公开(公告)号：US5356970A

公开(公告)日：1994-10-18

申请号：US217397

申请日：1994-03-24

申请人： Robert C. Bening ,  James R. Erickson ,  David J. St. Clair ,  Carma J. Gibler ,  Joe J. Flores

发明人： Robert C. Bening ,  James R. Erickson ,  David J. St. Clair ,  Carma J. Gibler ,  Joe J. Flores

IPC分类号： C08C19/40 ,  C08F8/00 ,  C08G18/62 ,  C09D175/04 ,  C08F8/32

CPC分类号： C09D175/04 ,  C08C19/40 ,  C08F8/00 ,  C08F8/04 ,  C08F8/12 ,  C08F8/32 ,  C08G18/6208 ,  C08F2810/20

摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.

摘要翻译： 一种在二烯嵌段中含有羟基的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种共轭二烯制备前体聚合物，所述共轭二烯离开1,2-二取代的1,1,1-二取代的1,1,2三取代 或聚合物中的四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）使所述前体聚合物环氧化，使得环氧基在所述取代部位形成，聚合物中环氧官能度的量为0.1-5Meq / g聚合物，和（d）使环氧化聚合物与盐酸的醇溶液反应。 含有0.1〜10Meq / g羟基的二烯聚合物，其由式（III）或式（Ia）的醇单元组成，其中R 1和R 2为氢或烷基，X和X'为-OH或-Cl 并且其中至少一个是-OH。

公开(公告)号：US5284901A

公开(公告)日：1994-02-08

申请号：US49687

申请日：1993-04-16

申请人： Robert C. Bening ,  James R. Erickson ,  Charles J. Stark ,  David J. St. Clair

发明人： Robert C. Bening ,  James R. Erickson ,  Charles J. Stark ,  David J. St. Clair

IPC分类号： C08C19/40 ,  C08F8/00 ,  C08G18/62 ,  C09D175/04

CPC分类号： C09D175/04 ,  C08C19/40 ,  C08F8/00 ,  C08G18/6208

摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.

摘要翻译： 在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成， 聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自 由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。 含有0.01〜15 Meq / g羟基聚合物的二烯聚合物，优选包括高反应性伯羟基，并且由式（*化学结构*）（F）或（*化学结构*）（ G）其中R选自含有至多10个碳原子的烷基，一元和二元醇基和碳酸酯基; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。

公开(公告)号：US5264480A

公开(公告)日：1993-11-23

申请号：US49682

申请日：1993-04-16

申请人： Robert C. Bening ,  James R. Erickson ,  Charles J. Stark ,  David J. St. Clair

发明人： Robert C. Bening ,  James R. Erickson ,  Charles J. Stark ,  David J. St. Clair

IPC分类号： C08C19/40 ,  C08F8/00 ,  C08G18/62 ,  C09D175/04

CPC分类号： C09D175/04 ,  C08C19/40 ,  C08F8/00 ,  C08G18/6208

摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.

摘要翻译： 在二烯嵌段中制备含有羟基（包括高反应性伯羟基）的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种离去1,2-二取代的共轭二烯制备前体聚合物，1,1 聚合物中的二取代的，1,1,2三取代或四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）环氧化所述前体聚合物，使得环氧基在所述取代部位形成， 聚合物为至少0.1Meq / g聚合物，和（d）使环氧化聚合物与具有一个未保护羟基的醇在溶剂中，在路易斯酸存在下反应，该路易斯酸选自MXn，其中M选自 由硼，铝，铁和锡组成的组，X是卤素，以及这些酸的有机络合物。 含有0.01至15Meq / g羟基聚合物的二烯聚合物，优选包括高度反应性的伯羟基，并且由式（I）所示的醚 - 醇单元组成，其中R选自含有至多 一个碳原子，一个羟基和二元醇基团和碳酸酯基团; 并且R 1和R 2是氢或烷基，其中在（G）中，R 1或R 2中只有一个是氢。

公开(公告)号：US5242989A

公开(公告)日：1993-09-07

申请号：US863580

申请日：1992-04-03

申请人： Robert C. Bening ,  James R. Erickson ,  Charles J. Stark ,  David J. St. Clair

发明人： Robert C. Bening ,  James R. Erickson ,  Charles J. Stark ,  David J. St. Clair

IPC分类号： C08C19/40 ,  C08F8/00 ,  C08G18/62 ,  C09D175/04

CPC分类号： C09D175/04 ,  C08C19/40 ,  C08F8/00 ,  C08G18/6208

摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups, including highly reactive primary hydroxyl groups, in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from at least 0.1 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol having one unprotected hydroxyl group in a solvent in the presence of a Lewis acid selected from the group consisting of MX.sub.n where M is selected from the group consisting of boron, aluminum, iron and tin, and X is a halogen, and organic complexes of such acids.A diene polymer containing 0.01 to 15 Meq/g polymer of hydroxyl group, preferably including highly reactive primary hydroxyl groups, and comprised of ether-alcohol units of the formula ##STR1## where R is selected from the group consisting of alkyl radicals containing up to 10 carbon atoms, monohydric and dihydric alcohol groups and carbonate groups; and R.sub.1 and R.sub.2 are hydrogen or alkyl radicals wherein in (G) only one of R.sub.1 or R.sub.2 is hydrogen.

公开(公告)号：US08349950B2

公开(公告)日：2013-01-08

申请号：US12401878

申请日：2009-03-11

申请人： Dale Lee Handlin, Jr. ,  Peter Pasman ,  Glenn H. Fredrickson ,  Carl L. Willis ,  Robert C. Bening

发明人： Dale Lee Handlin, Jr. ,  Peter Pasman ,  Glenn H. Fredrickson ,  Carl L. Willis ,  Robert C. Bening

IPC分类号： C08F297/04 ,  C08L53/02 ,  B60C1/00

CPC分类号： C08F236/10 ,  C08F297/04 ,  C08F297/044 ,  C08L53/02 ,  C08L53/025 ,  C08L2666/02

摘要： The present invention provides a block copolymer composition and method of making the same having the structures (A2-B)n—X-(A1) or (A2-B2)n—X—(B1A1), where A1 and A2 are each a polymer block of a monoalkenyl arene and B, B1, and B2 are each a polymer block of one or more conjugated dienes or a hydrogenated diene polymer, n is an integer from 2 to 30 and X is the residue of a coupling agent.

摘要翻译： 本发明提供了具有（A2-B）n-X-（A1）或（A2-B2）n-X-（B1A1）结构的嵌段共聚物组合物及其制备方法，其中A1和A2各自为 单链烯基芳烃的聚合物嵌段和B，B1和B2各自为一个或多个共轭二烯或氢化二烯聚合物的聚合物嵌段，n为2至30的整数，X为偶联剂的残基。

公开(公告)号：US07582702B2

公开(公告)日：2009-09-01

申请号：US11388909

申请日：2006-03-24

申请人： Kathryn J. Wright ,  Carl L. Willis ,  Tomomi Nishi ,  Norio Masuko ,  Dale L. Handlin, Jr. ,  Robert C. Bening

发明人： Kathryn J. Wright ,  Carl L. Willis ,  Tomomi Nishi ,  Norio Masuko ,  Dale L. Handlin, Jr. ,  Robert C. Bening

IPC分类号： C08L53/02 ,  C08C19/04 ,  C08C19/20

CPC分类号： C08L53/02 ,  C08F8/04 ,  C08F287/00 ,  C08F297/04 ,  C08L51/006 ,  C08L53/025 ,  C08L2666/24 ,  C08L2666/02

摘要： The present invention relates to novel compositions comprising (a) anionic block copolymers of mono alkenyl arenes and conjugated dienes where one of the blocks is a controlled distribution copolymer of a conjugated diene and mono alkenyl arene having a specific arrangement of the monomers in the copolymer block, and (b) tailored softening modifiers have a particular structure that results in a surprising improvement in properties for the composition. Also included are processes for the manufacturing such novel compositions and various end-uses and applications for such compositions.

摘要翻译： 本发明涉及包含（a）单烯基芳烃和共轭二烯的阴离子嵌段共聚物的新型组合物，其中一个嵌段是共聚物嵌段中具有单体特异排列的共轭二烯和单烯基芳烃的受控分布共聚物 ，和（b）定制的软化改性剂具有导致组合物性能惊人改进的特定结构。 还包括用于制造这种新型组合物和各种最终用途和用于这种组合物的方法。

公开(公告)号：US07232864B2

公开(公告)日：2007-06-19

申请号：US10965307

申请日：2004-10-14

申请人： Robert C. Bening

发明人： Robert C. Bening

IPC分类号： C08K5/54

CPC分类号： C08C19/02 ,  C08C19/44 ,  C08F8/42

摘要： The present invention is a coupled radial anionic polymer comprising a polyhedral oligosilsesquioxane [POSS] of the formula [R—SiO3/2]n. POSS compounds having R=vinyl, glycidyldimethyl silyl, and isobutyl have been found effective in coupling anionic living polymers to yield radial polymers having 2 to 10 arms. Radial polymers of the present invention have been formed using POSS octamers and mixtures of POSS octamers, decamers and dodecamers. The present invention also relates to a process for coupling living anionic polymers with POSS compounds.

摘要翻译： 本发明是一种耦合的径向阴离子聚合物，其包含式[R-SiO 3/2/2] n N的多面体低聚倍半硅氧烷[POSS]。 已经发现具有R =乙烯基，缩水甘油基二甲基甲硅烷基和异丁基的POSS化合物在偶联阴离子活性聚合物中有效产生具有2至10个臂的径向聚合物。 本发明的径向聚合物已经使用POSS八聚体和POSS八聚体，十聚体和十二烷基醚的混合物形成。 本发明还涉及将活性阴离子聚合物与POSS化合物偶联的方法。

公开(公告)号：US07138456B2

公开(公告)日：2006-11-21

申请号：US11055317

申请日：2005-02-10

申请人： Robert C. Bening ,  Dale L. Handlin, Jr. ,  Larry L. Sterna ,  Carl L. Willis

发明人： Robert C. Bening ,  Dale L. Handlin, Jr. ,  Larry L. Sterna ,  Carl L. Willis

IPC分类号： C08F293/00 ,  C08F297/00 ,  C08L53/02

CPC分类号： C09J153/02 ,  C08F287/00 ,  C08F297/04 ,  C08L23/10 ,  C08L53/02 ,  C08L53/025 ,  C08L77/00 ,  C08L95/00 ,  C08L101/00 ,  C08L2666/02 ,  C08L2666/24 ,  C09D153/02 ,  C09D153/025 ,  C09J153/025 ,  C08L2666/04 ,  C08L53/00

摘要： The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.

公开(公告)号：US5545691A

公开(公告)日：1996-08-13

申请号：US540996

申请日：1995-10-11

申请人： Robert C. Bening ,  David J. St. Clair

发明人： Robert C. Bening ,  David J. St. Clair

IPC分类号： C08C19/44 ,  C08F36/04 ,  C08F8/20

CPC分类号： C08C19/44 ,  C08F36/04

摘要： The capping of anionic polymers to make functionalized polymers is used to make heterotelechelic polymers by using a protected functional initiator to polymerize a polymer comprising a conjugated diene and then capping the polymer with low surface energy fluorocarbons. The protected functional groups are stable under a variety of conditions and then readily convert to more reactive terminal functional groups useful for making sealants, coatings, molded or extruded goods and fibers having low surface energy.

摘要翻译： 使用阴离子聚合物制备官能化聚合物的封端物通过使用保护的官能引发剂来聚合包含共轭二烯的聚合物，然后用低表面能碳氟化合物封端聚合物，来制备杂多炔类聚合物。 受保护的官能团在各种条件下是稳定的，然后容易地转化成用于制备具有低表面能的密封剂，涂料，模塑或挤出物品和纤维的更具反应性的末端官能团。

公开(公告)号：US5516824A

公开(公告)日：1996-05-14

申请号：US337714

申请日：1995-01-23

申请人： Michael A. Masse ,  Paul A. Mancinelli ,  James R. Erickson ,  Steven H. Dillman ,  Robert C. Bening ,  David R. Hansen

发明人： Michael A. Masse ,  Paul A. Mancinelli ,  James R. Erickson ,  Steven H. Dillman ,  Robert C. Bening ,  David R. Hansen

IPC分类号： B32B27/08 ,  C08G59/34 ,  C09J153/00 ,  C09J153/02 ,  C09J163/08 ,  C08K5/10 ,  C08L63/08

CPC分类号： C08G59/027 ,  B32B27/08 ,  C09J153/005 ,  C09J153/025 ,  C09J163/08 ,  Y10T428/31515

摘要： A laminating adhesive comprising an adhesive composition which comprises(a) An epoxidized block copolymer of the formula(A-B-A.sub.p).sub.n -Y.sub.r -(A.sub.q -B).sub.mwherein Y is a coupling agent or coupling monomers, andwherein A and B are polymer blocks which may be homopolymer blocks of conjugated diolefin monomers, copolymer blocks of conjugated diolefin monomers or copolymer blocks of conjugated diolefin monomers and monoalkenyl aromatic hydrocarbon monomers, andwherein the A blocks have a higher number of aliphatic double bonds between a tertiary carbon atom and either a primary, secondary, or tertiary carbon atom per unit of block mass than do the B blocks, andwherein the A blocks have a molecular weight from about 100 to about 3000 and the B blocks have a molecular weight from about 1000 to about 15,000, and wherein p and q are 0 or 1 and n>0, r is 0 or 1, m.gtoreq.0 and n+m ranges from 1 to 100; and(b) at least a significant amount of a tackifying resin compatible with the polymer of (a) up to 400 phr.The invention also relates to a laminate containing the adhesive.

摘要翻译： 一种层压粘合剂，其包含粘合剂组合物，其包含（a）式（AB-Ap）n-Yr-（Aq-B）m的环氧化嵌段共聚物，其中Y为偶联剂或偶联单体，并且其中A和B为 聚合物嵌段，其可以是共轭二烯烃单体的均聚物嵌段，共轭二烯单体的共聚物嵌段或共轭二烯烃单体的共聚物嵌段和单链烯基芳烃单体，并且其中所述A嵌段在叔碳原子和叔碳原子之间具有更高数量的脂族双键 与B嵌段相比，每单位嵌段质量的伯，仲或叔碳原子，其中A嵌段的分子量为约100至约3000，B嵌段的分子量为约1000至约15,000 并且其中p和q为0或1且n> 0，r为0或1，m≥0和n + m的范围为1至100; 和（b）至少大量的与（a）多至400phr的聚合物相容的增粘树脂。 本发明还涉及含有粘合剂的层压体。