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公开(公告)号：US20100108879A1
公开(公告)日：2010-05-06
申请号：US12514972
申请日：2007-11-15
IPC分类号： H01J49/26
CPC分类号： H01J49/4215 , G01N27/622 , H01J49/004 , H01J49/426
摘要： A mass spectrometer is disclosed comprising an ion mobility spectrometer (8) and an ion gate (9). A collision cell (10) is arranged downstream of the ion gate (9). The operation of the ion mobility spectrometer (8) and the ion gate (9) are synchronised so that only ions having a particular mass to charge ratio and a desired charge state are onwardly transmitted to the collision cell (10).
摘要翻译： 公开了一种质谱仪，其包括离子迁移谱仪（8）和离子门（9）。 碰撞室（10）布置在离子门（9）的下游。 离子迁移谱仪（8）和离子浇口（9）的操作是同步的，使得只有具有特定质荷比的离子和期望的电荷状态向上传输到碰撞池（10）。
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公开(公告)号：US07622711B2
公开(公告)日：2009-11-24
申请号：US11574554
申请日：2005-09-14
IPC分类号： B01D59/44
CPC分类号： H01J49/005
摘要： A mass spectrometer is disclosed comprising an ion mobility spectrometer or separator (3) arranged upstream of a collision or fragmentation cell (5). Ions are separated according to their ion mobility within the ion mobility spectrometer or separator (3). The kinetic energy of the ions exiting the ion mobility spectrometer or separator (3) is increased substantially linearly with time in order to optimize the fragmentation energy of ions as they enter the collision or fragmentation cell (5).
摘要翻译： 公开了一种质谱仪，其包括设置在碰撞或破碎电池（5）的上游的离子迁移谱仪或分离器（3）。 离子在离子迁移谱仪或分离器（3）内根据其离子迁移率分离。 离子离子迁移谱仪或分离器（3）离子的动能随时间呈线性增加，以优化离子进入碰撞或破碎电池（5）时的碎裂能。
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公开(公告)号：US20090014641A1
公开(公告)日：2009-01-15
申请号：US12094561
申请日：2006-12-07
IPC分类号： B01D59/44
CPC分类号： G01N27/622 , H01J49/062
摘要： A closed-loop ion guide (1) is disclosed comprising a plurality of electrodes having apertures through which ions are transmitted in use. Ions are injected into the closed-loop ion guide (1) and may make several circuits of the closed-loop ion guide (1) before being ejected from the ion guide (1). In a mode of operation the ion guide (1) may be arranged to separate ions temporally according to their ion mobility.
摘要翻译： 公开了一种闭环离子导向器（1），其包括具有孔的多个电极，在使用中通过该孔具有离子。 离子被注入到闭环离子导向器（1）中，并且可以在从离子导向器（1）喷射之前制造闭环离子导向器（1）的几个电路。 在操作模式中，离子导向器（1）可以被布置成根据离子迁移率暂时分离离子。
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公开(公告)号：US09673031B2
公开(公告)日：2017-06-06
申请号：US12302177
申请日：2007-06-01
申请人： Robert Harold Bateman , Jeffery Mark Brown , Martin Green , Jason Lee Wildgoose , Anthony James Gilbert , Steven Derek Pringle
发明人： Robert Harold Bateman , Jeffery Mark Brown , Martin Green , Jason Lee Wildgoose , Anthony James Gilbert , Steven Derek Pringle
IPC分类号： H01J49/00
CPC分类号： H01J49/0036
摘要： A mass spectrometer is disclosed comprising a Time of Flight mass analyzer comprising an ion detector comprising an Analog to Digital Converter. Signals from the Analog to Digital Converter are digitized and the arrival time and intensity of ions are determined. The arrival time T0 and intensity S0 of each ion arrival event is converted into two separate intensities S(n),S(n+i) which are stored in neighboring time bins T(n), T(n+1).
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公开(公告)号：US08354634B2
公开(公告)日：2013-01-15
申请号：US12601094
申请日：2008-05-22
CPC分类号： H01J49/0036 , H01J49/40
摘要： A mass spectrometer is disclosed wherein an ion signal is split into a first and second signal. The first and second signals are multiplied by different gains and are digitised. Arrival time and intensity pairs are calculated for both digitised signals and the resulting time and intensity pairs are combined to form a high dynamic range spectrum. The spectrum is then combined with other corresponding spectra to form a summed spectrum.
摘要翻译： 公开了一种质谱仪，其中离子信号被分成第一和第二信号。 第一和第二信号乘以不同的增益并被数字化。 对于两个数字化信号计算到达时间和强度对，并且将所得到的时间和强度对组合以形成高动态范围谱。 然后将光谱与其他对应的光谱组合以形成相加光谱。
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公开(公告)号：US07919747B2
公开(公告)日：2011-04-05
申请号：US12297481
申请日：2007-04-30
CPC分类号： H01J49/065 , H01J49/0031 , H01J49/022 , H01J49/062 , H01J49/36 , H01J49/4235 , Y10T436/24
摘要： An ion guide or mass analyser (2) is disclosed comprising a plurality of electrodes (2a) having apertures through which ions are transmitted in use. A pseudo-potential barrier is created at the exit of the ion guide or mass analyser (2). The amplitude or depth of the pseudo-potential barrier is inversely proportional to the mass to charge ratio of an ion. One or more transient DC voltages (4) are applied to the electrodes (2a) of the ion guide or mass analyser (2) in order to urge ions along the length of the ion guides or mass analyser (2). The amplitude of the transient DC voltage (4) applied to the electrode (2a) may be increased with time so that ions are caused to be emitted from the ion guide or mass analyser (2) in reverse order of their mass to charge ratio.
摘要翻译： 公开了一种离子导向器或质量分析器（2），其包括具有孔的多个电极（2a），在使用中通过该孔具有离子。 在离子导向器或质量分析器（2）的出口处产生伪势垒。 伪势垒的幅度或深度与离子的质荷比成反比。 一个或多个瞬态DC电压（4）被施加到离子导向器或质量分析器（2）的电极（2a），以促使沿着离子导向器或质量分析器（2）的长度的离子。 施加到电极（2a）的瞬态直流电压（4）的振幅可以随时间增加，从而离子引导或质量分析器（2）以与其质荷比相反的顺序发射离子。
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公开(公告)号：US20100001180A1
公开(公告)日：2010-01-07
申请号：US12302168
申请日：2007-06-01
申请人： Robert Harold Bateman , Jeffery Mark Brown , Martin Green , Jason Lee Wildgoose , Anthony James Gilbert , Steven Derek Pringle
发明人： Robert Harold Bateman , Jeffery Mark Brown , Martin Green , Jason Lee Wildgoose , Anthony James Gilbert , Steven Derek Pringle
CPC分类号： H01J49/0036 , G06K9/0053
摘要： A Time of Flight mass analyser is disclosed comprising an ion detector comprising an Analogue to Digital Converter. Output signals from the ion detector are digitised and the arrival times and intensity values relating to ion arrival events are determined. If the determined arrival times from two signals fall within the same time window then the arrival times are added together in a weighted manner and the intensity values are combined.
摘要翻译： 公开了一种飞行时间质量分析仪，其包括离子检测器，该离子检测器包括模数转换器。 来自离子检测器的输出信号被数字化，确定与离子到达事件有关的到达时间和强度值。 如果从两个信号确定的到达时间落在相同的时间窗口内，则以加权的方式将到达时间相加在一起并且强度值被组合。
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28.发明授权Time of flight mass spectrometer with analog to digital converter and method of using 有权具有模数转换器的飞行时间质谱仪及其使用方法公开(公告)号：US08809767B2
公开(公告)日：2014-08-19
申请号：US12302168
申请日：2007-06-01
申请人： Robert Harold Bateman , Jeffery Mark Brown , Martin Green , Jason Lee Wildgoose , Anthony James Gilbert , Steven Derek Pringle
发明人： Robert Harold Bateman , Jeffery Mark Brown , Martin Green , Jason Lee Wildgoose , Anthony James Gilbert , Steven Derek Pringle
CPC分类号： H01J49/0036 , G06K9/0053
摘要： A Time of Flight mass analyser is disclosed comprising an ion detector comprising an Analogue to Digital Converter. Output signals from the ion detector are digitised and the arrival times and intensity values relating to ion arrival events are determined. If the determined arrival times from two signals fall within the same time window then the arrival times are added together in a weighted manner and the intensity values are combined.
摘要翻译： 公开了一种飞行时间质量分析仪，其包括离子检测器，该离子检测器包括模数转换器。 来自离子检测器的输出信号被数字化，确定与离子到达事件有关的到达时间和强度值。 如果从两个信号确定的到达时间落在相同的时间窗口内，则以加权的方式将到达时间相加在一起并且强度值被组合。
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公开(公告)号：US08633435B2
公开(公告)日：2014-01-21
申请号：US12445774
申请日：2007-10-16
申请人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
发明人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
CPC分类号： H01J49/005 , H01J49/0031 , H01J49/004 , H01J49/0045 , H01J49/065 , H01J49/34 , H01J49/4235
摘要： A collision or fragmentation cell is disclosed comprising a plurality of electrodes wherein a first RF voltage is applied to an upstream group of electrodes and a second different RF voltage is applied to a downstream group of electrodes. The radial confinement of parent ions entering the collision or fragmentation cell is optimized by the first RF voltage applied to the upstream group of electrodes and the radial confinement of daughter or fragment ions produced within the collision or fragmentation cell is optimized by the second different RF voltage applied to the downstream group of electrodes.
摘要翻译： 公开了包括多个电极的碰撞或分裂单元，其中将第一RF电压施加到上游电极组，并且将第二不同的RF电压施加到下游电极组。 通过施加到上游电极组的第一RF电压来优化进入碰撞或破碎电池的母体离子的径向约束，并且通过第二不同RF电压优化在碰撞或断裂电池内产生的子或碎片离子的径向约束 应用于下游电极组。
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公开(公告)号：US20110180704A1
公开(公告)日：2011-07-28
申请号：US13078198
申请日：2011-04-01
CPC分类号： H01J49/065 , H01J49/0031 , H01J49/022 , H01J49/062 , H01J49/36 , H01J49/4235 , Y10T436/24
摘要： An ion guide or mass analyser is disclosed comprising a plurality of electrodes having apertures through which ions are transmitted in use. A pseudo-potential barrier is created at the exit of the ion guide or mass analyser. The amplitude or depth of the pseudo-potential barrier is inversely proportional to the mass to charge ratio of an ion. One or more transient DC voltages are applied to the electrodes of the ion guide or mass analyser in order to urge ions along the length of the ion guides or mass analyser. The amplitude of the transient DC voltage applied to the electrode may be increased with time so that ions are caused to be emitted from the ion guide or mass analyser in reverse order of their mass to charge ratio.
摘要翻译： 公开了一种离子导向器或质量分析器，其包括具有孔的多个电极，在使用中离子传播通过该孔。 在离子导向器或质量分析器的出口处产生伪势垒。 伪势垒的幅度或深度与离子的质荷比成反比。 一个或多个瞬态直流电压被施加到离子导向器或质量分析器的电极，以沿着离子导向器或质量分析器的长度推动离子。 施加到电极的瞬态直流电压的幅度可以随时间增加，使得离子从离子导向器或质量分析器以其质荷比的相反顺序被发射。
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