摘要:
It is an object of the present invention to provide a curable which has good storage stability and can give cured products retaining the high elongation characteristic originating from the polyether polymer and showing a high gel fraction and good weatherability.Thus, the present invention provides a durable compositionwhich comprises the following two components:a polyether polymer having at least one crosslinkable functional group anda vinyl polymerwhich is compatible with said polyether polymer having at least one crosslinkable functional group at a polymer terminus.Further, the present invention provides a curable compositionwhich comprises the following three components:a polyether polymer having at least one crosslinkable functional group,a vinyl polymer incompatible with said polyether polymer and having at least one crosslinkable function group, anda compatibilizing agent capable of compatibilizing said polyether polymer and said vinyl polymer with each other when added to a mixture thereof.
摘要:
The present invention relates to a method for producing a vinyl polymer retaining the ability for atom transfer radical polymerization, a method for reliably producing a vinyl polymer having terminal functional groups, a vinyl polymer having functional groups prepared by these methods, and a curable composition comprising the polymer. A vinyl polymer having terminal functional groups can be reliably produced through the steps of preparing a vinyl polymer by atom transfer radical polymerization of a vinyl monomer in a polymerization solvent in the presence of a polymerization initiator and a transition metal complex functioning as a polymerization catalyst, removing the polymerization solvent and the vinyl monomer while the ability for atom transfer radical polymerization is maintained, and supplying a functional-group-introducing agent having a low polymerizability to introduce a functional group to a polymer terminus.
摘要:
A composition comprising a vinyl polymer having a crosslinkable silyl group may suffer from a delay in curing after the storage. The present invention relates to the following items. A curable composition comprising, as an essential component, (I) a vinyl polymer, which has at least one crosslinkable silyl group at the terminus and also has a monomer containing a methyl ester group as a constituent unit. A sealant, a liquid gasket, and an adhesive, wherein the above curable composition is used. A polymer has at least one crosslinkable functional group at the terminus and also has a vinyl polymer as a main chain thereof, wherein 2% to 80% by weight of monomers based on the total monomers constituting the main chain is methyl acrylate. A curable composition with improved storage stability, which comprises the following two components as essential components: (a) a vinyl polymer having at least one crosslinkable silyl group; and (b) a compound having a methyl ester group other than the compound (a).
摘要:
The present invention has its object to provide an acrylic hot-melt pressure-sensitive adhesive composition showing only small changes in melt viscosity, showing good hot-melt applicability and excellent in initial cohesive force prior to moisture curing, and showing excellent tackiness and thermostable cohesive force after moisture curing.The present invention relates to a acrylic block copolymer which comprises an acrylic polymer block (A) and an acrylic polymer block (B) differing in glass transition temperature range and having at least one crosslinkable functional group (X) at its molecular termini; and a reactive hot-melt adhesive composition which comprises the acrylic block copolymer described above.
摘要:
A first object of the present invention is to provide a vinyl polymer that has a molecular chain into which a structure containing a polar functional group is introduced, and that is useful as a precursor of a graft polymer. A second object of the present invention is to provide a process for producing the vinyl polymer. These objects can be achieved by the present invention providing a vinyl polymer having a polar functional group (X), and further having, at the position of at least one molecular terminal thereof, a group (A) containing a carbon-carbon double bond.
摘要:
It is an object of the present invention to provide a curable which has good storage stability and can give cured products retaining the high elongation characteristic originating from the polyether polymer and showing a high gel fraction and good weatherability. Thus, the present invention provides a curable composition which comprises the following two components: a polyether polymer having at least one crosslinkable functional group and a vinyl polymer which is compatible with said polyether polymer having at least one crosslinkable functional group at a polymer terminus. Further, the present invention provides a curable composition which comprises the following three components: a polyether polymer having at least one crosslinkable functional group, a vinyl polymer incompatible with said polyether polymer and having at least one crosslinkable function group, and a compatibilizing agent capable of compatibilizing said polyether polymer and said vinyl polymer with each other when added to a mixture thereof.
摘要:
An object of the present invention is to provide a novel method for producing a vinyl polymer (P) having a polar functional group (X) and having in its main chain a branched structure. The object can be achieved by the present invention providing a method for producing a vinyl polymer (P) having a polar functional group (X) and having in its main chain a branched structure, wherein while and/or after polymerization of a vinyl polymer (I) having a protecting group (Y) and having at its molecular terminal a group (A) containing carbon-carbon double bond, the protecting group (Y) is converted to the polar functional group (X).
摘要:
The present invention relates to a method for producing a vinyl polymer retaining the ability for atom transfer radical polymerization, a method for reliably producing a vinyl polymer having terminal functional groups, a vinyl polymer having functional groups prepared by these methods, and a curable composition comprising the polymer. A vinyl polymer having terminal functional groups can be reliably produced through the steps of preparing a vinyl polymer by atom transfer radical polymerization of a vinyl monomer in a polymerization solvent in the presence of a polymerization initiator and a transition metal complex functioning as a polymerization catalyst, removing the polymerization solvent and the vinyl monomer while the ability for atom transfer radical polymerization is maintained, and supplying a functional-group-introducing agent having a low polymerizability to introduce a functional group to a polymer terminus. During the step of supplying the functional-group-introducing agent, a functional-group-introducing solvent having a dielectric constant higher than that of the functional-group-introducing agent may be supplied to effectively introduce a functional group to a terminus of the vinyl polymer. Furthermore, according to the present invention, the polymerization solvent and the functional-group-introducing agent can be recovered and recycled.
摘要:
The present invention provides a method for producing a vinyl polymer including the steps of polymerizing a vinyl monomer by atom transfer radical polymerization with a transition metal complex as a polymerization catalyst, and bringing the resultant vinyl polymer into contact with an adsorbent in the presence of an oxidizing agent; the vinyl polymer produced by the method; and a reactive composition susceptible to hydrosilylation containing the vinyl polymer produced by the method and having at least one alkenyl group per molecule.
摘要:
A curable composition comprises a polyether polymer having at least one crosslinkable functional group and a vinyl polymer compatible therewith having at least one crosslinkable functional group at a terminus. Another aspect includes a compatibilizing agent capable of compatibilizing the polyether polymer and vinyl polymer when added to the mixture thereof.