摘要:
Acetates of the formula ##STR1## wherein X.sub.1 represents hydrogen, halogen or C.sub.1 -C.sub.4 alkyl, X.sub.2 represents hydrogen or halogen, and Y represents hydrogen, halogen or methyl, processes for their manufacture and a method of controlling pests which comprises the use of these compounds.
摘要:
The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1##
摘要:
The reaction of 2,2-difluorobenzo-1,3-dioxole with (a) an alkali metal or an alkali metal compound and then (b) a compound R.sup.1 -Z.sup.1 in which Z.sup.1 is a leaving group, or with an aldehyde produces compounds of formula I ##STR1## wherein R.sup.1 is --OH, --SH, --CHO, --CN, --COOH, --B(OH).sub.2, --COX, with X being Cl or Br, or is --COOR.sup.2, --SiR.sub.3.sup.2 or --B(OR.sup.2).sub.2, with R.sup.2 being a C.sub.1 -C.sub.12 alcohol moiety without the hydroxy group, wherein R.sup.1 is further --C.sub.n H.sub.2n COOR.sup.2, with n being an integer from 1 to 4, or linear or branched C.sub.1 -C.sub.12 hydroxyalkyl which is unsubstituted or is substituted by --F, --CN, C.sub.1 -C.sub.6 alkoxy, phenyl, fluorophenyl, C.sub.1 -C.sub.4 alkoxy-phenyl, C.sub.1 -C.sub.4 alkylthio-phenyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 fluoroalkyl-phenyl, nitrophenyl or by cyanophenyl, or wherein R.sup.1 is a benzyl alcohol which is unsubstituted or is substituted by F, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 fluoroalkyl, nitro or by cyano, or is C.sub.1 -C.sub.12 acyl, or wherein R.sup. 1 is a radical of formula II ##STR2## wherein R.sup.5 is --CN, --CF.sub.3, --COOR.sup.2, --CONH.sup.2, --CO--NHR.sup.2 or --CONR.sub.2.sup.2, R.sup.3 and R.sup.4 are a direct bond or each is H, or R.sup.3 is H and R.sup.4 independently has the meanings of R.sup.5, or R.sup.3 and R.sup.4 together are --CH.sub.2 --NR.sup.6 --CH.sub.2 --, --CH.sub.2 --NR.sup.6 --CO-- or --CO--NR.sup.6 --CO-- wherein R.sup.6 is the radical of a removable protecting group, or wherein further R.sup.1 is a radical of formula III ##STR3## Insecticides or fungicides can be prepared from the compounds of formula I. 3-(2,2-difluorobenzodioxol-4-yl)-4-cyanopyrrole can be prepared by reacting 4-metallo-2,2-difluorobenzodioxole (III) with an unsaturated nitrile and then with a sulfonylmethyl isocyanide in a one-pot process. The compounds III are novel intermediates.
摘要:
1-Aminocyclohexanecarboxylic acid derivatives of the formula I ##STR1## or their acid addition salts or a metal complex can be employed for protecting plants from microorganisms. In the formula I, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, benzyl, or an ammonium radical which is unsubstituted or substituted by hydrocarbon radicals having not more than 20 C atoms, or a metal ion equivalent.Compounds of the formula I can be employed in the form of crop protection agents using suitable carrier materials.
摘要:
Novel benzothiophene and benzofuran derivatives of the general formula I ##STR1## wherein X is oxygen or sulfur, R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or halogen and R is a 4-cyano-3-pyrrole radical of which the N atom carries one of the following substituents:A: hydrogen or CO--R.sub.4 in which R.sub.4 is unsubstituted C.sub.1 C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, unsubstituted C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkoxy substituted by halogen or by C.sub.1 -C.sub.3 alkoxy; C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 cycloalkyl or tetrahydrofur2-yl;B: S-R.sub.5 in which R.sub.5 is C.sub.1 -C.sub.3 haloalkyl;C: CH(Y)R.sub.6 in which R.sub.6 is hydrogen or C.sub.1 -C.sub.8 haloalkyl and Y is hydroxy, halogen or OC(O)R.sub.7 in which R.sub.7 is C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 haloalkyl, C.sub.2 -C.sub.6 -alkenyl, 2-tetrahydrofuryl, 2-tetrahydropyranyl or C.sub.1 -C.sub.6 alkoxycarbonyl;D: CH.sub.2 -Z in which Z is one of the groups ##STR2## wherein R.sub.8 and R.sub.9 are each, independently of the other, hydrogen, unsubstituted C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkyl substituted by cyano or by C.sub.1 -C.sub.6 alkoxycarbonyl; C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, unsubstituted phenyl or phenyl substituted by halogen, by C.sub.1 -C.sub.6 alkyl, by C.sub.1 -C.sub.6 haloalkyl and/or by C.sub.1 -C.sub.6 alkoxy, with the proviso that only R.sub.8 or R.sub.9 may be hydrogen; R.sub.10 and R.sub.11 are each, independently of the other, hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; R.sub.12 and R.sub.13 are each, independently of the other, hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and R.sub.15 is oxygen, sulfur, >C.dbd.0 or >N--R.sub.14, wherein R.sub.14 is hydrogen, C.sub.1 -C.sub.6 alkyl, formyl, C.sub.1 -C.sub.6 alkanoyl or C.sub.1 -C.sub.6 alkoxycarbonyl; and n is one of the numbers 0 or 1.The novel active ingredients serve to control harmful microorganisms, especially phytophathogenic fungi. They can be used together with suitable formulation adjuvants in the form of compositions, and are suitable also for preventing attack on cultivated plants by harmful microorganisms.
摘要:
The invention relates to .alpha.-methyl-(6-phenoxy)-2-picolyl cyclopropanecarboxylates of the formula ##STR1## wherein X.sub.1 is methyl or halogen,R.sub.1 is hydrogen or halogen, andR.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 alkynyl, nitro or cyano.The invention also relates to the preparation of these esters and to the use thereof in pest control.
摘要:
The invention relates to vinylcyclopropanecarboxylic acid 3-phenoxy-.alpha.-vinylbenzyl esters of the formula ##STR1## wherein each of X.sub.1 and Y is fluorine, chlorine or bromine, processes for the manufacture of these compounds and their use in pest control.
摘要:
.alpha.-Phenyl-.alpha.-cyclopropylacetates of the formula ##STR1## wherein X.sub.1 represents hydrogen, halogen or C.sub.1 -C.sub.4 alkyl, X.sub.2 represents hydrogen, methyl or halogen, R.sub.1 represents hydrogen, cyano, vinyl or ethynyl, and Y represents fluorine or bromine, processes for their manufacture, and a method of controlling pests which comprises the use of these novel esters.
摘要:
Cyclopropanecarboxylic acid-phenoxy-.alpha.-vinyl-benzyl esters of the formula ##STR1## in which Y is chlorine or bromine, and R.sub.1 is --CH.dbd.CH.sub.2 or ##STR2## processes for producing them, and their use in combating pests.
摘要:
Cyclopropanecarboxylic acid esters of the formula ##STR1## in which X.sub.1 is fluorine, chlorine or bromine, R.sub.1 and R.sub.2 are each hydrogen, fluorine, chlorine, bromine or methyl, R.sub.3 and R.sub.4 are each hydrogen, fluorine, chlorine, bromine, methyl, methoxy, nitro or dimethylamine, or together are methylenedioxy, and R.sub.5 is hydrogen or methyl, processes for producing them, and their use in controlling insect pests.