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公开(公告)号：US20080199387A1
公开(公告)日：2008-08-21
申请号：US11841548
申请日：2007-08-20
IPC分类号： D01F9/12
CPC分类号： D01F11/122 , Y10T428/2918
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassium chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种氧化碳微纤维表面的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US5965470A
公开(公告)日：1999-10-12
申请号：US447948
申请日：1995-05-23
CPC分类号： D01F11/122 , Y10T428/2918 , Y10T428/2935 , Y10T428/2975 , Y10T428/31678
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassium chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种使碳微纤维表面氧化的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US07410628B2
公开(公告)日：2008-08-12
申请号：US11212441
申请日：2005-08-26
IPC分类号： D01F9/12
CPC分类号： D01F11/122 , Y10T428/2918
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassiaum chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种氧化碳微纤维表面的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US07862794B2
公开(公告)日：2011-01-04
申请号：US11841548
申请日：2007-08-20
IPC分类号： D01F9/12
CPC分类号： D01F11/122 , Y10T428/2918
摘要： A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassium chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
摘要翻译： 一种氧化碳微纤维表面的方法，其包括在足以氧化表面的反应条件下使微纤维与包含硫酸和氯酸钾的氧化剂接触。 本发明还具有减少碳微纤维长度的方法，其包括在足以减少长度的反应条件下使微纤维与氧化剂接触。
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公开(公告)号：US07332542B2
公开(公告)日：2008-02-19
申请号：US11055367
申请日：2005-02-10
IPC分类号： C08F297/04 , C08L9/06
CPC分类号： C09J153/02 , C08F287/00 , C08F297/04 , C08L23/10 , C08L53/02 , C08L53/025 , C08L77/00 , C08L95/00 , C08L101/00 , C08L2666/02 , C08L2666/24 , C09D153/02 , C09D153/025 , C09J153/025 , C08L2666/04 , C08L53/00
摘要： The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.
摘要翻译： 本发明是含有共轭二烯和单烯基芳烃的受控分布共聚物嵌段的新型嵌段共聚物，其中受控分布共聚物嵌段具有富含共轭二烯单元的末端区域和富含单烯基的中心区域 别墅单位 还公开了一种制备嵌段共聚物的方法。
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6.发明授权Terminally functionalized polymers produced using protected functional initiators 失效使用保护的官能引发剂制备终端官能化聚合物
公开(公告)号：US5612435A
公开(公告)日：1997-03-18
申请号：US539467
申请日：1995-10-05
申请人： Robert C. Bening , Carl L. Willis
发明人： Robert C. Bening , Carl L. Willis
CPC分类号： C08F4/48 , C07F7/1864 , C08F36/06
摘要： The anionic polymerization of unsaturated monomers with functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--O--A'--Li is improved by selecting A' from the structures --CH.sub.2 --CH.sub.2 --CH.sub.2 -- (1,3-propyl), --CH.sub.2 --CH(CH.sub.3)--CH.sub.2 -- (2-methyl-1,3-propyl), --CH.sub.2 --C(CH.sub.3).sub.2 --CH.sub.2 --(2,2-dimethyl-1,3-propyl), or --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,8-octyl). This narrow class of polymerization initiators operate at surprisingly higher polymerization temperatures with surprisingly lower amounts of dead initiator than similar initiators wherein A' is --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,4-butyl), --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,5-pentyl), or --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --(1,6-hexyl).
摘要翻译： 通过从结构-CH 2 -CH 2 -CH 2 - （1,3-丙基），-CH 2 -CH（CH 3）2中选择A'来改善不饱和单体与具有结构R1R2R3Si-O-A'-Li的官能化引发剂的阴离子聚合 ）-CH 2 - （2-甲基-1,3-丙基），-CH 2 -C（CH 3）2 -CH 2 - （2,2-二甲基-1,3-丙基）或-CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 - （1,8-辛基）。 这种窄类聚合引发剂在令人惊奇的更高的聚合温度下操作，其中A'是-CH 2 -CH 2 -CH 2 - （1-丁基），-CH 2 -CH 2 -CH 2 - CH 2 -CH 2 - （1,5-戊基）或-CH 2 -CH 2 -CH 2 -CH 2 -CH 2 -CH 2 - （1,6-己基）。
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公开(公告)号：US5486568A
公开(公告)日：1996-01-23
申请号：US359805
申请日：1994-12-20
摘要： The capping of anionic polymers to make functionalized polymers is used to make heterotelechelic polymers by using a protected functional initiator to polymerize a polymer comprising a conjugated diene and then capping the polymer with low surface energy fluorocarbons. The protected functional groups are stable under a variety of conditions and then readily convert to more reactive terminal functional groups useful for making sealants, coatings, molded or extruded goods and fibers having low surface energy.
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公开(公告)号：US5418296A
公开(公告)日：1995-05-23
申请号：US319398
申请日：1994-10-06
摘要： Living anionic polymers of unsaturated monomers are conveniently capped with oxetane or an alkyl substituted oxetane to provide terminal primary hydroxyl groups. The hydroxyl capped polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.
摘要翻译： 不饱和单体的活性阴离子聚合物方便地用氧杂环丁烷或烷基取代的氧杂环丁烷封端以提供末端伯羟基。 羟基封端的聚合物可用于制备涂料，密封剂，粘合剂和与聚酯，聚酰胺和聚碳酸酯的嵌段共聚物。
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9.发明授权Protected functional initiators for making terminally functionalized polymers 失效用于制备末端官能化聚合物的受保护的官能引发剂
公开(公告)号：US5416168A
公开(公告)日：1995-05-16
申请号：US220804
申请日：1994-03-31
申请人： Carl L. Willis , Robert C. Bening
发明人： Carl L. Willis , Robert C. Bening
IPC分类号： C08L9/00 , C07F7/18 , C08F4/00 , C08F4/42 , C08F4/48 , C08F36/00 , C08F36/04 , C08F136/06 , C08L21/00 , C08F36/06 , C07F7/04
CPC分类号： C08F36/04 , C07F7/1864 , C08F4/48
摘要： The anionic polymerization of unsaturated monomers with functionalized initiators having the structure R.sup.1 R.sup.2 R.sup.3 Si--O--A'--Li is improved when each R is methyl and A' is --CH.sub.2 --C.sub.6 H.sub.10 --CH.sub.2 -- or --CH.sub.2 --CR'R"--CH.sub.2 -- wherein R' is a linear alkyl having from 1 to 10 carbon atoms and R" is hydrogen or a linear alkyl having from 1 to 10 carbon atoms. This initiator provides process and product advantages over all other known initiators of the same type.
摘要翻译： 当R 1为甲基且A'为-CH 2 -C 6 H 10 -CH 2 - 或-CH 2 -CR'R“-CH 2 - （CH 3））时，不饱和单体与具有结构R1R2R3Si-O-A'-Li结构的官能化引发剂的阴离子聚合得到改善， 其中R'是具有1至10个碳原子的直链烷基，R“是氢或具有1至10个碳原子的直链烷基。 该起始物相对于相同类型的所有其它已知的引发剂提供了方法和产物优点。
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10.发明授权
公开(公告)号：US5356974A
公开(公告)日：1994-10-18
申请号：US217472
申请日：1994-03-24
IPC分类号： C08C19/40 , C08F8/00 , C08G18/62 , C09D175/04
CPC分类号： C09D175/04 , C08C19/40 , C08F8/00 , C08F8/04 , C08F8/12 , C08F8/32 , C08G18/6208 , C08F2810/20
摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
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