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公开(公告)号:US20160118637A1
公开(公告)日:2016-04-28
申请号:US14919136
申请日:2015-10-21
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kazuhei NARITA , Jun Ishikawa , Teppei Oguni , Aya Uchida
IPC: H01M2/16 , H01M10/0569 , H01G11/62 , H01M10/0525 , H01G11/50 , H01G11/28
CPC classification number: H01M2/1673 , H01G11/28 , H01G11/50 , H01G11/52 , H01M2/1626 , H01M2/18 , H01M10/0525 , H01M10/0566 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
Abstract: When cellulose is used as a separator, the cellulose is impregnated with an ionic liquid. Charge and discharge are repeated with this separator touching a surface of a current collector; then, the separator is changed in color. Thus, it is an object to provide a power storage device with a structure in which a side reaction other than a battery reaction, e.g., a change in color of separator, is unlikely to occur. In the power storage device, a separator impregnated with an ionic liquid is not in contact with a surface of a current collector. The separator has a tubular shape, a bag-like shape, or a sheet-like shape. The separator includes cellulose. The power storage device including the ionic liquid is non-volatile and non-flammable. The power storage device can be bent.
Abstract translation: 当纤维素用作隔膜时,用离子液体浸渍纤维素。 用分离器接触集电器的表面重复充电和放电; 那么分离器的颜色就会改变。 因此,本发明的目的是提供一种电池存储装置,其具有除电池反应以外的副反应(例如隔膜的颜色变化)不可能发生的结构。 在蓄电装置中,浸渍有离子液体的隔膜不与集电体的表面接触。 隔膜具有管状,袋状或片状。 分离器包括纤维素。 包括离子液体的蓄电装置是非挥发性和不易燃的。 蓄电装置可弯曲。
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公开(公告)号:US20250158054A1
公开(公告)日:2025-05-15
申请号:US19023705
申请日:2025-01-16
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Jyo SAITO , Mayumi MIKAMI , Yohei MOMMA , Teruaki OCHIAI , Tatsuyoshi TAKAHASHI , Kazuhei NARITA
IPC: H01M4/525 , H01M4/02 , H01M4/36 , H01M10/0525 , H01M10/0569
Abstract: A positive electrode active material that has high capacity and excellent charge and discharge cycle performance for a secondary battery is provided. A positive electrode active material that inhibits a decrease in capacity in charge and discharge cycles is provided. A high-capacity secondary battery is provided. A secondary battery with excellent charge and discharge characteristics is provided. A highly safe or reliable secondary battery is provided. A positive electrode active material contains lithium, cobalt, oxygen, and aluminum and has a crystal structure belonging to a space group R-3m when Rietveld analysis is performed on a pattern obtained by powder X-ray diffraction. In analysis by X-ray photoelectron spectroscopy, the number of aluminum atoms is less than or equal to 0.2 times the number of cobalt atoms.
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公开(公告)号:US20230327207A1
公开(公告)日:2023-10-12
申请号:US18141841
申请日:2023-05-01
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Nobuhiro INOUE , Masaki YAMAKAJI , Jun ISHIKAWA , Kazuhei NARITA
IPC: H01M10/0568 , H01M4/36 , H01M4/587 , H01M4/38 , H01M4/62 , H01M10/0525 , H01M10/054
CPC classification number: H01M10/0568 , H01M4/366 , H01M4/587 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/625 , H01M10/0525 , H01M10/054 , H01M2004/021
Abstract: A storage battery includes positive and negative electrodes and an electrolytic solution. The negative electrode includes a first element and carbon. The first element is any of silicon, tin, gallium, aluminum, germanium, lead, antimony, bismuth, silver, zinc, cadmium, and indium. The negative electrode includes an active material and a first layer in contact with a surface of the active material. The first layer has a thickness of 10 nm to 1000 nm inclusive. The electrolytic solution contains first and second cations. The first cation is one or more of a lithium ion, a sodium ion, a calcium ion, and a magnesium ion. The second cation is an imidazolium cation or a tertiary sulfonium cation.
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24.
公开(公告)号:US20230135556A1
公开(公告)日:2023-05-04
申请号:US17906450
申请日:2021-03-17
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kazuhei NARITA , Yohei MOMMA , Shunpei YAMAZAKI
Abstract: A method for manufacturing a positive electrode active material with high charge and discharge capacity is provided. Alternatively, a method for manufacturing a positive electrode active material with high charge and discharge voltage is provided. Alternatively, a method for manufacturing a power storage device with little deterioration is provided. Alternatively, a method for manufacturing a highly safe power storage device is provided. Alternatively, a method for manufacturing a novel power storage device is provided. A method for manufacturing a secondary battery including a positive electrode active material is provided. A method for manufacturing the positive electrode active material includes a first step of synthesizing a first lithium source and a first transition metal source to form a first composite oxide; a second step of synthesizing an impurity source to provide an impurity layer for the first composite oxide after the first step; and a third step of synthesizing a second lithium source and a second transition metal source to form a second composite oxide after the second step and providing the second composite oxide over the first composite oxide provided with the impurity layer.
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25.
公开(公告)号:US20220371906A1
公开(公告)日:2022-11-24
申请号:US17621792
申请日:2020-06-16
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kazuhei NARITA , Jo SAITO , Yohei MOMMA , Teruaki OCHIAI , Mayumi MIKAMI
Abstract: A positive electrode active material that has high capacity and excellent charge and discharge cycle performance for a secondary battery is provided. The positive electrode active material includes a group of particles including a first group of particles and a second group of particles. The group of particles includes lithium, cobalt, nickel, aluminum, magnesium, oxygen, and fluorine. When the number of cobalt atoms included in the group of particles is taken as 100, the number of nickel atoms is greater than or equal to 0.05 and less than or equal to 2, the number of aluminum atoms is greater than or equal to 0.05 and less than or equal to 2, and the number of magnesium atoms is greater than or equal to 0.1 and less than or equal to 6. When particle size distribution in the group of particles is measured by a laser diffraction and scattering method, the first group of particles has a first peak and the second group of particles has a second peak; the first peak has a local maximum value at longer than or equal to 2 μm and shorter than or equal to 4 μm, and the second peak has a local maximum value at longer than or equal to 9 μm and shorter than or equal to 25 μm.
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公开(公告)号:US20220190319A1
公开(公告)日:2022-06-16
申请号:US17438645
申请日:2020-03-19
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kazuhei NARITA , Mayumi MIKAMI , Yohei MOMMA , Teruaki OCHIAI , Jo SAITO
IPC: H01M4/36 , H01M4/525 , H01M10/0525
Abstract: A positive electrode active material for a lithium-ion secondary battery and with high capacity and excellent charging and discharging cycle performance is provided. The positive electrode active material contains lithium, cobalt, nickel, aluminum, and oxygen, and the spin density attributed to one or more of a divalent nickel ion, a trivalent nickel ion, a divalent cobalt ion, and a tetravalent cobalt ion is within a predetermined range. It is preferable that the positive electrode active material further contain magnesium. An appropriate magnesium concentration is represented by a concentration with respect to cobalt. It is preferable that the positive electrode active material further contain fluorine.
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公开(公告)号:US20210184214A1
公开(公告)日:2021-06-17
申请号:US16761504
申请日:2018-11-16
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Mayumi MIKAMI , Yohei MOMMA , Kazutaka KURIKI , Kazuhei NARITA
IPC: H01M4/58 , H01M10/0562 , H01M10/0525 , H01M4/62 , H01M4/587
Abstract: A conduction path in an all-solid-state secondary battery is difficult to keep with a volume change in an active material due to charging and discharging in some cases.
A positive electrode active material with a small volume change between the charged state and the discharged state is used for an all-solid-state secondary battery. For example, a positive electrode active material that has a layered rock-salt crystal structure in the discharged state and a crystal structure similar to the cadmium chloride type crystal structure in the charged state with a depth of charge of approximately 0.8 changes less in its volume and crystal structure between charging and discharging than known positive electrode active materials.-
公开(公告)号:US20210175573A1
公开(公告)日:2021-06-10
申请号:US17179979
申请日:2021-02-19
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Ryota TAJIMA , Kazuhei NARITA , Kensuke YOSHIZUMI
IPC: H01M50/209 , H01M50/543 , H01M50/50 , H01M50/116 , H01M50/531
Abstract: A battery module with high impact resistance is provided. A battery module using an elastic body such as rubber for its exterior body covering a battery is provided. A bendable battery module is provided. As the exterior body covering a battery, an elastic body such as rubber is used, and the exterior body is molded in two steps. First, a first portion provided with a depression in which a battery is stored is molded using a first mold. Next, a battery is inserted into the first portion. Subsequently, second molding is performed using a second mold so as to fill an opening of the depression in the first portion, so that a second portion is formed. The second portion serves as a cover for closing the opening of the depression in the first portion. The second portion is formed in contact with part of the electrodes in the battery and part of an end portion of the second exterior body in the battery.
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公开(公告)号:US20210143404A1
公开(公告)日:2021-05-13
申请号:US17086959
申请日:2020-11-02
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Mayumi MIKAMI , Kazuhei NARITA , Teruaki OCHIAI , Yumiko YONEDA
IPC: H01M4/1397 , H01M4/04 , H01M4/62 , H01M4/58 , H01M10/0525 , H01M4/136
Abstract: A method for manufacturing a lithium-ion secondary battery more safely at a lower cost is provided. A method for manufacturing a positive electrode for a secondary battery includes a step of forming slurry by mixing graphene oxide, a binder, and a positive electrode active material in a solvent containing water; a step of applying the slurry on a positive electrode current collector; and a step of reducing graphene oxide by at least one of chemical reduction and thermal reduction. As a reducing agent for the chemical reduction, ascorbic acid can be used.
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30.
公开(公告)号:US20170237127A1
公开(公告)日:2017-08-17
申请号:US15519692
申请日:2015-10-15
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Jun ISHIKAWA , Kazuhei NARITA , Teppei OGUNI , Aya UCHIDA
IPC: H01M10/42 , H01G11/70 , H01G11/86 , H01G11/52 , H01M4/58 , H01G11/08 , H01M10/0525 , H01M4/66 , H01M4/04 , H01M4/587 , H01G11/28 , H01G11/68
CPC classification number: H01M10/4235 , H01G11/06 , H01G11/08 , H01G11/26 , H01G11/28 , H01G11/52 , H01G11/68 , H01G11/70 , H01G11/86 , H01M4/0404 , H01M4/0471 , H01M4/13 , H01M4/139 , H01M4/5825 , H01M4/587 , H01M4/66 , H01M4/661 , H01M4/667 , H01M10/0525 , H01M2004/021 , Y02T10/7011
Abstract: A power storage device with a high capacity is provided. A power storage device with a high energy density is provided. A highly reliable power storage device is provided. A power storage device with a long lifetime is provided.A method for manufacturing an electrode is characterized by including the steps of: mixing an active material, a binder, and a conductive additive to form a slurry; applying the slurry onto a current collector; drying the applied slurry to form an active material layer; and performing heat treatment in an atmosphere containing oxygen to form a film in contact with the current collector. The film is formed on a surface of the current collector where the active material layer is not provided and includes at least one component of the current collector and oxygen.
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