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公开(公告)号：US4435607A
公开(公告)日：1984-03-06
申请号：US421628
申请日：1982-09-22
申请人： Tamotsu Imai
发明人： Tamotsu Imai
CPC分类号： C07C15/46 , C07C5/322 , C07C5/3332 , C07C5/48 , Y02P20/128
摘要： Dehydrogenatable hydrocarbons may be subjected to a dehydrogenation reaction in which the hydrocarbons are treated with a dehydrogenation catalyst such as a modified iron compound in the presence of steam in a multi-catalyst bed system. The reaction mixture containing unconverted hydrocarbon, dehydrogenated hydrocarbon, hydrogen and steam is then contacted with a selective oxidation catalyst such as a noble metal of Group VIII of the Periodic Table, a metal of Group IVA of the Periodic Table and, if so desired, a metal of Group IA or IIA of the Periodic Table composited on a highly porous inorganic support. The oxidation catalyst will selectively oxidize the hydrogen to improve the combustion thereof and supply the necessary heat required for a subsequent dehydrogenation treatment.
摘要翻译： 可脱氢烃可以进行脱氢反应，其中烃在多催化剂床系统中在蒸汽存在下用脱氢催化剂如改性铁化合物处理。 然后将含有未转化的烃，脱氢烃，氢气和蒸汽的反应混合物与选择性氧化催化剂如周期表第VIII族的贵金属，元素周期表IVA族的金属接触，如果需要，将 在高度多孔无机载体上复合的元素周期表IA或IIA族金属。 氧化催化剂将选择性地氧化氢气以改善其燃烧并提供随后的脱氢处理所需的必要热量。
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公开(公告)号：US4430517A
公开(公告)日：1984-02-07
申请号：US477699
申请日：1983-03-22
申请人： Tamotsu Imai , Chi-Wen Hung
发明人： Tamotsu Imai , Chi-Wen Hung
CPC分类号： C07C5/3337 , B01J23/56 , B01J23/622 , C07C5/325 , Y02P20/52
摘要： This invention relates to a new catalyst for converting hydrocarbons. The catalyst comprises a platinum group component, a Group IVA component, especially tin, an alkali or alkaline earth component, more than 0.2 weight %, calculated on an elemental basis, of a halogen component and a porous carrier material, wherein the atomic ratio of the alkali or alkaline earth component to the platinum group component is more than 10. The catalyst is particularly useful for dehydrogenating paraffins having from 2 to 5 or more carbon atoms to the corresponding mono-olefins, or for dehydrogenating mono-olefins having from 3 to 5 or more carbon atoms to the corresponding di-olefins.
摘要翻译： 本发明涉及用于转化烃的新型催化剂。 该催化剂包括基于元素计算的大于0.2重量％的卤素组分和多孔载体材料的铂族组分，特别是锡，碱金属或碱土金属组分，特别是锡，碱金属或碱土金属组分，其中原子比 铂族组分的碱金属或碱土金属成分大于10.该催化剂特别适用于将具有2至5个或更多个碳原子的链烷烃脱氢成相应的单烯烃，或将脱氢的单烯烃脱氢为3〜 5个或更多碳原子与相应的二烯烃。
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公开(公告)号：US4418237A
公开(公告)日：1983-11-29
申请号：US380796
申请日：1982-05-21
申请人： Tamotsu Imai
发明人： Tamotsu Imai
摘要： Dehydrogenatable hydrocarbons may be subjected to a dehydrogenation process in which a dehydrogenatable hydrocarbon is contacted with a dehydrogenation catalyst at dehydrogenation conditions in the presence of steam. The resulting mixture of undehydrogenated dehydrogenatable hydrocarbon, dehydrogenated hydrocarbon, hydrogen and steam is contacted with an oxygen-containing gas in the presence of an oxidative catalyst comprising a noble metal of Group VIII of the Periodic Table and a metal cation which possesses an ionic radius no less than about 1.35 Angstroms composited on a porous alumina support.
摘要翻译： 可脱氢烃可以进行脱氢过程，其中可脱氢烃在脱氢条件下在蒸汽存在下与脱氢催化剂接触。 在含有元素周期表第Ⅷ族贵金属的氧化催化剂存在下，将所得到的未脱氢的可脱氢烃，脱氢烃，氢气和蒸汽的混合物与含氧气体接触，并且具有离子半径无 小于约1.35埃复合在多孔氧化铝载体上。
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公开(公告)号：US4357479A
公开(公告)日：1982-11-02
申请号：US308705
申请日：1981-10-05
申请人： Tamotsu Imai
发明人： Tamotsu Imai
摘要： The production of alcohols in which an olefinic hydrocarbon is hydrated with a liquid water in the presence of an aqueous sulfur-containing acid catalyst such as sulfuric acid may be improved by effecting the reaction in the presence of a solid, porous carbon support which will act as the co-catalyst or promoter. The hydration reactions which are employed for the process will include a temperature in the range of from about 100.degree. to about 300.degree. C. and a pressure in the range of from about 1 to about 300 atmospheres.
摘要翻译： 在含硫的含硫酸催化剂如硫酸的存在下，用液态水合成烯烃的醇的生产可以通过在固体多孔碳载体的存在下进行反应来改善，所述固体多孔碳载体将起作用 作为助催化剂或助催化剂。 用于该方法的水合反应将包括约100℃至约300℃的温度和约1至约300个大气压的压力。
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公开(公告)号：US4339617A
公开(公告)日：1982-07-13
申请号：US241868
申请日：1981-03-09
申请人： Tamotsu Imai , Robert J. Schmidt
发明人： Tamotsu Imai , Robert J. Schmidt
CPC分类号： C07C29/04
摘要： Olefinic hydrocarbons may be hydrated to form corresponding alcohols by treating said olefins with water in the presence of an acidic compound which acts as a catalyst, said hydration reaction being effected at a temperature in the range of from about 100.degree. to about 300.degree. C. and a pressure in the range of from about 1 to about 100 atmospheres. In addition, the reaction medium also contains a salt of a metal selected from the group consisting of magnesium, barium, beryllium and radium, said metal salts suppressing the corrosive nature of the acid catalyst and thus permitting the reaction to be effected in normal metal reactors.
摘要翻译： 在作为催化剂的酸性化合物存在下，通过用水处理所述烯烃，烯烃可以水合形成相应的醇，所述水合反应在约100℃至约300℃的温度下进行。 压力范围为约1至约100个大气压。 此外，反应介质还含有选自镁，钡，铍和镭的金属盐，所述金属盐抑制酸催化剂的腐蚀性质，从而允许反应在常规金属反应器中进行 。
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公开(公告)号：US4250115A
公开(公告)日：1981-02-10
申请号：US971282
申请日：1978-12-20
申请人： Tamotsu Imai
发明人： Tamotsu Imai
IPC分类号： C07C209/60 , C07C85/18
CPC分类号： C07C209/60 , Y02P20/582
摘要： Tertiary amines may be prepared by reacting an olefinic compound, carbon monoxide, hydrogen and a nitrogen-containing compound such as ammonia, a primary amine or a secondary amine in the presence of a rhodium or ruthenium-containing catalyst at temperatures in the range of from about 50.degree. to about 350.degree. C. and a pressure in the range of from about 10 to about 300 atmospheres.
摘要翻译： 叔胺可以通过使烯属化合物，一氧化碳，氢和含氮化合物如氨，伯胺或仲胺在铑或钌催化剂存在下，在 约50℃至约350℃，压力范围为约10至约300大气压。
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27.发明授权
公开(公告)号：US5043509A
公开(公告)日：1991-08-27
申请号：US395939
申请日：1989-08-18
CPC分类号： C07C2/70 , B01J27/16 , B01J35/023 , C07C2/18 , B01J35/026 , C07C2521/08 , C07C2527/173
摘要： Catalyst particles which are employed in reactions involving the conversion of organic compounds should possess a desired configuration in order to maintain a desired voidage which will permit passage of the feedstock through the catalyst bed during the conversion reaction. Solid phosphoric acid catalysts which comprise an admixture of an acid of phosphorus and a solid binder such as a siliceous material may be formed into polylobular, tubular, ridged, fluted, or channeled cylindrical particles which will permit a sufficient amount of voidage in the catalyst bed to be maintained even though the catalyst particles will swell during the reaction due to the formation of coke on the surface thereof.
摘要翻译： 在涉及有机化合物转化的反应中使用的催化剂颗粒应具有所需的构型，以保持所需的空隙率，这将允许原料在转化反应期间通过催化剂床。 包含磷的酸和诸如硅质材料的固体粘合剂的混合物的固体磷酸催化剂可以形成为多叶状，管状，脊状，槽纹或通道的圆柱形颗粒，这将允许催化剂床中足够的空隙率 即使催化剂颗粒在反应期间由于在其表面上形成焦炭而溶胀而被保持。
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公开(公告)号：US5003121A
公开(公告)日：1991-03-26
申请号：US399044
申请日：1989-08-28
申请人： Tamotsu Imai , Joseph A. Kocal
发明人： Tamotsu Imai , Joseph A. Kocal
CPC分类号： B01J21/16 , B01J37/0201 , C07C2/66 , C07C2/861 , C07C2/864 , C07C2521/02 , C07C2521/06 , C07C2521/16 , C07C2523/10 , Y02P20/582
摘要： Alkyl aromatic compounds may be prepared by reacting an aromatic compound with an alkylating agent such as an olefin in the presence of an alkylation catalyst. The alkylation catalyst of the present invention comprises a composite which has been prepared by coextruding a clay component and at least one multi-valent metal component in which the metal is selected from the group consisting of Groups IIIA, IIIB and IVB of the Periodic Table, followed by drying the resultant extrudate and calcination thereof. By utilizing a catalyst which has been prepared by this method in an alkylation reaction it is possible to obtain an improved alkylate selectivity.
摘要翻译： 烷基芳族化合物可以通过在烷基化催化剂的存在下使芳族化合物与烷基化剂如烯烃反应来制备。 本发明的烷基化催化剂包括通过共挤出粘土组分和至少一种多价金属组分制备的复合材料，其中金属选自周期表的IIIA，IIIB和IVB族组， 然后干燥所得挤出物并进行煅烧。 通过利用在烷基化反应中通过该方法制备的催化剂，可以获得改进的烷基化物选择性。
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公开(公告)号：US4795851A
公开(公告)日：1989-01-03
申请号：US132450
申请日：1987-12-14
申请人： Robert R. Frame , Tamotsu Imai
发明人： Robert R. Frame , Tamotsu Imai
IPC分类号： B01J23/835 , B01J31/14 , B01J31/28 , C07C2/20 , C07C2/30 , C07C11/107
CPC分类号： C07C2/30 , B01J23/835 , B01J31/143 , B01J31/28 , B01J2231/20 , C07C2521/04 , C07C2521/08 , C07C2523/14 , C07C2523/745 , C07C2523/755 , C07C2531/14 , C07C2531/26 , C07C2531/28
摘要： Olefinic feedstocks which contain catalyst contaminants or poisons such as sulfur-containing compounds may be oligomerized to a desired oligomer and configuration of the oligomer by utilizing a catalyst which is stable and will not deactivate due to the presence of the aforementioned poisons. The catalyst comprises a porous support which has been impregnated with a catalytically effective amount of an iron group metal compound and a Group IVA metal compound. In addition, the catalyst composite may also contain in combination therewith, a catalytically effective amount of an alkyl aluminum compound and an aluminum alkoxy/aluminum halide compound. The catalyst of this invention is prepared by impregnating a porous support with an aqueous solution containing an iron group metal salt and a Group IVA metal salt, calcining and containing the calcined support with a solution containing an alkyl aluminum compound.
摘要翻译： 含有催化剂污染物或毒素如含硫化合物的含烯烃原料可以通过利用稳定的催化剂低聚而成为低聚物，并且由于上述毒物的存在而不会失活。 催化剂包括已经浸渍有催化有效量的铁族金属化合物和IVA族金属化合物的多孔载体。 此外，催化剂复合材料还可以与其组合含有催化有效量的烷基铝化合物和铝烷氧基/卤化铝化合物。 本发明的催化剂是通过用含有铁基金属盐和IVA族金属盐的水溶液浸渍多孔载体来制备的，用含有烷基铝化合物的溶液煅烧并含有煅烧载体。
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公开(公告)号：US4788371A
公开(公告)日：1988-11-29
申请号：US139690
申请日：1987-12-30
申请人： Tamotsu Imai , Deng-Yang Jan
发明人： Tamotsu Imai , Deng-Yang Jan
IPC分类号： C10G27/04 , B01J23/58 , B01J23/62 , C07B61/00 , C07C5/48 , C07C11/06 , C07C15/46 , C10G35/085 , C07C4/02 , C07C5/09 , C07C5/333
摘要： A novel process is disclosed for the steam dehydrogenation of dehydrogenatable hydrocarbons in the vapor phase in conjunction with oxidative reheating of the intermediate products. The process utilizes a single catalyst to perform both the selective oxidation and steam dehydrogenation functions. The particular catalyst employed comprises a Group VIII noble metal component, a Group IA and/or a Group IIA component and may contain among other modifiers a Group IIIA or IVA metal, and a halogen component. The catalytic components are supported on an inorganic substrate such as alumina.
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