monitor is disclosed for monitoring an atmosphere for the presence of a target gas. The monitor includes an electrical gas sensor having a working (sensing) electrode and a counter electrode, an operational amplifier connected between the sensor electrodes, a detector, and a circuit. The sensor provides a current between the electrodes that is indicative of the amount of a target gas in the atmosphere. The operational amplifier generates an output signal according to the current flowing between the terminals where the output signal is indicative of the amount of target gas in the atmosphere. The detector detects when the current flowing between the sensor electrodes exceeds a predetermined threshold. The circuit restricts the potential difference between the sensor electrodes when the current between the terminals exceeds the predetermined threshold by supplying additional current or removing current from the working sensor electrode.
摘要:
A method and apparatus for gas detection uses a sensor such as an electrochemical (EC) cell and includes a feedback control loop to control a pump to establish a first predetermined gas flow rate to the EC cell. The concentration of the gas at the first predetermined flow rate is measured. If the detected concentration exceeds a predetermined Alert value at the first flow rate an Initial Warning without remedial action is generated, and, the system then changes the gas flow rate before an Alarm is indicated. An Alarm is signaled only if the system verifies the first measurement. Preferably the first flow rate is set to optimize the measurement accuracy of the EC cell being used, and the second flow rate is lower than the first. Verification of an Alarm at the first flow rate may be conducted quickly by a quick-reaction process. The controller may periodically cycle the flow rates between the first and second rates for better accuracy and faster verification times.
摘要:
An electrorheological fluid e.g. for selectively coupling clutch members consists of silicone oil containing 30 volume % of dispersed polyaniline. The polyaniline is acidically oxidised aniline subsequently treated with base.