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29 条记录 (耗时 0.037 秒)

    Process for preparing 1,3-propanediol
    27.
    发明授权
    Process for preparing 1,3-propanediol 失效
    1,3-丙二醇制备方法

    公开(公告)号：US5463144A

    公开(公告)日：1995-10-31

    申请号：US316671

    申请日：1994-09-30

    申请人： Joseph B. Powell ,  Lynn H. Slaugh ,  Thomas C. Forschner ,  Terry B. Thomason ,  Thomas C. Semple ,  Paul R. Weider ,  Juan P. Arhancet

    发明人： Joseph B. Powell ,  Lynn H. Slaugh ,  Thomas C. Forschner ,  Terry B. Thomason ,  Thomas C. Semple ,  Paul R. Weider ,  Juan P. Arhancet

    IPC分类号： C07C29/141 ,  C07C29/16 ,  C07C45/58 ,  C07C45/80 ,  C07C27/20 ,  C07C45/49 ,  C07C47/17

    CPC分类号： C07C45/58 ,  C07C29/141 ,  C07C29/16 ,  C07C45/80

    摘要： 1,3-propanediol is prepared in a process comprising the steps of:contacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of an effective amount of a non-phosphine-ligated cobalt catalyst and an effective amount of a lipophilic quaternary ammonium salt at a temperature within the range of about 50.degree. to about 100.degree. C. and a, pressure within the range of about 500 to about 5000 psig, under reaction conditions effective to produce an intermediate product mixture comprising less than 15 wt % 3-hydroxypropanal;adding an aqueous liquid to said intermediate product mixture and extracting into said aqueous liquid at a temperature less than about 100.degree. C. a major portion of the 3-hydroxypropanal so as to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the-concentration of 3-hydroxypropanal in said intermediate product mixture and an organic phase comprising at least a portion of the cobalt catalyst or a cobalt-containing derivative thereof and at least a portion of the lipophilic quaternary ammonium salt;contacting the aqueous phase comprising 3-hydroxypropanal with hydrogen in, the presence of a hydrogenation catalyst at a pressure of at least about 100 psig and a temperature during at least a portion of the hydrogenation step of at least 40.degree. C. to provide a hydrogenation product mixture comprising 1,3-propanediol.

    摘要翻译： 以包括以下步骤的方法制备1,3-丙二醇：在有效量的非磷化氢连接的钴催化剂存在下，将环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中接触， 在有效量的亲油性季铵盐的温度范围为约50至约100℃，和a，压力范围为约500至约5000psig，在有效产生中间产物混合物的反应条件下，包括 小于15重量％的3-羟基丙醛; 向所述中间产物混合物中加入水性液体，并在低于约100℃的温度下将3-羟基丙醛的主要部分萃取到所述含水液体中，以提供包含比所述中间产物混合物更高浓度的3-羟基丙醛的水相， 所述中间产物混合物中的3-羟基丙醛的浓度和包含至少一部分钴催化剂或其含钴衍生物和至少一部分亲脂性季铵盐的有机相; 在氢化催化剂存在下，在至少约100psig的压力和在至少40℃的至少一部分氢化步骤期间的温度下使包含3-羟基丙醛的水相与氢接触以提供氢化 产物混合物包含1,3-丙二醇。

    Process for making 3-hydroxypropanal and 1,3-propanediol
    28.
    发明授权
    Process for making 3-hydroxypropanal and 1,3-propanediol 失效
    制备3-羟基丙醛和1,3-丙二醇的方法

    公开(公告)号：US5304686A

    公开(公告)日：1994-04-19

    申请号：US91107

    申请日：1993-07-13

    申请人： Lynn H. Slaugh ,  Juan P. Arhancet

    发明人： Lynn H. Slaugh ,  Juan P. Arhancet

    IPC分类号： C07C29/16 ,  C07C31/20 ,  C07C45/58 ,  C07C47/19

    CPC分类号： C07C31/20 ,  C07C29/141 ,  C07C45/58

    摘要： This invention relates to a process for making 3-hydroxypropanal by intimately contacting(a) ethylene oxide,(b) ditertiary phosphine-modified cobalt carbonyl catalyst, said phosphine being a hydrocarbylene-bis(monophosphabicyclononane) in which each phosphorus atom is joined to hydrocarbylene and is a member of a bridge linkage without being a bridgehead atom and which hydrocarbylene-bis(monophosphabicyclononane) has 18 to 50 carbon atoms, 8 carbon atoms thereof together with a phosphorus atom being members of each of the two bicyclic skeletal structures,(c) a catalyst promoter comprising an acid and a metal salt promoter selected from a salt of a metal of Group IIA, Group IIB, Group IIIB and the Rare Earth Series of the Periodic Table of the Elements (CAS version),(d) carbon monoxide, and(e) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6,in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi. The use of the acid/metal salt promoter enhances the activity of the catalyst.

    摘要翻译： 本发明涉及一种通过使（a）环氧乙烷紧密接触来制备3-羟基丙醛的方法，（b）二膦膦改性的羰基钴催化剂，所述膦是其中每个磷原子连接到亚烃基的亚烃基 - 二（单磷酰基二环壬烷） 并且是桥联原子的成员，而不是桥头原子，并且亚烃基 - 双（单磷杂二环壬烷）具有18至50个碳原子，其8个碳原子和作为两个双环骨架结构中的每一个的成员的磷原子（c ）催化剂促进剂，其包含酸和选自IIA族，IIB族，IIIB族的金属和元素周期表的稀土系列（CAS版）的金属盐助催化剂，（d）一氧化碳 ，和（e）氢气，一氧化碳与氢的摩尔比约为4:1至约1:6，在惰性反应溶剂中的液相溶液中，温度为约30℃。 至约150℃和约50psi至约10,000psi的压力。 酸/金属盐助催化剂的使用增强了催化剂的活性。