公开(公告)号：US4957724A

公开(公告)日：1990-09-18

申请号：US171348

申请日：1988-03-21

Applicant: Freimut Marold ,  Michael Heisel

Inventor： Freimut Marold ,  Michael Heisel

IPC: C01B17/04

CPC classification number: C01B17/0439 ,  C01B17/0469 ,  Y02P20/584

Abstract: A process and apparatus for conducting a catalytic reaction of H.sub.2 S and SO.sub.2 to elementary sulfur provides for at least two catalyst beds and that at least one part of one of the catalyst beds is operated during the reaction at below the sulfur dew point, preferably below the solids condensation point, and above the water dew point. The adsorbed and deposited sulfur is removed by heating and evaporation. At least two serially connected and interchangeable reactors are employed in preferably a single flow direction in one cycle, and the flow direction of the gas stream is reversed in a second cycle by means of a multiway fitting.

Abstract translation: 用于进行H 2 S和SO 2对元素硫的催化反应的方法和装置提供至少两个催化剂床，并且催化剂床中的至少一部分在反应期间在硫露点以下，优选低于 固体凝结点，以上水露点。 通过加热和蒸发除去吸附和沉积的硫。 在一个循环中优选使用至少两个串联和可互换的反应器，优选地单一流动方向，并且通过多道配件在第二循环中使气流的流动方向反转。

公开(公告)号：US4530827A

公开(公告)日：1985-07-23

申请号：US545427

申请日：1983-10-26

Applicant: Michael Heisel ,  Gerhard Ranke

Inventor： Michael Heisel ,  Gerhard Ranke

IPC: C01B17/04 ,  B01D53/14 ,  B01D53/52 ,  C01B17/05 ,  C10K1/16

CPC classification number: B01D53/523 ,  C01B17/05 ,  C10K1/16

Abstract: A process for the simultaneous removal of H.sub.2 S, SO.sub.2 and elemental sulfur from gaseous mixtures, comprises treating the gaseous mixture with a solvent. After the solvent becomes loaded with the components to be removed, it is regenerated and reused. In order to obtain savings in costs and energy, the sulfur is separated from the loaded solvent by lowering the temperature thereof. In this way, chemical regeneration of the scrubbing medium takes place within the cycle eliminating the requirement for outside regenerating apparatus.

Abstract translation: 从气体混合物中同时除去H 2 S，SO 2和元素硫的方法包括用溶剂处理气态混合物。 溶剂加载待除去的组分后，再次再生再利用。 为了节省成本和能量，通过降低其温度将硫与负载的溶剂分离。 以这种方式，洗涤介质的化学再生在循环内进行，消除了对外部再生装置的要求。

公开(公告)号：US4425317A

公开(公告)日：1984-01-10

申请号：US328554

申请日：1981-12-08

Applicant: Rainer Zeller ,  Aldo Belloni ,  Michael Heisel

Inventor： Rainer Zeller ,  Aldo Belloni ,  Michael Heisel

IPC: B01D53/52 ,  B01D53/14 ,  B01D53/34 ,  B01D53/77 ,  C01B17/04 ,  C01B17/16 ,  C01B17/00

CPC classification number: B01D53/1462 ,  C01B17/0456 ,  Y02C10/06 ,  Y02P20/152

Abstract: In a process for the separation of at least carbon dioxide and hydrogen sulfide from a raw gaseous mixture to form a purified gaseous mixture comprising passing said gas through a sour gas removal system including the steps of scrubbing said gaseous mixture with a liquid scrubbing agent having a higher affinity for hydrogen sulfide than for carbon dioxide, removing from said system an off-gas enriched in hydrogen sulfide, and passing said off-gas to a sulfur recovery system comprising the conversion of sulfur values to elemental sulfur and the recovery of a tail gas containing hydrogen sulfide and sulfur dioxide,the improvement which comprises hydrogenating said tail gas to convert sulfur dioxide to hydrogen sulfide and recycling resultant hydrogenated tail gas to said sour gas removal system, whereby essentially no hydrogen sulfide or sulfur dioxide is discharged into the environment.

Abstract translation: 在用于从原始气体混合物中分离至少二氧化碳和硫化氢以形成纯化的气体混合物的方法中，包括使所述气体通过酸性气体去除系统，所述气体混合物包括用液体洗涤剂洗涤所述气体混合物的步骤，所述液体洗涤剂具有 对硫化氢的亲合力高于二氧化碳，从所述系统中除去富含硫化氢的废气，并将所述废气送至硫回收系统，硫回收系统包括将硫值转化为元素硫并回收尾气 含有硫化氢和二氧化硫的改进包括使所述尾气氢化以将二氧化硫转化为硫化氢，并将所得氢化尾气再循环到所述酸性气体去除系统，由此基本上不将硫化氢或二氧化硫排放到环境中。