Method of operating a non-balanced lithium-ion microbattery
    22.
    发明授权
    Method of operating a non-balanced lithium-ion microbattery 有权
    操作非平衡锂离子微电池的方法

    公开(公告)号:US08389138B2

    公开(公告)日:2013-03-05

    申请号:US12818708

    申请日:2010-06-18

    Abstract: The lithium-ion microbattery comprises a positive electrode having a first Li+ ion storage capacity and a first thickness made from a first lithium insertion material, an electrolyte and a negative electrode having a second storage capacity and a second thickness made from a second insertion material. The thicknesses are such that the ratio of the first storage capacity over the second storage capacity is greater than or equal to 10 and lower than or equal to 1000. During the first charging of the micro-battery, the Li+ ions are inserted in the negative electrode and completely saturate the second insertion material. When initial charging is continued, they form a metallic lithium layer between the electrolyte and the lithium-saturated negative electrode by electroplating. During the subsequent charging and discharging cycles, only the metallic lithium layer participates in transfer of lithium ions.

    Abstract translation: 锂离子微电池包括具有第一Li +离子存储容量的正极和由第一锂插入材料制成的第一厚度,具有第二存储容量的电解质和负极以及由第二插入材料制成的第二厚度。 厚度使得第一存储容量与第二存储容量之比大于或等于10且小于或等于1000.在微电池的第一次充电期间,将Li +离子插入到负极 电极并使第二插入材料完全饱和。 当继续进行初始充电时,它们通过电镀在电解质和锂饱和负极之间形成金属锂层。 在随后的充放电循环中,只有金属锂层参与锂离子的转移。

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