摘要:
The present invention provides an electrode paste which comprises catalyst particles, a solvent and an varnish which comprises a solvent and an electrode electrolyte for a solid polymer fuel cell electrolyte, wherein the electrode electrolyte comprises a polymer with a structure having a main chain including a polyphenylene, a side chain including a sulfonic acid group and a repeating structural unit represented by formula (C) as a side chain including a nitrogen-containing heterocyclic group; wherein the structural variables are defined herein.
摘要:
A membrane-electrode assembly having superior hot water resistance has a membrane containing an aromatic polymer having a repeating unit expressed by general formula (1): in which A represents independently either —CO— or —SO2—; B represents independently an oxygen atom or sulfur atom; R1 to R8, which may be identical or different from each other, represent a hydrogen atom, fluorine atom, alkyl group, phenyl group or nitrile group; R9 to R24, which may be identical or different from each other, represent a hydrogen atom, alkyl group or phenyl group; and ‘a’ represents an integer of 0 to 4.
摘要翻译:具有优异的耐热水性的膜 - 电极组件具有含有具有由通式(1)表示的重复单元的芳族聚合物的膜:其中A独立地表示-CO-或-SO 2 - ; B独立地表示氧原子或硫原子; R 1〜R 8可以相同或不同,表示氢原子,氟原子,烷基,苯基或腈基; R 9〜R 24可以相同或不同,表示氢原子,烷基或苯基; 'a'表示0〜4的整数。
摘要:
A membrane-electrode assembly for a solid polymer electrolyte fuel cell having excellent hot water resistance, oxidation resistance and low temperature size stability and exhibiting excellent power generation performance even under low temperature environment. The membrane-electrode assembly is equipped with a polymer electrolyte membrane composed of a sulfonated polyarylene polymer having a recurring unit of the formula (1) and a recurring unit of the formula (2):
摘要:
A membrane-electrode assembly for solid polymer electrolyte fuel cells, in which a sulfonic acid is an ion exchange group, and the heat resistance is superior, is provided. The membrane-electrode assembly for solid polymer electrolyte fuel cells contains a polymer including a principal chain that forms polyphenylene structure, a branched chain having a sulfonic acid group, and a branched chain having a nitrogen-containing heterocyclic group. It is preferred that a branched chain having a nitrogen-containing heterocyclic group is a structure expressed by the general formula (D) below.
摘要:
Membrane-electrode assemblies are provided having a solid polymer electrolyte membrane that exhibits higher proton conductivity over a wide temperature range, and exhibits superior hot water resistance, chemical stability, toughness and mechanical strength. The membrane-electrode assemblies utilized for solid polymer electrolyte fuel cells include an anode electrode, a cathode electrode and a solid polymer electrolyte membrane, the anode electrode and the cathode electrode disposed on opposite sides of the solid polymer electrolyte membrane. The solid polymer electrolyte membrane contains a polyarylene copolymer with a specific constitutional unit having a fluorine atom and nitrile group introduced in their principal chains.
摘要:
A membrane-electrode assembly for solid polymer electrolyte fuel cells is provided which has a solid polymer electrolyte membrane having a high concentration of protonic acid groups enabling high proton conductivity and high humid condition, along with superior dimensional stability, without the membrane-electrode assembly dissolving in hot water. The membrane-electrode assembly for solid polymer electrolyte fuel cells was formed by using a polymer electrolyte composition consisting of a polymer having a cross-linking structure, this polymer electrolyte composition being obtained from a mixed solution that includes a polymer electrolyte containing a protonic acid group, a compound containing plurality of ethylenic unsaturated groups, and a solvent.
摘要:
The present invention provides a membrane electrode assembly for solid polymer electrolyte fuel cells, which has superior hot water resistance, superior mechanical properties, superior power generating performance, and higher proton conductivity, even when a large number of sulfonic acid groups are introduced. The solid polymer electrolyte membrane has constitutional units expressed by the general formulas (1) and (2).
摘要:
The present invention provides a membrane-electrode assembly excellent in electric power generation performance and durability for use in a solid polymer electrolyte fuel cell and a solid polymer electrolyte fuel cell formed therefrom. The membrane-electrode assembly for use in a solid polymer electrolyte fuel cell has a solid polymer electrolyte membrane 1 sandwiched between a pair of electrodes 2 and 2 each containing a catalyst. The solid polymer electrolyte membrane 1 is formed of a polyarylene polymer including a repeating unit represented by the general formula (1), or a polyarylene copolymer including the repeating unit represented by the general formula (1) and a repeating unit represented by the general formula (2). The solid polymer electrolyte fuel cell includes the membrane-electrode assembly for use in a solid polymer electrolyte fuel cell.
摘要:
A membrane-electrode assembly having superior hot water resistance has a membrane containing an aromatic polymer having a repeating unit expressed by general formula (1): in which A represents independently either —CO— or —SO2—; B represents independently an oxygen atom or sulfur atom; R1 to R8, which may be identical or different from each other, represent a hydrogen atom, fluorine atom, alkyl group, phenyl group or nitrile group; R9 to R24, which may be identical or different from each other, represent a hydrogen atom, alkyl group or phenyl group; and ‘a’ represents an integer of 0 to 4.
摘要翻译:具有优异的耐热水性的膜 - 电极组件具有含有具有由通式(1)表示的重复单元的芳族聚合物的膜:其中A独立地表示-CO-或-SO 2 - ; B独立地表示氧原子或硫原子; R 1至R 8可以相同或不同,表示氢原子,氟原子,烷基,苯基或腈基; R 9〜R 24可以相同或不同,表示氢原子,烷基或苯基; 'a'表示0〜4的整数。
摘要:
Provided is a varnish which contains a solvent and an electrode electrolyte for a solid polymer fuel cell electrolyte, which contains a polymer with a structure having a main chain including a polyphenylene, a side chain including a sulfonic acid group and a repeating structural unit as a side chain including a nitrogen-containing heterocyclic group.