公开(公告)号：US08563222B2

公开(公告)日：2013-10-22

申请号：US12601110

申请日：2008-05-15

Applicant: Jan Venneman ,  Peter Hendrikx ,  Paul Callant ,  Alexander Williamson

Inventor： Jan Venneman ,  Peter Hendrikx ,  Paul Callant ,  Alexander Williamson

IPC: G03F7/031 ,  G03F7/30

CPC classification number: C07C41/30 ,  C07C43/215 ,  C07C43/23 ,  C07C43/243 ,  C07C2601/14 ,  C08F2/50 ,  G03F7/031

Abstract: A lithographic printing plate precursor comprising an image-recording layer, said image-recording layer being photopolymerizable upon exposure to light having a wavelength of from 300 to 500 nm and containing a mixture of sensitizers.

公开(公告)号：US20130230704A1

公开(公告)日：2013-09-05

申请号：US13885747

申请日：2011-12-06

Applicant: Paul Callant ,  Ingrid Geuens ,  Bart Waumans ,  Hubertus Van Aert

Inventor： Paul Callant ,  Ingrid Geuens ,  Bart Waumans ,  Hubertus Van Aert

IPC: B41M5/323 ,  B41J2/44

CPC classification number: B41M5/323 ,  B41J2/442 ,  B41M3/142 ,  B41M5/267 ,  B41M5/30 ,  B41M5/327 ,  B41M5/3275 ,  B41M5/3336 ,  B41M5/34 ,  B42D25/29 ,  B42D25/382 ,  B42D25/435 ,  B42D2033/30 ,  Y10S430/146 ,  Y10T428/24802

Abstract: A method of colour laser marking an article having a polymeric foil with at least one colourless layer containing an infrared absorber, a polymeric binder and a colour forming compound; including the steps of:—laser marking the colourless layer with an infrared laser using a first laser operation mode to generate a blue or cyan colour; and—laser marking the same colourless layer with an infrared laser using a second laser operation mode to generate a black colour, wherein the first laser operation mode applies less energy to the colourless layer than the second laser operation mode. Also disclosed is an article, such as a security document, including a polymeric foil and a colourless layer containing laser marked graphical data having a blue or cyan colour and laser marked information having a black colour

Abstract translation: 一种彩色激光标记具有聚合物箔的制品的方法，其具有至少一个含有红外线吸收剂，聚合物粘合剂和成色化合物的无色层; 包括以下步骤：使用第一激光操作模式用红外激光激光标记无色层以产生蓝色或青色; 并且使用第二激光操作模式用红外激光器激发相同的无色层以产生黑色，其中所述第一激光操作模式对所述无色层施加比所述第二激光操作模式更少的能量。 还公开了一种诸如安全文件的物品，包括聚合物箔和含有激光的无色层，标记的具有蓝色或青色的图形数据和具有黑色的激光标记信息

公开(公告)号：US08304165B2

公开(公告)日：2012-11-06

申请号：US12439578

申请日：2007-10-10

Applicant: Hieronymus Andriessen ,  Paul Callant ,  Alexander Williamson

Inventor： Hieronymus Andriessen ,  Paul Callant ,  Alexander Williamson

IPC: G03F7/004 ,  B41N1/08

CPC classification number: B41C1/1025 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24

Abstract: A heat-sensitive negative-working lithographic printing plate precursor comprising: a support having a hydrophilic surface or which is provided with a hydrophilic layer; and an image-recording layer comprising hydrophobic thermoplastic polymer particles and an infrared light absorbing dye; characterized in that: said image-recording layer further comprises a compound, said compound comprising an aromatic moiety and at least one acidic group or salt thereof and having a most bathochromic light absorption peak at a wavelength between 300 nm and 450 nm.

Abstract translation: 一种热敏负性平版印刷版原版，其包含：具有亲水表面的或具有亲水层的载体; 和包含疏水性热塑性聚合物颗粒和红外光吸收染料的图像记录层; 其特征在于：所述图像记录层还包含化合物，所述化合物包含芳族部分和至少一种酸性基团或其盐，并且在300nm至450nm之间的波长处具有最大的红移光吸收峰。

公开(公告)号：US20120208126A1

公开(公告)日：2012-08-16

申请号：US13501598

申请日：2010-10-15

Applicant: Paul Callant

Inventor： Paul Callant

IPC: G03F7/004 ,  C07D209/60

CPC classification number: B41C1/1008 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  C09B23/0066

Abstract: A lithographic printing plate precursor includes a cyanine dye, characterized in that the cyanine dye includes two different chromophoric groups, a chromophoric group that has its main absorption in the infrared region and another chromophoric group that has its main absorption in the visible light region. The cyanine dye has preferably a structure according to Formula I:

Abstract translation: 平版印刷版前体包括花青染料，其特征在于，所述花青染料包括两个不同的发色基团，其在红外区域中具有主要吸收的发色基团和在可见光区域具有其主要吸收的另一发色团。 花青染料优选具有式I的结构：

公开(公告)号：US20110287364A1

公开(公告)日：2011-11-24

申请号：US13121658

申请日：2009-12-03

Applicant: Paul Callant

Inventor： Paul Callant

IPC: G03F7/20 ,  G03F7/004

CPC classification number: B41C1/1025 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24 ,  C08K5/0041 ,  C09B23/0066 ,  C09B23/06 ,  C08L25/12

Abstract: A lithographic printing plate precursor comprising a coating provided on a support having a hydrophilic surface, the coating containing thermoplastic polymer particles and an IR-dye characterized in that the IR-dye contains a structural element according to Formula I wherein A represents hydrogen, halogen or a monovalent organic group; Y and Y′ independently represent —CH— or —N—; R1 and R2 independently represent hydrogen, an optionally substituted alkyl or aryl group or represent the necessary atoms to form a ring; * represents the linking positions to the rest of the molecule.

Abstract translation: 一种平版印刷版原版，其包含提供在具有亲水表面的载体上的涂层，所述涂层含有热塑性聚合物颗粒和IR-染料，其特征在于所述IR染料含有根据式I的结构元件，其中A表示氢，卤素或 一价有机基团; Y和Y'独立地表示-CH-或-N-; R1和R2独立地表示氢，任意取代的烷基或芳基或代表必需的原子以形成环; *表示与分子其余部分的连接位置。

公开(公告)号：US20100159388A1

公开(公告)日：2010-06-24

申请号：US12601110

申请日：2008-05-15

Applicant: Jan Venneman ,  Peter Hendrikx ,  Paul Callant ,  Alexander Williamson

Inventor： Jan Venneman ,  Peter Hendrikx ,  Paul Callant ,  Alexander Williamson

IPC: G03F7/004 ,  G03F7/20

CPC classification number: C07C41/30 ,  C07C43/215 ,  C07C43/23 ,  C07C43/243 ,  C07C2601/14 ,  C08F2/50 ,  G03F7/031

Abstract: A lithographic printing plate precursor comprising an image-recording layer, said image-recording layer being photopolymerizable upon exposure to light having a wavelength of from 300 to 500 nm and containing a mixture of sensitizers.

公开(公告)号：US20100104980A1

公开(公告)日：2010-04-29

申请号：US12626352

申请日：2009-11-25

Applicant: Jan Venneman ,  Peter Hendrikx ,  Paul Callant ,  Alexander Williamson

Inventor： Jan Venneman ,  Peter Hendrikx ,  Paul Callant ,  Alexander Williamson

IPC: G03F7/20 ,  G03F7/004

CPC classification number: G03F7/029 ,  G03F7/031

Abstract: A lithographic printing plate precursor comprising an image-recording layer, said image-recording layer being photo-polymerizable upon exposure to actinic light and containing a mixture of sensitizers characterized in that said mixture of sensitizers has in 1-methoxy-2-propanol at 80° C. a solubility of at least 30 wt. %. and preferably a MetaStable Zone Width (MSZW) of at least 8.5° C., said MSZW measured at a cooling and heating rate of 0.2° C./minute.

Abstract translation: 一种包含图像记录层的平版印刷版原版，所述图像记录层在曝光于光化反应之后可光聚合并含有敏化剂混合物，其特征在于所述敏化剂混合物在1-甲氧基-2-丙醇中具有80 ℃至少30重量％的溶解度。 ％。 并且优选地为至少8.5℃的MetaStable Zone Width（MSZW），所述MSZW以0.2℃/分钟的冷却和加热速率测量。

公开(公告)号：US06472137B1

公开(公告)日：2002-10-29

申请号：US09709628

申请日：2000-11-13

Applicant: Ann Verbeeck ,  Paul Callant ,  Freddy Henderickx

Inventor： Ann Verbeeck ,  Paul Callant ,  Freddy Henderickx

IPC: G03C1005

CPC classification number: G03C5/16 ,  G03C1/0051 ,  G03C1/122 ,  G03C1/29 ,  Y10S430/167

Abstract: A light-sensitive silver halide photographic film material has been provided, said film material comprising a transparent support and on both sides thereof at least one light-sensitive emulsion layer having spectrally and chemically sensitized tabular silver halide grains rich in silver bromide, further having silver iodide in an amount of less than 3 mole % based on silver, with two flat parallel {111} crystal faces, said grains accounting for a total projective surface of said parallel crystal faces in said emulsion of at least 50%, further having an average aspect ratio of at least 2:1, a grain thickness of from 0.05 up to 0.15 &mgr;m, a site-directing azacyanine compound satisfying the general formulae disclosed herein in an amount of not less than 1×10−4 mole per mole of silver halide coated and one or more J-aggregating spectrally sensitizing dye(s), wherein a molar ratio amount between said site directing compound and said J-aggregating spectrally sensitizing dye(s) is at least 1:6 for a grain coverage of said {111} tabular grains exceeding 50%. A radiographic screen/film combination has also been described comprising said light-sensitive silver halide photographic film material and two supporting or self-supporting X-ray intensifying screens) comprising luminescent phosphors, wherein by contacting the film material with a sandwich of a pair of said intensifying screens and exposing said combination to X-rays, emission of radiation by said luminescent phosphors in the wavelength range for which said material has been made spectrally sensitive provides a black-and-white diagnostic image after processing of said exposed radiographic film material.

Abstract translation: 已经提供了感光卤化银照相胶片材料，所述胶片材料包括透明支撑体，并且在其两侧上具有至少一个感光乳剂层，其具有富含溴化银的光谱和化学增感的片状卤化银颗粒，还具有银 碘化物的量小于3摩尔％，具有两个平的平行{111}晶面，所述颗粒占所述乳液中所述平行晶面的总投影面至少为50％，进一步具有平均 纵横比为至少2:1，晶粒厚度为0.05至0.15μm，位置引导的氮杂菁化合物，其满足本文公开的通式，其用量为每摩尔卤化银涂层不小于1×10 -4摩尔， 一种或多种J聚集光谱增感染料，其中所述位点引导化合物和所述J-聚集光谱增感染料之间的摩尔比为至少1:6 所述{111}片状晶粒的晶粒覆盖率超过50％。还描述了包括所述感光卤化银照相胶片材料和两种支撑或自支撑X射线增强屏幕的放射照相屏/膜组合，其包含发光 荧光体，其中通过使膜材料与一对所述增强屏幕的夹层接触并将所述组合暴露于X射线，所述发光荧光体在所述材料已经被制成光谱敏感的波长范围内的发射由黑色 处理所述暴露的放射线照相胶片材料之后的白色诊断图像。

公开(公告)号：US06261733B1

公开(公告)日：2001-07-17

申请号：US09562945

申请日：2000-05-03

Applicant: Paul Coppens ,  Ludo Vervloet ,  Paul Callant

Inventor： Paul Coppens ,  Ludo Vervloet ,  Paul Callant

IPC: G03C806

CPC classification number: G03F7/07 ,  G03C8/06 ,  G03C8/44

Abstract: According to the present invention, there is provided a silver salt diffusion transfer material, comprising on a hydrophilic surface of a support in the order given (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) a top layer containing gelatin, said silver halide emulsion being spectrally sensitized with a dye with a sensitizing maximum between 380 and 430 nm, characterized in that said top layer comprises a compound I and/or a compound II

Abstract translation: 根据本发明，提供了一种银盐扩散转移材料，其包含在载体的亲水表面上，其顺序为（i）含有物理显影核的图像接收层，（ii）含有卤化银的感光层 所述乳液与所述图像接受层呈水可渗透关系，和（iii）含有明胶的顶层，所述卤化银乳剂用380至430nm之间的感光最大值的染料进行光谱增感，其特征在于所述顶层包含化合物 Iand /或化合物II

公开(公告)号：US6074814A

公开(公告)日：2000-06-13

申请号：US889411

申请日：1997-07-08

Applicant: Geert Deroover ,  Herman Uytterhoeven ,  Paul Callant ,  Johan Loccufier

Inventor： Geert Deroover ,  Herman Uytterhoeven ,  Paul Callant ,  Johan Loccufier

IPC: G03C1/28 ,  G03C1/498 ,  G03C1/490

CPC classification number: C09B23/0066 ,  C09B23/0075 ,  C09B23/086 ,  C09B23/148 ,  G03C1/49854 ,  G03C1/49863 ,  G03C1/28

Abstract: A photothermographic recording material comprising a photo-addressable thermally developable element including a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt, in a quantity of 0.1 to 35 mol % relative to the organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder comprises a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer and the dye is represented by formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.17 are independently each an alkyl or sulfo-alkyl group which may be substituted with at least one fluorine, chlorine, bromine, iodine or an alkoxy-, aryloxy- or ester-group; and X represents an anion.

Abstract translation: 一种光热记录材料，其包含可光寻址的热显影元件，其包含基本上不光敏的有机银盐，相对于基本上不光敏的有机银盐催化缔合的感光卤化银，其量相对于 有机银盐，用染料对红外线进行光谱敏化，染料用超增敏剂，与基本上不透光的有机银盐和粘合剂的热加工关系的还原剂，其中粘合剂包含水溶性聚合物， 水分散性聚合物或水溶性聚合物和水分散性聚合物，染料由式（I）表示：其中Z1和Z2独立地表示S，O或Se; R 1和R 17各自独立地为可以被至少一个氟，氯，溴，碘或烷氧基 - ，芳氧基或酯基取代的烷基或磺基 - 烷基; X表示阴离子。