-
公开(公告)号：US5660807A
公开(公告)日：1997-08-26
申请号：US553588
申请日：1996-05-13
Applicant: Wolfgang Forg , Gerhard Ranke , Michael Heisel , Dietrich Maschmeyer , Robert Walter
Inventor： Wolfgang Forg , Gerhard Ranke , Michael Heisel , Dietrich Maschmeyer , Robert Walter
CPC classification number: B01J23/26 , B01D53/8603 , B01D53/8621 , C01B3/58 , C10K1/34 , B01D2257/308 , B01D2257/408 , C01B2203/045 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485
Abstract: The invention relates to a process for the removal of HCN from gas mixtures that contain at least HCN and sulfur compounds, especially from gas mixtures that are obtained by partial oxidation of hydrocarbons, by catalytic decomposition of HCN, as well as a catalyst for the decomposition of HCN. According to the invention, the gas mixture is brought into contact with a catalyst which decomposes the HCN by hydrogenation and/or by hydrolysis and COS that is contained in the gas mixture is decomposed at least partially in this catalyst by hydrolysis. Advantageously, a catalyst that is based on titanium oxide and/or zirconium oxide as a vehicle and that contains chromium oxide as an active component is used. Advantageously, the catalyst is reduced during catalyst production or before use with H.sub.2 and/or a reducing gas at temperatures above the operating temperature of catalytic decomposition.
Abstract translation: PCT No.PCT / EP94 / 01646 Sec。 371日期：1996年5月13日 102（e）日期1996年5月13日PCT提交1994年5月20日PCT公布。 出版物WO94 / 29004 日期1994年12月22日本发明涉及从气体混合物中除去HCN的方法，所述气体混合物至少含有HCN和硫化合物，特别是通过烃的部分氧化获得的气体混合物，HCN的催化分解以及 用于分解HCN的催化剂。 根据本发明，使气体混合物与通过氢化和/或水解分解HCN的催化剂接触，并且气体混合物中包含的COS至少部分地通过水解在该催化剂中分解。 有利地，使用基于氧化钛和/或氧化锆作为载体并且含有氧化铬作为活性组分的催化剂。 有利地，催化剂在催化剂生产期间或在高于催化分解操作温度的温度下用H2和/或还原气体使用之前被还原。
-
2.发明授权Process for the simultaneous removal of H.sub.2 S, SO.sub.2 and elemental sulfur from gaseous mixtures 失效同时从气体混合物中除去H 2 S，SO 2和元素硫的方法
公开(公告)号：US4530827A
公开(公告)日：1985-07-23
申请号：US545427
申请日：1983-10-26
Applicant: Michael Heisel , Gerhard Ranke
Inventor： Michael Heisel , Gerhard Ranke
CPC classification number: B01D53/523 , C01B17/05 , C10K1/16
Abstract: A process for the simultaneous removal of H.sub.2 S, SO.sub.2 and elemental sulfur from gaseous mixtures, comprises treating the gaseous mixture with a solvent. After the solvent becomes loaded with the components to be removed, it is regenerated and reused. In order to obtain savings in costs and energy, the sulfur is separated from the loaded solvent by lowering the temperature thereof. In this way, chemical regeneration of the scrubbing medium takes place within the cycle eliminating the requirement for outside regenerating apparatus.
Abstract translation: 从气体混合物中同时除去H 2 S，SO 2和元素硫的方法包括用溶剂处理气态混合物。 溶剂加载待除去的组分后，再次再生再利用。 为了节省成本和能量，通过降低其温度将硫与负载的溶剂分离。 以这种方式，洗涤介质的化学再生在循环内进行，消除了对外部再生装置的要求。
-
3.发明授权Process for obtaining C.sub.2+ or C.sub.3+ hydrocarbons from gaseous mixtures 失效从气体混合物中获得C2 +或C3 +烃的方法
公开(公告)号：US4713940A
公开(公告)日：1987-12-22
申请号：US927986
申请日：1986-11-07
Applicant: Gerhard Ranke , Friedrich Siegert
Inventor： Gerhard Ranke , Friedrich Siegert
CPC classification number: C07C7/11
Abstract: A process is disclosed for obtaining C.sub.2+ or C.sub.3+ hydrocarbons from hydrocarbon-containing gaseous mixtures by pressure scrubbing with a physically acting solvent selective for C.sub.2+ and, respectively, C.sub.3+ hydrocarbons. The solvent, after loading, is regenerated and reused. In order to avoid impurities in the C.sub.2+ and, respectively, C.sub.3+ product in an economical and energy-saving way, the loaded solvent is subjected to expansion to a pressure lying below the critical pressure of the solvent-gas mixture, and to heating and partial evaporation in order to drive off concomitantly dissolved inert gases. The solvent, reduced in its content of inert gases, is then to be passed on to regeneration. The process is advantageous, in particular, in cases where crude gases are to be processed which exhibit a low concentration of components to be scrubbed out.
Abstract translation: 公开了一种用于通过用对C2 +和分别为C3 +烃选择性的物理作用溶剂的压力洗涤从含烃气体混合物中获得C2 +或C3 +烃的方法。 加载后的溶剂被再生并重复使用。 为了以经济和节能的方式避免C2 +和C3 +产品中的杂质，将负载的溶剂膨胀至低于溶剂 - 气体混合物的临界压力的压力，并加热和部分 蒸发以排除伴随溶解的惰性气体。 然后将其惰性气体含量降低的溶剂传递至再生。 该方法是有利的，特别是在粗制气体被处理的情况下，其表现出低浓度待洗涤的组分。
-
4.发明授权Parallel stream heat exchange for separation of ethane and higher hydrocarbons from a natural or refinery gas 失效用于从天然或炼厂气体分离乙烷和高级烃的平行流热交换
公开(公告)号：US4592766A
公开(公告)日：1986-06-03
申请号：US650016
申请日：1984-09-13
Applicant: Paul Kumman , Gerhard Ranke
Inventor： Paul Kumman , Gerhard Ranke
CPC classification number: F25J3/0238 , C07C7/04 , F25J3/0209 , F25J3/0233 , F25J2200/02 , F25J2200/50 , F25J2200/70 , F25J2205/04 , F25J2210/02 , F25J2240/02 , F25J2245/02 , F25J2270/04 , F25J2270/90
Abstract: For the separation of ethane and higher hydrocarbons from a high pressure incoming gas containing hydrocarbons, the raw gas is cooled and expanded in several stages and the condensates that are produced are fed to a rectifying column to provide an overhead gaseous product essentially consisting of methane and a bottoms product consisting essentially of ethane and higher hydrocarbons. To save energy, the raw gas and/or the product streams are heat exchanged in parallel streams under different pressures, the cooled high-pressure gas is work-expanded and the condensates produced by cooling and expansion are fed separately to the rectifying column.
Abstract translation: 为了从含有烃的高压进入气体中分离乙烷和高级烃，将原料气体在几个阶段中冷却和膨胀，并将生产的冷凝物加入到精馏塔中以提供基本上由甲烷和 基本上由乙烷和高级烃组成的底部产物。 为了节省能源，原料气体和/或产物流在不同压力下以平行流进行热交换，冷却的高压气体被工作膨胀，并且通过冷却和膨胀产生的冷凝物分别供给到精馏塔。
-
5.发明授权Process for regenerating a scrubbing agent loaded with H.sub.2 S and/or COS 失效用于再生装载有H 2 S和/或COS的洗涤剂的方法
公开(公告)号：US5133954A
公开(公告)日：1992-07-28
申请号：US679840
申请日：1991-04-01
Applicant: Gerhard Ranke , Gunter Weber
Inventor： Gerhard Ranke , Gunter Weber
CPC classification number: C01B17/05 , B01D53/1425 , B01D53/1456
Abstract: For regenerating a scrubbing agent loaded with H.sub.2 S and/or COS, as well as optionally with other raw gas components to be recovered, the loaded scrubbing agent is mixed, preferably without prior heating, with an oxidatively acting solvent that is immiscible with the scrubbing agent, and the H.sub.2 S dissolved in the immiscible solvent is converted to elementary sulfur.
Abstract translation: 为了再生装载有H 2 S和/或COS的洗涤剂以及任选地与待回收的其它原料气体组分一起，将加载的洗涤剂优选不经过预先加热与与洗涤剂不混溶的氧化作用溶剂混合 ，溶解在不混溶溶剂中的H 2 S转化为元素硫。
-
Patent Agency Ranking
公开(公告)号：US4810267A
公开(公告)日：1989-03-07
申请号：US871988
申请日：1986-06-09
Applicant: Heiner Landeck , Gerhard Ranke
Inventor： Heiner Landeck , Gerhard Ranke
CPC classification number: C07C7/11
Abstract: For scrubbing C.sub.2+ or C.sub.3+ hydrocarbons from gaseous mixture containing hydrocarbons and/or inerts like H.sub.2 N.sub.2, CO and possibly acid gases, e.g. CO.sub.2 H.sub.2 S, COS e.g. natural gas and the like, the scrubbing medium consists essentially of compounds having one to two rings formed by 5 or 6 carbon atoms, wherein the compounds comprise, in total, at least 9 and at most 17 carbon atoms, and the rings are saturated unsaturated or partially saturated especially alkylated ring compounds of 9 or 10 carbon atoms, e.g. isomeric forms of trimethylbenzene, propylbenzene, propylcyclohexane, tetrahydronaphthalene, decahydronaphthalene.
-
7.发明授权
公开(公告)号：US4668488A
公开(公告)日：1987-05-26
申请号：US791128
申请日：1985-10-24
Applicant: Gerhard Ranke , Heinz Karwat
Inventor： Gerhard Ranke , Heinz Karwat
CPC classification number: C01B25/027 , B01D53/002 , Y10S62/92
Abstract: Process for the treatment of CO-rich gases incurred in the manufacture of phosphorus, which gases contain impurities like water, and compounds of sulfur, nitrogen and phosphorus. The gas is passed through regenerators for the purpose of removing impurities. In this manner, a product gas is obtained from which impurities have been condensed or frozen.
Abstract translation: 用于处理在制造磷中产生的富含CO的气体的方法，其中气体含有杂质如水，以及硫，氮和磷的化合物。 为了除去杂质，气体通过再生器。 以这种方式，获得产物气体，其中杂质已被冷凝或冷冻。
-
公开(公告)号：US3975172A
公开(公告)日：1976-08-17
申请号：US451044
申请日：1974-03-14
Applicant: Gerhard Ranke
Inventor： Gerhard Ranke
CPC classification number: B01D53/14 , B01D53/1418 , B01D53/1425 , Y02C10/06
Abstract: Process for the recovery of one or more components of a raw gas, absorbed by the scrubbing liquid during a physical gas scrubbing step, by expanding the laden scrubbing liquid, characterized in that the expanded, laden scrubbing liquid is stripped, before its final regeneration, with a gas consisting exclusively of one or more components of the raw gas and essentially free of the components to be recovered and to be scrubbed out.
Abstract translation: 用于在物理气体洗涤步骤期间通过膨胀装载的洗涤液体来回收原料气体的一种或多种组分被洗涤液体吸收的方法，其特征在于，在其最终再生之前剥离膨胀的载满洗涤液体， 其中气体仅由原料气体的一种或多种组分组成，并且基本上不含待回收的组分并被洗涤出来。
-
9.发明授权Process for the selective removal of inorganic and/or organic sulfur compounds 失效选择性去除无机和/或有机硫化合物的方法
公开(公告)号：US5413627A
公开(公告)日：1995-05-09
申请号：US34798
申请日：1993-03-01
Applicant: Heiner Landeck , Gerhard Ranke
Inventor： Heiner Landeck , Gerhard Ranke
CPC classification number: B01D53/14 , B01D53/1425 , B01D53/1493 , C10K1/14
Abstract: For the selective removal of sulfur from gases, a physical scrubbing agent is used, comprising a heterocycle having five or more ring atoms, which contains two heteroatoms, one of which is nitrogen and the other of which is oxygen or nitrogen; and the heteroatoms in the rings of even member number of atoms occupy; one of the positions from 1,2 to 1,n/2 and, in the rings of uneven member number of atoms occupy one of the positions from 1,2 up to 1, (n-1)/2. Further, the nitrogen heteroatom(s) present in the ring is/are either double bonded or single bonded but, if single bonded, the nitrogen is organo-substituted.
Abstract translation: 为了从气体中选择性除去硫，使用物理洗涤剂，其包含具有五个或更多个环原子的杂环，其含有两个杂原子，其中一个是氮，另一个是氧或氮; 并且偶数个原子的环中的杂原子占据; 位置从1,2到1，n / 2之一，并且在不均匀成员数原子的环中占据从1,2到1，（n-1）/ 2的位置之一。 此外，存在于环中的氮杂原子是双键或单键的，但如果单键键合，则氮被有机取代。
-
公开(公告)号：US4797140A
公开(公告)日：1989-01-10
申请号：US896371
申请日：1986-08-14
Applicant: Heiner Landeck , Gerhard Ranke
Inventor： Heiner Landeck , Gerhard Ranke
CPC classification number: C07C7/11
Abstract: For scrubbing C.sub.2+ or C.sub.3+ hydrocarbons from gaseous mixture containing hydrocarbons and/or inerts like H.sub.2' N.sub.2, CO and possibly acid gases, e.g. CO.sub.2 H.sub.2 S, COS e.g., natural gas and the like, the scrubbing medium consists essentially of compounds having one to two rings formed by 5 or 6 carbon atoms, wherein the compounds comprise, in total, at least 9 and at most 17 carbon atoms, and the rings are saturated unsaturated or partially saturated especially alkylated ring compounds of 9 or 10 carbon atoms, e.g. isomeric forms of trimethylbenzene, propylbenzene, propylcyclohexane, tetrahydronaphthalene, decahydronaphthalene.
Abstract translation: 用于从含有碳氢化合物和/或惰性气体的气体混合物（如H2'N2，CO）和可能的酸性气体（例如酸性气体）中洗涤C2 +或C3 +烃。 CO 2 H 2 S，COS例如天然气等，洗涤介质基本上由具有一个或两个由5或6个碳原子形成的环的化合物组成，其中化合物总共包含至少9个且至多17个碳原子，以及 环是饱和的不饱和或部分饱和的，尤其是9或10个碳原子的烷基化环化合物，例如 三甲基苯，丙基苯，丙基环己烷，四氢萘，十氢萘的异构体形式。
-
-
-
-
-
-
-
-
-
Search Results
23
records
(took 0.018 seconds)
