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公开(公告)号：US5391637A
公开(公告)日：1995-02-21
申请号：US157785
申请日：1993-11-23
摘要： Living anionic polymers of unsaturated monomers are conveniently capped with oxetane or an alkyl substituted oxetane to provide terminal primary hydroxyl groups. The hydroxyl capped polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
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公开(公告)号：US20080199387A1
公开(公告)日：2008-08-21
申请号：US11841548
申请日：2007-08-20
IPC分类号： D01F9/12
CPC分类号： D01F11/122 , Y10T428/2918
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassium chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种氧化碳微纤维表面的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US5965470A
公开(公告)日：1999-10-12
申请号：US447948
申请日：1995-05-23
CPC分类号： D01F11/122 , Y10T428/2918 , Y10T428/2935 , Y10T428/2975 , Y10T428/31678
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassium chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种使碳微纤维表面氧化的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US5486568A
公开(公告)日：1996-01-23
申请号：US359805
申请日：1994-12-20
摘要： The capping of anionic polymers to make functionalized polymers is used to make heterotelechelic polymers by using a protected functional initiator to polymerize a polymer comprising a conjugated diene and then capping the polymer with low surface energy fluorocarbons. The protected functional groups are stable under a variety of conditions and then readily convert to more reactive terminal functional groups useful for making sealants, coatings, molded or extruded goods and fibers having low surface energy.
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25.发明授权
公开(公告)号：US5356974A
公开(公告)日：1994-10-18
申请号：US217472
申请日：1994-03-24
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
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公开(公告)号：US07410628B2
公开(公告)日：2008-08-12
申请号：US11212441
申请日：2005-08-26
IPC分类号： D01F9/12
CPC分类号： D01F11/122 , Y10T428/2918
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassiaum chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种氧化碳微纤维表面的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US5548025A
公开(公告)日：1996-08-20
申请号：US510928
申请日：1995-08-03
申请人： Robert C. Bening
发明人： Robert C. Bening
摘要： The capping of anionic polymers to make functionalized polymers is improved by using alkoxy silyl compounds having protected functional groups, such as acetal groups, as the capping agent. The protected functional groups are stable under a variety of conditions and then readily convert to more reactive terminal functional groups useful for making adhesives, sealants and coatings.
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28.发明授权Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II) 失效环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法（II）
公开(公告)号：US5300586A
公开(公告)日：1994-04-05
申请号：US863648
申请日：1992-04-03
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
摘要翻译： 一种在二烯嵌段中含有羟基的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种共轭二烯制备前体聚合物，所述共轭二烯离开1,2-二取代的1,1,1-二取代的1,1,2三取代 或聚合物中的四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）使所述前体聚合物环氧化，使得环氧基在所述取代部位形成，聚合物中环氧官能度的量为0.1-5Meq / g聚合物，和（d）使环氧化聚合物与盐酸的醇溶液反应。 含有0.1〜10Meq / g羟基的二烯聚合物，由式（* CHEMICAL STRUCTURE *）的醇单元组成，其中R1和R2为氢或烷基，X和X'为-OH或-Cl， 其中至少一个是-OH。
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29.发明授权Functionalized block copolymers, method for making same, and various uses for such block copolymers 有权官能化嵌段共聚物，其制备方法以及这种嵌段共聚物的各种用途公开(公告)号：US07977432B2
公开(公告)日：2011-07-12
申请号：US11972701
申请日：2008-01-11
CPC分类号： C08L53/025 , C08F8/00 , C08F8/04 , C08F8/44 , C08F297/02 , C08L23/08 , C08L53/005 , C08F297/023 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： The present invention is a, solid block copolymer comprising at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to lithiation and each B block is a polymer block susceptible to lithiation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. After lithiation, the lithiated polymer is reacted with at least one graftable functional molecule selected from the group consisting of an electrophilic graftable molecule containing a functional group and an electrophile. Preferred are carbon monoxide and ethylene oxide. Also claimed are processes for making such block copolymers, and the various end uses and applications for such block copolymers.
摘要翻译： 本发明是一种固体嵌段共聚物，其包含至少两个聚合物端嵌段A和至少一个聚合物内嵌块B，其中每个A嵌段是耐锂化的聚合物嵌段，每个B嵌段是易于锂化的聚合物嵌段，其中 所述A和B嵌段不含任何显着水平的烯属不饱和度。 在锂化后，锂化聚合物与至少一种选自含有官能团的亲电子可接枝分子和亲电子试剂的可接枝的功能性分子反应。 优选的是一氧化碳和环氧乙烷。 还要求的是制备这种嵌段共聚物的方法，以及这些嵌段共聚物的各种最终用途和应用。
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30.发明申请FUNCTIONALIZED BLOCK COPOLYMERS, METHOD FOR MAKING SAME, AND VARIOUS USES FOR SUCH BLOCK COPOLYMERS 有权功能性嵌段共聚物，其制备方法以及用于这种嵌段共聚物的各种用途公开(公告)号：US20080171828A1
公开(公告)日：2008-07-17
申请号：US11972701
申请日：2008-01-11
CPC分类号： C08L53/025 , C08F8/00 , C08F8/04 , C08F8/44 , C08F297/02 , C08L23/08 , C08L53/005 , C08F297/023 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： The present invention is a, solid block copolymer comprising at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to lithiation and each B block is a polymer block susceptible to lithiation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. Preferably, each A block comprising one or more segments selected from polymerized (i) para-substituted styrene monomers not having hydrogen on a para benzylic carbon center, (ii) ethylene, (iii) alpha olefins of 3 to 18 carbon atoms; (iv) hydrogenated 1,3-cyclodiene monomers, (v) hydrogenated monomers of conjugated dienes having a vinyl content less than 35 mol percent prior to hydrogenation, (vi) acrylic esters, (vii) methacrylic esters, and (viii) mixtures thereof; and each B block comprising segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) para-substituted styrene having hydrogen on a para benzylic carbon center (vi) 1,1-diphenylethylene, (vii) 1,2-diphenylethylene and (viii) mixtures thereof. After lithiation, the lithiated polymer is reacted with at least one graftable functional molecule selected from the group consisting of an electrophilic graftable molecule containing a functional group and an electrophile. Preferred are carbon monoxide and ethylene oxide. Also claimed are processes for making such block copolymers, and the various end uses and applications for such block copolymers.
摘要翻译： 本发明是一种固体嵌段共聚物，其包含至少两个聚合物端嵌段A和至少一个聚合物内嵌块B，其中每个A嵌段是耐锂化的聚合物嵌段，每个B嵌段是易于锂化的聚合物嵌段，其中 所述A和B嵌段不含任何显着水平的烯属不饱和度。 优选地，每个A嵌段包含一个或多个选自在对苄基碳中心上不具有氢的对位取代的苯乙烯单体的区段，（ii）乙烯，（iii）3至18个碳原子的α-烯烃; （iv）氢化1,3-环二烯单体，（v）在氢化之前乙烯基含量低于35摩尔％的共轭二烯的氢化单体，（vi）丙烯酸酯，（vii）甲基丙烯酸酯和（viii）其混合物 ; 并且每个B嵌段包含一个或多个聚合的乙烯基芳族单体的链段，其选自（i）未取代的苯乙烯单体，（ii）邻位取代的苯乙烯单体，（iii）间位取代的苯乙烯单体，（iv）α-甲基苯乙烯，（v ）对位取代的苯乙烯在对苄基碳中心具有氢（vi）1,1-二苯基乙烯，（vii）1,2-二苯基乙烯和（viii）它们的混合物。 在锂化后，锂化聚合物与至少一种选自含有官能团的亲电子可接枝分子和亲电子试剂的可接枝的功能性分子反应。 优选的是一氧化碳和环氧乙烷。 还要求的是制备这种嵌段共聚物的方法，以及这些嵌段共聚物的各种最终用途和应用。
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