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公开(公告)号：US5871815A
公开(公告)日：1999-02-16
申请号：US891813
申请日：1997-07-14
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C17/30 , C03C17/42 , C09D4/00 , C09D5/24 , C09K3/16 , H01J2229/8632 , Y10S428/91 , Y10T428/1317 , Y10T428/1393 , Y10T428/261 , Y10T428/268 , Y10T428/31536 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： An antistatic film comprising a chemically adsorbed film of straight chain molecules each containing a conductive group and provided on a chargeable substrate via covalent bonds each containing a Si group, said chemically adsorbed film having a conductivity of 10.sup.-10 S/cm or above. With the antistatic chemically adsorbed film according to the invention, conductive functional groups are secured via chemically adsorbed molecules and by siloxane bonds to the surface of a substrate material such as ceramics, glass, synthetic resins or synthetic fibers, a film, a plate, an display screen surface, a light-emitting tube. Thus, the film provides an antistatic effect and does not separate. In addition, this chemically adsorbed film has a thickness at the nanometer level and is thus excellently transparent, as well as capable of preventing contamination of the substrate surface due to charging thereof. The film is also excellently durable. Further, when a chemically adsorbed polymer film is formed, a high molecular density, chemically adsorbed film can be obtained.
摘要翻译： 一种抗静电膜，其包含各自含有导电性基团的直链分子的化学吸附膜，并且通过各自含有Si基团的共价键在带电性基板上提供，所述化学吸附膜的导电率为10〜10S / cm以上。 根据本发明的抗静电化学吸附膜，通过化学吸附分子和硅氧烷键将导电官能团固定在基材材料如陶瓷，玻璃，合成树脂或合成纤维的表面上，膜，板， 显示屏表面，发光管。 因此，该胶片提供抗静电效果并且不分离。 此外，该化学吸附膜的厚度为纳米级，因此具有优异的透明性，并且能够防止由于其充电而导致的基板表面的污染。 这部电影也非常耐用。 此外，当形成化学吸附的聚合物膜时，可以获得高分子密度的化学吸附膜。
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公开(公告)号：US5695836A
公开(公告)日：1997-12-09
申请号：US500014
申请日：1995-07-10
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C17/30 , C03C17/42 , C09D4/00 , C09D5/24 , C09K3/16 , H01J2229/8632 , Y10S428/91 , Y10T428/1317 , Y10T428/1393 , Y10T428/261 , Y10T428/268 , Y10T428/31536 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： An antistatic film comprising a chemically adsorbed film of straight chain molecules each containing a conductive group and provided on a chargeable substrate via covalent bonds each containing a Si group, said chemically adsorbed film having a conductivity of 10.sup.-10 S/cm or above. With the antistatic chemically adsorbed film according to the invention, conductive functional groups are secured via chemically adsorbed molecules and by siloxane bonds to the surface of a substrate material such as ceramics, glass, synthetic resins or synthetic fibers, a film, a plate, an display screen surface, a light-emitting tube. Thus, the film provides an antistatic effect and does not separate. In addition, this chemically adsorbed film has a thickness at the nanometer level and is thus excellently transparent, as well as capable of preventing contamination of the substrate surface due to charging thereof. The film is also excellently durable. Further, when a chemically adsorbed polymer film is formed, a high molecular density, chemically adsorbed film can be obtained.
摘要翻译： 一种抗静电膜，其包含各自含有导电性基团的直链分子的化学吸附膜，并且通过各自含有Si基团的共价键在带电性基板上提供，所述化学吸附膜的导电率为10〜10S / cm以上。 根据本发明的抗静电化学吸附膜，通过化学吸附分子和硅氧烷键将导电官能团固定在基材材料如陶瓷，玻璃，合成树脂或合成纤维的表面上，膜，板， 显示屏表面，发光管。 因此，该胶片提供抗静电效果并且不分离。 此外，该化学吸附膜的厚度为纳米级，因此具有优异的透明性，并且能够防止由于其充电而导致的基板表面的污染。 这部电影也非常耐用。 此外，当形成化学吸附的聚合物膜时，可以获得高分子密度的化学吸附膜。
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23.发明授权
公开(公告)号：US5614263A
公开(公告)日：1997-03-25
申请号：US443328
申请日：1995-05-17
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , B05D1/185 , B29D11/00865 , B82Y40/00 , G02B1/10 , Y10T428/261 , Y10T428/31663 , Y10T428/31667
摘要： A chemically adsorbed film containing hydrophilic groups is formed on a substrate such that it is chemically bonded by Si covalent bonds to the substrate. The adsorbed film has an improved hydrophilic property. In addition,the film provides an excellently durable and transparent fog-proof substrate. According to the method of the invention, a substrate containing hydrophilic groups is contacted with a non-aqueous solution containing a surface active material having straight chain molecules each having at one end a chlorosilyl group and at the other end at least one functional group selected from the group consisting of a bromo group, iodo group, cyano group, thiocyano group, chlorosilyl group etc. to cause a dehydrochlorination reaction between hydrophilic groups on the substrate surface and chlorosilyl groups of the surface active material, thereby forming a chemically adsorbed film on the substrate surface. The functional group at the other end of the surface active material is converted into at least one hydrophilic group selected from the group consisting of --OH, --COOH, --NH.sub.2, .dbd.NH, --N.sup.+ R.sub.3 X.sup.- (X representing a halogen atom, R represents a loner alkyl group), --NO.sub.2, --SH, and --SO.sub.3 H groups.
摘要翻译： 在基板上形成含有亲水基团的化学吸附膜，使其通过Si共价键与基材进行化学键合。 吸附的膜具有改善的亲水性。 此外，该膜还提供了耐用和透明的防雾基材。 根据本发明的方法，将含有亲水基团的基材与含有直链分子的表面活性物质的非水溶液接触，所述表面活性物质的一端各自具有氯甲硅烷基，另一端与至少一个选自 由溴基，碘基，氰基，硫氰基，氯代甲硅烷基等组成的基团，从而在基材表面的亲水基团与表面活性物质的氯甲硅烷基之间产生脱氯化氢反应，从而在 基材表面。 将表面活性物质的另一端的官能团转化为至少一种选自-OH，-COOH，-NH 2，= NH，-N + R 3 X - （X表示卤素原子， R表示孤立烷基），-NO 2，-SH和-SO 3 H基。
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24.发明授权
公开(公告)号：US5587209A
公开(公告)日：1996-12-24
申请号：US438875
申请日：1995-05-10
申请人： Mamoru Soga , Norihisa Mino , Kazufumi Ogawa , Yusuke Mochizuki , Tsuneo Shibata
发明人： Mamoru Soga , Norihisa Mino , Kazufumi Ogawa , Yusuke Mochizuki , Tsuneo Shibata
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C09D4/00 , Y10T428/31536 , Y10T428/3154 , Y10T428/31663
摘要： The invention seeks to provide a substrate such as metal, ceramic, plastic, and glass material having a fluorine-based coating film having strong adhesion to a surface of the substrate. The substrate material comprises a monomolecular or polymer adsorption film formed on a base substrate surface and having siloxane bonds and a fluorine-based coating film provided on the adsorption film. The invention also seeks to provide a method of manufacturing a substrate material having a fluorine coating, which is simple and does not involve any electrolytic etching step. The method comprises a step of forming a monomolecular or polymer adsorbed film having --Si-- bonds from dehydrochlorination or dealchoholation the bonded on the substrate surface and causing a silane-based surface active material, capable of reaction with an active hydrogen, to be brought in contact with the substrate surface, and laminating a fluorine-based polymer bonded by a cross-linking reaction process on the adsorbed film.
摘要翻译： 本发明寻求提供具有对基材表面具有强粘合性的氟基涂膜的金属，陶瓷，塑料和玻璃材料的基材。 基板材料包括在基底表面上形成并具有硅氧烷键的单分子或聚合物吸附膜和设置在吸附膜上的氟基涂膜。 本发明还寻求提供一种制造具有氟涂层的基材的方法，其简单且不涉及任何电解蚀刻步骤。 该方法包括从基板表面上结合的脱氯化氢或去氢化形成具有-Si-键的单分子或聚合物吸附膜的步骤，并引起能够与活性氢反应的硅烷类表面活性物质 与基板表面接触，并且通过交联反应工艺粘合的氟基聚合物在吸附膜上层压。
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公开(公告)号：US5580605A
公开(公告)日：1996-12-03
申请号：US431578
申请日：1995-05-01
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C17/30 , C03C2217/76
摘要： At least one monomolecule film is formed on a transparent substrate surface directly or via a protective film. The monomolecule film is formed with chemical coupling of chlorosilane surface active compound, for example, of the formula:F(CF.sub.2).sub.m (CH.sub.2).sub.n SiR.sub.q X.sub.3-qwhere m is an integer of from 1 to 15, n is an integer of from 0 to 15 provided that the total of m and n is an integer of from 10 to 30 and R is an alkyl or an alkoxyl group, orF(CF.sub.2).sub.m' (CH.sub.2).sub.n' A(CH.sub.2).sub.p SiR.sub.q X.sub.3-qwhere m' represents an integer ranging from 1 to 8, n' represents an integer ranging from 0 to 2, p represents an integer ranging from 5 to 25, q represents an integer ranging from 0 to 2, X represents a halogen atom or an alkoxyl group, R represents an alkyl or an alkoxyl group, and A represents --O--, a --COO-- or --Si(CH.sub.3).sub.2 --. The transparent substrate such as glass is made hydrophobic and free of contamination.
摘要翻译： 至少一个单分子膜直接或通过保护膜形成在透明基板表面上。 单分子膜由氯硅烷表面活性化合物的化学偶合形成，例如下式：F（CF 2）m（CH 2）n SiR q X 3-q，其中m为1至15的整数，n为0的整数 至15，其中m和n为10-30的整数，R为烷基或烷氧基，或F（CF 2）m'（CH 2）n'A（CH 2）p SiR q X 3-q其中m' 表示1〜8的整数，n'表示0〜2的整数，p表示5〜25的整数，q表示0〜2的整数，X表示卤素原子或烷氧基， R表示烷基或烷氧基，A表示-O-，-COO-或-Si（CH 3）2 - 。 透明基板如玻璃被制成疏水性并且没有污染。
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公开(公告)号：US5397597A
公开(公告)日：1995-03-14
申请号：US92871
申请日：1993-07-19
申请人： Mamoru Soga , Shinji Ozaki , Norihisa Mino , Kazufumi Ogawa
发明人： Mamoru Soga , Shinji Ozaki , Norihisa Mino , Kazufumi Ogawa
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , G11B7/252 , G11B7/2542 , G11B7/26 , G11B2007/24316 , G11B2007/2432 , G11B2007/25706 , G11B2007/25708 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715 , G11B7/2534 , G11B7/2545 , Y10S428/913 , Y10T428/31663
摘要： A chemically adsorbed film containing fluorocarbon groups is formed on an optical recording medium. Thus, an excellently water- and moisture-proof optical recording medium can be obtained. The optical recording medium is obtained by forming a chemically adsorbed film composed of fluorocarbon chain surface active material. The chemically adsorbed film is chemically bonded via siloxane covalent bonds. In the method of manufacture, an optical recording medium, e.g., an optical recording disk, is contacted with a solution which is made by dissolving a straight carbon chain surface active material having a chlorosilyl group at one end and a fluorocarbon group at the other end in a non-aqueous solvent or a gaseous phase condition, thereby chemically bonding the chlorosilane-based straight chain surface active material to the surface of the substrate via covalent siloxane bonds.
摘要翻译： 在光记录介质上形成含氟碳基团的化学吸附膜。 因此，可以获得优异的防水和防湿光学记录介质。 通过形成由氟碳链表面活性物质构成的化学吸附膜获得光记录介质。 化学吸附的膜通过硅氧烷共价键化学键合。 在制造方法中，将光记录介质（例如光记录盘）与通过溶解在一端具有氯甲硅烷基的直链碳链表面活性材料和另一端的氟碳基团而制成的溶液 在非水溶剂或气相条件下，通过共价硅氧烷键将基于氯硅烷的直链表面活性材料化学键合到基材的表面。
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公开(公告)号：US5372888A
公开(公告)日：1994-12-13
申请号：US831486
申请日：1992-02-05
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
CPC分类号： B82Y30/00 , A61L33/0088 , B05D1/185 , B82Y40/00 , B82Y5/00 , C09D4/00 , Y10T428/31544 , Y10T428/31612 , Y10T428/31699
摘要： Disclosed is an ornament with a thin film formed on the ornament surface. The thin film includes a fluorocarbon-based adsorbed monomolecular film, and the thin film is covalently bonded to the ornament. By contacting the ornament with the non-aqueous solution containing a chlorosilane group at one end and a fluorocarbon chain at the other end, a reaction occurs between hydroxyl groups at the ornament surface and the chlorosilyl groups of the material having a plurality of chlorosilyl groups. A monomolecular film which is covalently bonded to the ornament surface is thereby obtained. A thin, fluorine-containing, monomolecular film thus can be formed on the ornament such that it is chemically bonded to the ornament. The film is anti-contaminating, water- and oil-repelling, durable and does not spoil the intrinsic luster of the ornament.
摘要翻译： 公开了一种在装饰表面上形成有薄膜的装饰品。 薄膜包括氟碳基吸附单分子膜，并且该薄膜与装饰物共价键合。 通过使装饰物与一端含有氯硅烷基的非水溶液和另一端的碳氟化合物链接触，在装饰表面的羟基和具有多个氯甲硅烷基的材料的氯甲硅烷基之间发生反应。 由此获得共价键合到装饰表面的单分子膜。 因此，可以在装饰品上形成薄的含氟单分子膜，使其与装饰物化学结合。 该胶片具有防污，防水和防油，耐用，不会破坏装饰品的内在光泽。
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公开(公告)号：US5268211A
公开(公告)日：1993-12-07
申请号：US848914
申请日：1992-03-10
申请人： Mamoru Soga , Shinji Ozaki , Norihisa Mino , Kazufumi Ogawa
发明人： Mamoru Soga , Shinji Ozaki , Norihisa Mino , Kazufumi Ogawa
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , G11B7/252 , G11B7/2542 , G11B7/26 , G11B2007/24316 , G11B2007/2432 , G11B2007/25706 , G11B2007/25708 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715 , G11B7/2534 , G11B7/2545 , Y10S428/913 , Y10T428/31663
摘要： A chemically adsorbed film containing fluorocarbon groups is formed on an optical recording medium. Thus, an excellently water- and moisture-proof optical recording medium can be obtained. The optical recording medium is obtained by forming a chemically adsorbed film composed of fluorocarbon chain surface active material. The chemically adsorbed film is chemically bonded via siloxane covalent bonds. In the method of manufacture, an optical recording medium, e.g., an optical recording disk, is contacted with a solution which is made by dissolving a straight carbon chain surface active material having a chlorosilyl group at one end and a fluorocarbon group at the other end in a non-aqueous solvent or a gaseous phase condition, thereby chemically bonding the chlorosilane-based straight chain surface active material to the surface of the substrate via covalent siloxane bonds.
摘要翻译： 在光记录介质上形成含氟碳基团的化学吸附膜。 因此，可以获得优异的防水和防湿光学记录介质。 通过形成由氟碳链表面活性物质构成的化学吸附膜获得光记录介质。 化学吸附的膜通过硅氧烷共价键化学键合。 在制造方法中，将光记录介质（例如光记录盘）与通过溶解在一端具有氯甲硅烷基的直链碳链表面活性材料和另一端的氟碳基团而制成的溶液 在非水溶剂或气相条件下，通过共价硅氧烷键将基于氯硅烷的直链表面活性材料化学键合到基材的表面。
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公开(公告)号：US06503567B2
公开(公告)日：2003-01-07
申请号：US09804854
申请日：2001-03-13
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D138
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C17/30 , Y10T428/261 , Y10T428/3154 , Y10T428/31612 , Y10T428/31663
摘要： At least one monomolecule film is formed on a transparent substrate surface directly or via a protective film. The monomolecule film is formed with chemical coupling of chlorosilane surface active compound, for example, of the formula: F(CF2)m(CH2)nSiRqX3—q where m is an integer of from 1 to 15, n is an integer of from 0 to 15 provided that the total of m and n is an integer of from 10 to 30 and R is an alkyl or an alkoxyl group, or F(CF2)m′(CH2)n′A(CH2)pSiRqX3−q where m represents an integer ranging from 1 to 8, n′ represents an integer ranging from 0 to 2, p represents an integer ranging from 5 to 25, q represents an integer ranging from 0 to 2, X represents a halogen atom or an alkoxyl group, R represents an alkyl or an alkoxyl group, and A represents —O—, a —COO— or —Si(CH3)2—. The transparent substrate such as glass is made hydrophobic and free of contamination.
摘要翻译： 至少一个单分子膜直接或通过保护膜形成在透明基板表面上。 单分子膜由氯硅烷表面活性化合物的化学偶合形成，例如下式：其中m为1至15的整数，n为0至15的整数，条件是m和n的总和为 10〜30的整数，R为烷基或烷氧基，m表示1〜8的整数，n'表示0〜2的整数，p表示5〜25的整数，q表示 表示0〜2的整数，X表示卤素原子或烷氧基，R表示烷基或烷氧基，A表示-O-，-COO-或-Si（CH 3）2 - 。 透明基板如玻璃被制成疏水性并且没有污染。
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公开(公告)号：US5629088A
公开(公告)日：1997-05-13
申请号：US426477
申请日：1995-04-20
申请人： Kazufumi Ogawa , Mamoru Soga , Norihisa Mino
发明人： Kazufumi Ogawa , Mamoru Soga , Norihisa Mino
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C08J7/047 , C09D4/00 , D06M10/00 , D06M15/643 , D06M23/005 , C08J2483/00 , Y10T428/252 , Y10T428/2918 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964 , Y10T428/31623 , Y10T428/31663 , Y10T428/31678
摘要： According to the invention, a durable hydrophilic absorbed film is formed on the surface of a substrate including metals, glass, plastics and the like in which the substrate has a surface layer containing hydroxyl groups or imino groups. The film is formed by covalently bonding chemical absorbents of silane groups containing a pluralilty of chloro groups to the substrate surfaces. The substrate 1 such as glass or nylon is dipped and held in a non-aqueous solution containing fluorocarbon groups and hydrocarbon groups containing chemical absorbents of silane groups containing a plurality of chloro groups including SiCl.sub.4, Cl.sub.3 SiOSiCl.sub.3, HSiCl.sub.3 or Cl.sub.3 SiOSiCl.sub.2 OSiCl.sub.3. After taking out the substrate 1 from the solution, drying it in a low moisture or substantially moistureless atmosphere to remove said non-aqueous solvents, the substrate is exposed to the air. A hydrophilic adsorbed ultra-thin film is thus formed by a dehydrochlorination reaction.
摘要翻译： 根据本发明，在包括金属，玻璃，塑料等的基板的表面上形成耐久的亲水性吸收膜，其中基板具有含有羟基或亚氨基的表面层。 该膜通过将含有多个氯基团的硅烷基团的化学吸收剂共价键合到基底表面而形成。 将基板1如玻璃或尼龙浸渍并保持在含氟碳基团的非水溶液中，并且含有含有多个氯基团的硅烷基团的化学吸收剂的烃基包括SiCl 4，Cl 3 SiOSiCl 3，HSiCl 3或Cl 3 SiOSiCl 2 OSiCl 3。 从溶液中取出基材1后，将其在低水分或基本无水的气氛中干燥以除去所述非水溶剂，将基材暴露于空气中。 因此，通过脱氯化氢反应形成亲水吸附的超薄膜。
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