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21.发明授权Process for producing pyridine derivatives having a trifluoromethyl group at .beta.-position thereof 失效制备其β-位具有三氟甲基的吡啶衍生物的方法
公开(公告)号：US4288599A
公开(公告)日：1981-09-08
申请号：US124757
申请日：1980-02-26
IPC分类号： C07D213/26 , C07D213/61
CPC分类号： C07D213/61 , C07D213/26
摘要： Pyridine derivatives having a trifluoromethyl group at .beta.-position thereof are produced by reacting .beta.-picoline with chlorine and hydrogen fluoride in a vapor phase at high temperature for a short time. The reaction condition can be mild and the yield of the object compound is increased by reacting them in the presence of a specific metal fluodie. The pyridine derivatives useful as starting materials for agricultural chemicals and medicines can be continuously obtained by a simple reaction at high yield.
摘要翻译： 在β-位上具有三氟甲基的吡啶衍生物是通过使β-哌啶与氯和氟化氢在高温下在气相中短时间反应来制备的。 反应条件可以是温和的，并且通过在特定的金属荧光体存在下使它们反应来增加目标化合物的产率。 用作农药和药物原料的吡啶衍生物可通过简单的高收率反应连续获得。
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公开(公告)号：US4241213A
公开(公告)日：1980-12-23
申请号：US75022
申请日：1979-09-13
申请人： Ryuzo Nishiyama , Kanichi Fujikawa , Isao Yokomichi , Rikuo Nasu , Takao Awazu , Junichi Kawashima
发明人： Ryuzo Nishiyama , Kanichi Fujikawa , Isao Yokomichi , Rikuo Nasu , Takao Awazu , Junichi Kawashima
IPC分类号： C07D213/26 , C07D213/61 , C07D213/64
CPC分类号： C07D213/61
摘要： 2-Chloro-5-trichloromethyl pyridine is produced by reacting .beta.-picoline with chlorine in a gaseous phase at 300.degree. to 500.degree. C. in the presence of an inert diluent of nitrogen, a halogenated methane, a halogenated ethane a halogenated ethylene or a mixture thereof. 2-Chloro-5-trichloromethyl pyridine is useful as an intermediate for medicines, agricultural chemicals, dyes especially herbicides.
摘要翻译： 2-甲基-5-三氯甲基吡啶是在惰性稀释氮气，卤代甲烷，卤代乙烷，卤化乙烯或卤代乙烷的存在下，在300〜500℃下，使β-吡啶啉与氯气在氯气中反应生成的 它们的混合物。 2-氯-5-三氯甲基吡啶可用作药物，农药，染料，特别是除草剂的中间体。
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公开(公告)号：US3950435A
公开(公告)日：1976-04-13
申请号：US561994
申请日：1975-03-25
IPC分类号： C07C205/38 , C07C43/22
CPC分类号： C07C205/38
摘要： A herbicidal compund having the formula: ##SPC1##Wherein R represents allyloxy or (2-propynyl) oxy group.
摘要翻译： 具有下式的除草化合物：WHERE R R表示烯丙氧基或（2-丙炔基）氧基。
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公开(公告)号：US4563529A
公开(公告)日：1986-01-07
申请号：US270567
申请日：1981-06-04
IPC分类号： B01J27/00 , C07D213/26 , C07D213/61 , C07D211/72
CPC分类号： C07D213/61 , C07D213/26
摘要： A trifluoromethylpyridine selected from the group consisting of .alpha.-trifluoromethylpyridine, .gamma.-trifluoromethylpyridine, a bis(trifluoromethyl)pyridine and chlorides thereof which have 1 to 3 chlorine atoms in its pyridine nucleus is produced by reacting a pyridine derivative selected from the group consisting of .alpha.-picoline, .gamma.-picoline and a lutidine with chlorine and anhydrous hydrogen fluoride at a temperature of 300.degree. to 600.degree. C. in a vapor phase in the presence of a diluent and a catalyst comprising a fluoride of a metallic element selected from the group consisting of aluminum, chromium, iron, nickel, manganese, cobalt and copper.
摘要翻译： 选自α-三氟甲基吡啶，γ-三氟甲基吡啶，双（三氟甲基）吡啶及其吡啶核中具有1至3个氯原子的氯化物的三氟甲基吡啶通过使选自以下的吡啶衍生物 - 甲基吡啶，γ-甲基吡啶和二甲基吡啶与氯和无水氟化氢在温度为300℃至600℃的气相中，在稀释剂和包含选自以下的金属元素的氟化物的催化剂存在下， 由铝，铬，铁，镍，锰，钴和铜组成。
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公开(公告)号：US4417055A
公开(公告)日：1983-11-22
申请号：US356528
申请日：1982-03-09
IPC分类号： B01J27/00 , B01J27/12 , C07B61/00 , C07D213/26 , C07D213/61
CPC分类号： C07D213/61 , C07D213/26
摘要： A pyridine derivative having the formula ##STR1## wherein X.sup.2 and Y.sup.2 represents hydrogen atom or chlorine atom is produced by reacting a pyridine compound having the formula ##STR2## wherein X.sup.1 and Y.sup.1 represent hydrogen atom or chlorine atom, with chlorine and anhydrous hydrogen fluoride by a vapor phase reaction in the presence of a catalyst at a temperature of 250.degree. to 600.degree. C. using as the catalyst a fluoride of a metal selected from the group consisting of copper, vanadium, tin, bismuth, zirconium, magnesium, barium, zinc, calcium, potassium and sodium.
摘要翻译： 通过使具有式“IMAGE”的吡啶化合物（其中X1和Y1代表氢原子或氯原子）与氯和无水氟化氢反应，其中X2和Y2表示氢原子或氯原子，其中X2和Y2表示氢原子或氯原子的吡啶衍生物通过 在250℃〜600℃的温度下，在催化剂存在下进行气相反应，使用选自铜，钒，锡，铋，锆，镁，钡等的金属的氟化物作为催化剂， 锌，钙，钾和钠。
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26.发明授权Process for producing 3,5-dichloroaniline from 1-bromo-2,4-dichlorobenzene 失效从1-溴-2,4-二氯苯制备3,5-二氯苯胺的方法
公开(公告)号：US4138436A
公开(公告)日：1979-02-06
申请号：US819389
申请日：1977-07-27
申请人： Ryuzo Nishiyama , Kanichi Fujikawa , Isao Yokomichi , Yasuhiro Tsujii , Kuniaki Nagatani , Shigeyuki Nishimura
发明人： Ryuzo Nishiyama , Kanichi Fujikawa , Isao Yokomichi , Yasuhiro Tsujii , Kuniaki Nagatani , Shigeyuki Nishimura
IPC分类号： C07C211/52 , C07C67/00 , C07C209/00 , C07C209/10 , C07C85/04
CPC分类号： C07C209/10
摘要： 3,5-Dichloroaniline is advantageously produced by reacting 1-bromo-2,4-dichlorobenzene with a metal amide in liquid ammonia at a molar ratio of 1-bromo-2,4-dichlorobenzene to the metal amide of 1 : 2 to 7.The 3,5-dichloroaniline is useful as an intermediate for various agricultural chemicals, dyes and medicines.
摘要翻译： 3,5-二氯苯胺有利地通过使1-溴-2,4-二氯苯与液氨中的金属酰胺以1-溴-2,4-二氯苯的摩尔比与金属酰胺的比例为1:2至7 。
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公开(公告)号：US4266064A
公开(公告)日：1981-05-05
申请号：US127468
申请日：1980-03-05
IPC分类号： C07D213/61 , C07D213/26
CPC分类号： C07D213/61
摘要： A chloro .beta.-trifluoromethylpyridine is produced by reacting a chloro .beta.-trichloromethylpyridine with hydrogen fluoride in the presence of a specific metal fluoride in a vapor phase at high temperature for a short time. The chloro .beta.-trifluoromethylpyridines which are useful as intermediates for agricultural chemicals and medicines can be obtained at high yield.
摘要翻译： 通过在特定金属氟化物存在下，在高温下在短时间内在气相中使氯代三氯甲基吡啶与氟化氢反应来制备氯代β-三氟甲基吡啶。 可用于农药和药物中间体的氯代β-三氟甲基吡啶可以高产率获得。
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公开(公告)号：US4420618A
公开(公告)日：1983-12-13
申请号：US401744
申请日：1982-07-26
申请人： Isao Yokomichi , Takahiro Haga , Rikuo Nasu , Kuniaki Nagatani , Toshio Nakajima
发明人： Isao Yokomichi , Takahiro Haga , Rikuo Nasu , Kuniaki Nagatani , Toshio Nakajima
IPC分类号： B01J27/00 , B01J27/10 , B01J27/128 , B01J27/132 , B01J27/135 , C07B61/00 , C07D213/61 , C07D213/26
CPC分类号： C07D213/61
摘要： 5,6-Dichloro-.beta.-trifluoromethylpyridine or 2,5,6-trichloro-.beta.-trifluoromethylpyridine is produced by reacting 6-chloro-.beta.-trifluoromethylpyridine or 2,6-dichloro-.beta.-trifluoromethylpyridine with chlorine gas to chlorinate the 5-position of pyridine nucleus thereof:(1) at a temperature of 100.degree. C. to 250.degree. C. and at least sufficient amount of chlorine for the reaction;(2) in the presence of the catalyst of amount of at least 40% by weight (based on the 6-chloro or/and 2,6-dichloro-.beta.-trifluoromethylpyridine), the catalyst being chlorides a metallic element selected from the group consisting of iron, tungsten, molybdenum, titanium, and antimony.
摘要翻译： 通过6-氯-β-三氟甲基吡啶或2,6-二氯-α-三氟甲基吡啶与氯气反应生成5,6-二氯-β-三氟甲基吡啶或2,5,6-三氯-β-三氟甲基吡啶， 吡啶核的位置：（1）在100℃至250℃的温度和至少足够量的氯用于反应; （2）在催化剂存在下，至少40重量％（基于6-氯或/和2,6-二氯-β-三氟甲基吡啶），催化剂是氯化物，选自下组的金属元素 由铁，钨，钼，钛和锑组成。
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29.发明授权Phenoxybutyltriazole compound, agricultural and horticultural fungicidal composition containing the same, and process for producing the same 失效苯氧基丁基三唑化合物，含有其的农业和园艺杀真菌组合物及其制备方法
公开(公告)号：US4399143A
公开(公告)日：1983-08-16
申请号：US305676
申请日：1981-09-25
IPC分类号： A01N43/50 , A01N43/653 , C07D213/64 , C07D233/60 , C07D249/08 , C07D401/12 , C07D401/14 , C07D521/00 , A01N43/64
CPC分类号： C07D213/64 , A01N43/653 , C07D231/12 , C07D233/56 , C07D249/08
摘要： A phenoxybutyltriazole compound represented by the following formula (I): ##STR1## wherein X is a halogen atom, a phenyl group or a 5-trifluoromethylpyridine-2-yloxy group; Y is a halogen atom or a trifluoromethyl group; Q is a >C.dbd.O group or a >CH--OH group; A is a >CH-- group or a nitrogen atom; and m and n are each an integer of 0 to 2, or a salt thereof, which is useful as an active ingredient for agricultural and horticultural fungicides, is disclosed. A process for producing the compound of the formula (I) is also disclosed.
摘要翻译： 由下式（I）表示的苯氧基丁基三唑化合物：其中X是卤素原子，苯基或5-三氟甲基吡啶-2-基氧基; Y是卤原子或三氟甲基; Q是> C = O基或> CH-OH基; A是一个> CH-基团或一个氮原子; 并且m和n各自为0〜2的整数，或其盐，其可用作农业和园艺杀真菌剂的有效成分。 还公开了制备式（I）化合物的方法。
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公开(公告)号：US4349681A
公开(公告)日：1982-09-14
申请号：US218971
申请日：1980-12-22
IPC分类号： H04B10/572 , A01N43/40 , A01N47/36 , C07D213/73 , C07D213/74 , C07D213/75 , H03G3/20 , H03G3/30 , H04B10/00 , H04B10/07 , H04B10/2507 , H04B10/293 , H04B10/524 , H04B10/564 , H04B10/58 , C07D213/72 , C07D211/72
CPC分类号： C07D213/73 , A01N43/40 , A01N47/36 , C07D213/74 , C07D213/75
摘要： A novel compound, 2-amino-trifluoromethyl-halogenopyridine, is provided, which is prepared by amination of a 2-halogeno-trifluoromethyl-halogenopyridine or by halogenation of 2-amino-trifluoromethylpyridine. This compound is useful as an intermediate for synthesis of agricultural chemicals and medicines.
摘要翻译： 提供了2-氨基 - 三氟甲基 - 卤代吡啶的新化合物，其通过2-卤代三氟甲基 - 卤代吡啶的胺化或通过2-氨基 - 三氟甲基吡啶的卤化制备。 该化合物可用作合成农药和药物的中间体。
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