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    Polyarylene, Process For Producing The Same, Solid Polyelectrolyte, And Proton-Conductive Film
    4.
    发明申请
    Polyarylene, Process For Producing The Same, Solid Polyelectrolyte, And Proton-Conductive Film 有权
    聚亚芳基，其制备方法，固体聚电解质和质子导电膜

    公开(公告)号：US20080015389A1

    公开(公告)日：2008-01-17

    申请号：US11815370

    申请日：2005-02-04

    申请人： Yoshitaka Yamakawa ,  Makoto Higami

    发明人： Yoshitaka Yamakawa ,  Makoto Higami

    IPC分类号： C07C301/00

    CPC分类号： C08G61/02 ,  C08G61/12 ,  C08J5/18 ,  C08J2365/02 ,  H01B1/122

    摘要： A polyarylene having a structural unit shown by the following formula (1) is disclosed. wherein X and Y indicate a divalent organic group or a single bond, Z shows an oxygen atom or a sulfur atom, R represents at least one atom or group selected from the group consisting of a hydrogen atom, a fluorine atom, an alkyl group, and a fluorine-substituted alkyl group, a is an integer of 1 to 20, n is an integer of 1 to 5, and p is an integer of 1 to 10.

    摘要翻译： 公开了具有下述通式（1）所示的结构单元的聚亚芳基。 其中X和Y表示二价有机基团或单键，Z表示氧原子或硫原子，R表示至少一个选自氢原子，氟原子，烷基， 氟取代烷基，a为1〜20的整数，n为1〜5的整数，p为1〜10的整数。

    ELECTRODE ELECTROLYTE FOR USE IN SOLID POLYMER FUEL CELL
    5.
    发明申请
    ELECTRODE ELECTROLYTE FOR USE IN SOLID POLYMER FUEL CELL 有权
    用于固体聚合物燃料电池的电极电解质

    公开(公告)号：US20090130526A1

    公开(公告)日：2009-05-21

    申请号：US11995701

    申请日：2006-06-30

    申请人： Makoto Higami ,  Igor Rozhanskii ,  Yoshitaka Yamakawa ,  Nagayuki Kanaoka ,  Kaoru Fukuda ,  Ryoichiro Takahashi ,  Hiroshi Shinkai

    发明人： Makoto Higami ,  Igor Rozhanskii ,  Yoshitaka Yamakawa ,  Nagayuki Kanaoka ,  Kaoru Fukuda ,  Ryoichiro Takahashi ,  Hiroshi Shinkai

    IPC分类号： H01M8/10

    CPC分类号： C08G61/02 ,  C08G73/028 ,  C08J5/2256 ,  C08J2371/12 ,  H01M4/8652 ,  H01M4/8807 ,  H01M4/92 ,  H01M4/926 ,  H01M8/0239 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1048 ,  H01M8/106

    摘要： This invention provides an electrode electrolyte for a solid polymer-type fuel cell, in which a cost problem and a problem related to recovery of catalyst metals are solved, having excellent proton conductivity, dimensional stability and heat resistance.An electrode electrolyte for a solid polymer electrolyte-type fuel cell contains a polymer, which has a polyphenylene structure as a main chain and both a sulfonic acid group and a nitrogen-containing heterocyclic group as a side chain. A side chain having the nitrogen-containing heterocyclic group has a structure represented by the following general formula (D). (In formula, Z represents at least one kind of structures selected from a group consisting of a direct bond, —O— and —S—, Y represents at least one kind of structures selected from a group consisting of —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)1— (1 is an integer of 1 to 10) and —C(CF3)2— and R20 represents a nitrogen-containing heterocyclic group. q represents an integer of 1 to 5 and p represents an integer of 0 to 4.)The above nitrogen-containing heterocyclic group is at least one kind of group derived from a compound selected from the group consisting of nitrogen-containing heterocyclic compounds including pyrrole, thiazole, isothiazole, oxazole, isoxazole, pyridine, imidazole, imidazoline, pyrazole, 1,3,5-triazine, pyrimidine, pyridazine, pyrazine, indole, quinoline, isoquinoline, purine, benzimidazole, benzoxazole, benzothiazole, tetrazole, tetrazine, triazole, carbazole, acridine, quinoxaline and quinazoline and derivatives thereof.

    摘要翻译： 本发明提供一种固体聚合物型燃料电池用电极电解质，其中解决了成本问题和与催化剂金属的回收相关的问题，具有优异的质子传导性，尺寸稳定性和耐热性。 固体高分子电解质型燃料电池用电极电解质含有作为主链的聚亚苯基结构和磺酸基和含氮杂环基作为侧链的聚合物。 具有含氮杂环基的侧链具有由以下通式（D）表示的结构。 （式中，Z表示选自由直链，-O-和-S-组成的组中的至少一种结构，Y表示选自-CO - ， - SO 2的至少一种结构 - ， - SO - ， - CONH - ， - COO - ， - （CF 2）1 - （1为1〜10的整数）和-C（CF 3）2 - ，R 20为含氮杂环基 1〜5的整数，p表示0〜4的整数。）上述含氮杂环基是选自包含吡咯，噻唑等含氮杂环化合物的化合物中的至少一种 异噻唑，恶唑，异恶唑，吡啶，咪唑，咪唑啉，吡唑，1,3,5-三嗪，嘧啶，哒嗪，吡嗪，吲哚，喹啉，异喹啉，嘌呤，苯并咪唑，苯并恶唑，苯并噻唑四唑，四嗪，三唑， ，吖啶，喹喔啉和喹唑啉及其衍生物。

    Catalyst paste composition for electrode
    6.
    发明授权
    Catalyst paste composition for electrode 有权
    用于电极的催化剂浆料组合物

    公开(公告)号：US07060748B2

    公开(公告)日：2006-06-13

    申请号：US10483421

    申请日：2003-05-20

    申请人： Makoto Higami ,  Keiichi Bessho

    发明人： Makoto Higami ,  Keiichi Bessho

    IPC分类号： C08L3/04 ,  C08L3/09 ,  C08L9/00

    CPC分类号： H01M4/8828 ,  H01M4/8605 ,  H01M4/8668 ,  H01M8/1007 ,  H01M8/1018

    摘要： A catalyst paste composition for making electrodes has a uniform dispersion condition of a carbon black supporting a hydrogen reduction catalyst and is excellent in storage stability. The catalyst paste composition comprises a carbon black supporting a hydrogen reduction catalyst, an electrolyte, a water-soluble sulfonated polymer and a solvent.

    摘要翻译： 用于制造电极的催化剂浆料组合物具有支撑氢还原催化剂的炭黑的均匀分散条件，并且储存稳定性优异。 催化剂浆料组合物包含支持氢还原催化剂的炭黑，电解质，水溶性磺化聚合物和溶剂。

    Process of producing electrode paste and electrode paset compositon
    7.
    发明申请
    Process of producing electrode paste and electrode paset compositon 审中-公开
    生产电极膏和电极桩组合物的工艺

    公开(公告)号：US20050026029A1

    公开(公告)日：2005-02-03

    申请号：US10901052

    申请日：2004-07-29

    申请人： Junji Kawai ,  Makoto Higami ,  Kohei Goto ,  Ryoichiro Takahashi ,  Yoichi Asano

    发明人： Junji Kawai ,  Makoto Higami ,  Kohei Goto ,  Ryoichiro Takahashi ,  Yoichi Asano

    IPC分类号： H01M4/86 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10 ,  H01M4/96

    CPC分类号： H01M4/8828 ,  H01M4/8605 ,  H01M4/8652 ,  H01M4/8663 ,  H01M4/8673 ,  H01M4/926

    摘要： A process of producing an electrode paste having excellent storage stability and capable of forming a catalyst layer that has a sufficient pore volume for high generating performance, and an electrode paste composition having such properties are disclosed. The process comprises mixing and agitating carbon black supporting a catalyst metal, a polymer electrolyte, an organic solvent and at least either carbon fiber or water thereby to finely disperse the carbon black to a predetermined mean particle diameter of particles dispersed in the mixed solution, and admixing a dispersant to the mixed solution and agitating the resultant mixture to obtain an electrode paste in which particles having a predetermined mean particle diameter are uniformly dispersed.

    摘要翻译： 公开了一种具有优异的储存稳定性并且能够形成具有足够的孔体积以获得高发生性能的催化剂层的电极糊的方法和具有这种性能的电极糊组合物。 该方法包括混合和搅拌负载催化剂金属的炭黑，聚合物电解质，有机溶剂和至少一种碳纤维或水，从而将炭黑细分散到分散在混合溶液中的预定颗粒直径的颗粒，以及 将分散剂混合到混合溶液中并搅拌所得混合物以获得其中具有预定平均粒径的颗粒均匀分散的电极浆料。

    Process for producing electrolyte membrane-bonded electrode and varnish composition used therein
    8.
    发明申请
    Process for producing electrolyte membrane-bonded electrode and varnish composition used therein 审中-公开

    公开(公告)号：US20060269655A1

    公开(公告)日：2006-11-30

    申请号：US11498173

    申请日：2006-08-03

    申请人： Makoto Higami ,  Kohei Goto ,  Nagayuki Kanaoka ,  Ryoichiro Takahashi ,  Yoichi Asano ,  Osamu Kakutani ,  Gen Okiyama

    发明人： Makoto Higami ,  Kohei Goto ,  Nagayuki Kanaoka ,  Ryoichiro Takahashi ,  Yoichi Asano ,  Osamu Kakutani ,  Gen Okiyama

    IPC分类号： B05D5/12

    CPC分类号： H01M8/1023 ,  H01M4/8605 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1039 ,  H01M8/1053 ,  Y02P70/56

    摘要： The present invention is intended to provide a process for producing an electrolyte membrane-bonded electrode having excellent power generation property when constitutes an electrode assembly, and a varnish composition for an electrolyte, by the use of which an electrolyte membrane-electrode bonded structure capable of retaining excellent power generation property is obtained. A process for producing a first electrolyte membrane-bonded electrode comprises applying, onto an electrode, a water-containing dispersion containing a perfluorosulfonic acid polymer, an organic solvent A and water and having a perfluorosulfonic acid polymer content of 0.5 to 20% by weight and then applying, onto the resulting film, a solution of sulfonated polyarylene in an organic solvent B, to form an electrolyte membrane. A process for producing a second electrolyte membrane-bonded electrode comprises applying, onto an electrode, a solution or dispersion containing a proton-conductive polymer, an organic solvent B and water and having a water content of 25 to 50% by weight and then applying, onto the resulting film, a solution or dispersion containing a proton-conductive polymer, an organic solvent B and water and having a water content of less than 25% by weight, to form an electrolyte membrane. A process for producing a third electrolyte membrane-bonded electrode comprises applying, onto an electrode, a varnish composition 6 obtained by dissolving a sulfonated polymer in a solvent containing an organic solvent C, an organic solvent D and water to form an electrolyte membrane, said organic solvent C being a good solvent for the sulfonated polymer and having a higher boiling point than that of other solvent components, said organic solvent D having a boiling point of not lower than 50° C. and being not a good solvent for the sulfonated polymer when used alone but causing a solubility region of the sulfonated polymer to appear when mixed with the organic solvent C and/or the water. The varnish composition 6 of the invention is a varnish composition obtained by dissolving the sulfonated polymer in a solvent containing an organic solvent C, an organic solvent D and water.

    Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte
    9.
    发明申请
    Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte 有权
    具有含腈疏水嵌段和固体聚合物电解质的磺化聚合物

    公开(公告)号：US20050080220A1

    公开(公告)日：2005-04-14

    申请号：US10958622

    申请日：2004-10-06

    申请人： Yoshitaka Yamakawa ,  Makoto Higami ,  Toshiaki Kadota

    发明人： Yoshitaka Yamakawa ,  Makoto Higami ,  Toshiaki Kadota

    IPC分类号： C08G61/12 ,  C07C255/54 ,  C08G65/00 ,  C08G65/40 ,  C08G65/48 ,  C08J5/22 ,  H01B1/06 ,  H01M8/02 ,  H01M8/10 ,  C08G2/00

    CPC分类号： C07C255/54 ,  C08G61/12 ,  C08G65/40 ,  C08G65/4006 ,  C08G65/48 ,  C08J5/2256 ,  C08J2365/02 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M2300/0082

    摘要： Provided are a sulfonated polymer capable of high hot water resistance even if it has an increased amount of the sulfonic groups introduced therein, and a solid polymer electrolyte containing the sulfonated polymer that has high proton conductivity and excellent generating performance. The sulfonated polymer has repeating units represented by the formula (1′): wherein B's are each independently an oxygen or a sulfur atom, R1 to R3 may be the same or different and are selected from a hydrogen atom, a fluorine atom, a nitrile group and an alkyl group, n is an integer of 2 or greater, and Q is a structure represented by the formula (q): wherein A is independently a divalent atom or organic group or a direct bond, and R4 to R11 may be the same or different and are selected from a hydrogen atom, a fluorine atom, an alkyl group and an aromatic group.

    摘要翻译： 即使其中引入的磺酸基的量增加，也能够具有高耐热水性的磺化聚合物，以及含有高质子传导性和优异发生性能的磺化聚合物的固体高分子电解质。 磺化聚合物具有由式（1'）表示的重复单元：其中B各自独立地为氧或硫原子，R 1至R 3可以相同或不同，并且选自氢原子， 氟原子，腈基和烷基，n为2以上的整数，Q为式（q）所示的结构：其中A独立地为二价原子或有机基团或直接键合，以及 R 4〜R 11可以相同或不同，选自氢原子，氟原子，烷基和芳基。

    Halogenated aromatic compound, polymer thereof, and proton-conductive membrane comprising same
    10.
    发明授权
    Halogenated aromatic compound, polymer thereof, and proton-conductive membrane comprising same 有权
    卤化芳族化合物，其聚合物和包含其的质子传导膜

    公开(公告)号：US06825310B2

    公开(公告)日：2004-11-30

    申请号：US10105213

    申请日：2002-03-26

    申请人： Kohei Goto ,  Masayuki Takahashi ,  Yoshitaka Yamakawa ,  Makoto Higami

    发明人： Kohei Goto ,  Masayuki Takahashi ,  Yoshitaka Yamakawa ,  Makoto Higami

    IPC分类号： C08G6538

    CPC分类号： H01B1/122 ,  C07C45/71 ,  C07C49/84 ,  C07C317/22 ,  C08G61/12 ,  C08G65/40 ,  C08G65/4018 ,  C08G65/4025 ,  C08G75/23 ,  C08J5/2256 ,  C08J2381/06 ,  H01M6/181 ,  H01M2300/0082

    摘要： A polymer which has a flexible structure in its main chain and thus exhibits a high toughness and can difficultly be deteriorated in its mechanical properties and thermal properties even when sulfonated, a sulfonic acid group-containing polymer obtained by the sulfonation of the polymer, and a proton-conductive membrane having an excellent mechanical strength and durability made of the sulfonic acid group-containing polymer. A novel halogenated aromatic compound represented by the following general formula (1m) is provided: wherein A independently represents an electron-withdrawing group; B independently represents an electron-donating atom or group; X represents a chlorine atom, iodine atom or bromine atom; R1 to R8 may be the same or different and each represent a hydrogen atom, fluorine atom or alkyl group; and n represents an integer of 2 or more.

    摘要翻译： 一种聚合物，其主链具有柔性结构，因此即使在磺化时也显示出高的韧性并且难以在其机械性能和热性能上劣化，通过聚合物磺化得到的含磺酸基的聚合物和 质子传导膜具有优异的机械强度和耐久性，由含磺酸基的聚合物制成。 提供由以下通式（1m）表示的新型卤代芳族化合物：其中A独立地表示吸电子基团; B独立地表示给电子原子或基团; X表示氯原子，碘原子或溴原子; R 1至R 8可以相同或不同，各自表示氢原子，氟原子或烷基; n表示2以上的整数。