公开(公告)号：US11427680B2

公开(公告)日：2022-08-30

申请号：US16469636

申请日：2017-12-12

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Cristiano Monzani ,  Vito Tortelli ,  Marco Galimberti ,  Roberto Valsecchi ,  Patrizia Maccone

IPC: C08G65/00 ,  C08G65/323 ,  C08G65/331 ,  G11B5/71 ,  C10M107/38

Abstract: The present invention relates to a novel process for the synthesis of (per)fluoropolyether polymers, to certain novel (per)fluoropolyether polymers. The present invention also relates to the use of the (per)fluoropolyether polymers thus obtained as intermediate compounds for the manufacture of further polymers suitable for use as lubricants, notably for magnetic recording media (MRM).

公开(公告)号：US10737997B2

公开(公告)日：2020-08-11

申请号：US16089903

申请日：2017-03-28

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Marco Galimberti ,  Vito Tortelli ,  Emanuela Antenucci ,  Giuseppe Marchionni

IPC: C07C51/41 ,  C07C68/00

Abstract: A method for the manufacture of perfluorinated compounds is herein disclosed. In particular, the method is useful for the manufacture of perfluorooxyalkyl carboxylic acid salts which can be used as surfactants. The method envisages the fluorination or a fluoroformate of an alcohol comprising a —CH2OCH2-moiety at a temperature equal to or higher than 20° C. and allows obtaining high yields and selectivity.

公开(公告)号：US10047045B2

公开(公告)日：2018-08-14

申请号：US14909280

申请日：2014-07-25

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Cristiano Monzani ,  Vito Tortelli

IPC: C07F9/02 ,  C07C381/00 ,  C08F216/14

Abstract: A process for the preparation of fluorinated compounds having at least one —OSF5 group, said method comprising the step of reacting SOF4 with a fluorinated 3- or 4-membered cyclic ether in the presence of a fluoride catalyst.

公开(公告)号：US09944593B2

公开(公告)日：2018-04-17

申请号：US15027167

申请日：2014-09-30

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Cristiano Monzani ,  Vito Tortelli

IPC: C07C303/32 ,  C07D213/20 ,  C07C277/08 ,  C07C209/00 ,  C07D487/04 ,  C07C211/63 ,  C07C279/06 ,  C07C309/06

CPC classification number: C07C303/32 ,  C07C209/00 ,  C07C211/63 ,  C07C277/08 ,  C07C279/06 ,  C07C309/06 ,  C07D213/20 ,  C07D487/04 ,  C07C279/04 ,  C07C309/10

Abstract: A process for the preparation of the fluoroalkyl sulfonate salt of a nitrogen-based organic base said process comprising the step of reacting a fluoroalkyl sulfonyl halide with an organic base selected from the group consisting of tertiary amines, pyridines, amidines and guanidines.

公开(公告)号：US20140378621A1

公开(公告)日：2014-12-25

申请号：US14365482

申请日：2012-12-06

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Vito Tortelli ,  Alessio Marrani ,  Ivan Wlassics ,  Ivan Falco

IPC: C08F214/22 ,  C08J5/18

CPC classification number: C08F214/22 ,  C08J5/18 ,  C08J2327/24 ,  C08K5/28 ,  C08K5/43 ,  C08L27/16

Abstract: The present invention relates to crosslinkable compositions comprising vinylidene fluoride (VDF)/trifluoroethylene (TrFE) polymers and a fluorine-containing crosslinking agent of formula (A) [agent (Cz)]: {N3[S(O)g1]s1}na—(RH)nh—Rf—(R′H)nh′—{[S(O)g2],s2N3}na′, formula (A) wherein each of g1 and g2, equal to or different from each other, is 1 or 2, each of s1 and s2, equal to or different from each other, is 0 or 1, each of na and na′ is independently zero or an integer of 1 to 3, provided that the sum na+na′ is at least 2, each of RH and R′H, equal to or different from each other, is a C1-C12 hydrocarbon group free of fluorine atoms, nh and nh′, equal or different from each other are independently 0 or 1, and Rf is selected from the group consisting of i) a C3-C20 fluorocarbon group, possibly comprising one or more ethereal oxygen atoms, ii) an oligomer comprising copolymerized units of vinylidene fluoride and trifluoroethylene, to a process for the manufacture of said compositions, to a method for curing the same, and to the use of said copolymers in electrical and electronic devices.

Abstract translation: 本发明涉及包含偏二氟乙烯（VDF）/三氟乙烯（TrFE）聚合物和式（A）的含氟交联剂[试剂（Cz）]的交联组合物：{N 3 [S（O）g1] s1} - （RH）nh-Rf-（R'H）nh' - {[S（O）g2]，s2N3} na'，式（A）其中g1和g2各自相同或不同， 如图1或图2所示，s1和s2中的每一个彼此等于或不同，为0或1，na和na'各自独立为零或1至3的整数，条件是总和na + na'在 至少2个，RH和R'H各自相同或不同，为不含氟原子的C1-C12烃基，nh和nh'彼此相同或不同，分别为0或1，Rf 选自i）可能包含一个或多个醚性氧原子的C 3 -C 20碳氟化合物基团，ii）包含偏二氟乙烯和三氟乙烯的共聚单元的低聚物，其制备方法 所述组合物，其固化方法以及所述共聚物在电气和电子设备中的用途。

公开(公告)号：US20140329970A1

公开(公告)日：2014-11-06

申请号：US14365423

申请日：2012-12-06

Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

Inventor： Ivan Wlassics ,  Vito Tortelli ,  Alessio Marrani

IPC: C08F214/22 ,  C07C311/49

CPC classification number: C08F214/222 ,  C07C311/49 ,  C08F14/18 ,  C08F214/22 ,  C08K5/0025 ,  C08K5/43

Abstract: This invention pertains to fluoroallylsulfonyl azide compounds of formula: CF2═CF—CF2—Rf—SO2N3 formula (I) wherein Rf is a divalent (per)fluorinated group, optionally comprising one or more than one ethereal oxygen atom [monomer (Az)], which are useful as functional monomers in fluoropolymers, to the fluoropolymers which comprise recurring units derived from such fluoroallylsulfonyl azide compounds, to a process for their manufacture, to a curable compound comprising the same and to a method for crosslinking the same.

Abstract translation: 本发明涉及式（I）的氟代烯丙基磺酰基叠氮化合物，其中R f是二价（全）氟化基团，任选地包含一个或多于一个醚类氧原子[单体（Az）] 其可用作含氟聚合物中的官能单体，含氟聚合物，其包含衍生自这些氟代烯丙基磺酰基叠氮化合物的重复单元，其制备方法，包含该聚合物的可固化化合物及其交联方法。