公开(公告)号：US20100035155A1

公开(公告)日：2010-02-11

申请号：US12515212

申请日：2007-11-16

申请人： Shigeto Okada ,  Manabu Nishijima ,  Takayuki Doi ,  Jun-ichi Yamaki ,  Irina D. Gocheva ,  Toshiyasu Kiyabu

发明人： Shigeto Okada ,  Manabu Nishijima ,  Takayuki Doi ,  Jun-ichi Yamaki ,  Irina D. Gocheva ,  Toshiyasu Kiyabu

IPC分类号： H01M4/58 ,  H01B1/02

CPC分类号： H01M10/0562 ,  C01G1/06 ,  C01P2006/40 ,  H01M4/13 ,  H01M4/582 ,  H01M4/626 ,  H01M10/0525 ,  Y02T10/7011

摘要： In a non-aqueous electrolyte secondary battery, in order to adjust a cathode active material in which guest cation such as Na and Li is included, alkaline metal fluoride which is expressed by a general formula AF and transition metal fluoride which is expressed by a formula M′ F2 are subjected to a mechanical milling process to produce metal fluoride compound AM′ F3. The mechanical milling process desirably uses a planetary ball mill.

摘要翻译： 在非水电解质二次电池中，为了调整包含Na和Li等客体阳离子的正极活性物质，由通式AF表示的碱金属氟化物和由式 对M'F2进行机械研磨处理以产生金属氟化物化合物AM'F3。 机械铣削加工优选使用行星式球磨机。

公开(公告)号：US20080213674A1

公开(公告)日：2008-09-04

申请号：US12035486

申请日：2008-02-22

申请人： Shigeto Okada ,  Plashnitsa Larisa ,  Eiji Kobayashi ,  Yoshinori Noguchi ,  Takayuki Doi ,  Jun-ichi Yamaki ,  Toshihiro Yoshida ,  Kazuhiro Yamamoto ,  Hiroyuki Katsukawa

发明人： Shigeto Okada ,  Plashnitsa Larisa ,  Eiji Kobayashi ,  Yoshinori Noguchi ,  Takayuki Doi ,  Jun-ichi Yamaki ,  Toshihiro Yoshida ,  Kazuhiro Yamamoto ,  Hiroyuki Katsukawa

IPC分类号： H01M10/26 ,  H01M10/28

CPC分类号： H01M4/5825 ,  H01M4/136 ,  H01M10/0525 ,  H01M10/054 ,  H01M10/0566 ,  Y10T29/49108

摘要： The present invention provides a secondary battery using a liquid electrolyte excellent in storage characteristics. The secondary battery includes a cathode, an anode, and a liquid electrolyte, where the cathode and the anode contain at least one mutual active material. This symmetrical electrode configuration, that the at least one active material for the cathode and the anode is mutual, enables equalization of an electrode electric potential difference before charge or after discharge; and thus electrolyte degradation is efficiently restrained to improve storage characteristics.

摘要翻译： 本发明提供使用储存特性优异的液体电解质的二次电池。 二次电池包括阴极，阳极和液体电解质，其中阴极和阳极包含至少一种相互活性材料。 用于阴极和阳极的至少一种活性材料相互的对称电极结构使得能够在充电之前或放电之后均衡电极电位差; 因此有效地抑制电解质降解以改善储存特性。

公开(公告)号：US4675260A

公开(公告)日：1987-06-23

申请号：US796084

申请日：1985-11-08

申请人： Yoji Sakurai ,  Toshiro Hirai ,  Shigeto Okada ,  Takeshi Okada ,  Jun-ichi Yamaki ,  Hideaki Ohtsuka

发明人： Yoji Sakurai ,  Toshiro Hirai ,  Shigeto Okada ,  Takeshi Okada ,  Jun-ichi Yamaki ,  Hideaki Ohtsuka

IPC分类号： H01M4/131 ,  H01M4/48 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/36 ,  H01M6/16 ,  H01M6/18

CPC分类号： H01M4/485 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M4/131

摘要： A lithium battery essentially consisting of an amorphous cathode active material mainly composed of V.sub.2 O.sub.5 and prepared by adding with at least one first additive selected from the group consisting of P.sub.2 O.sub.5, TeO.sub.2, GeO.sub.2, Sb.sub.2 O.sub.3, Bi.sub.2 O.sub.3 and B.sub.2 O.sub.3 and/or at least one second additive selected from the group consisting of MoO.sub.3 and WO.sub.3, heating to melt the admixture and then quenching the molten admixture; an anode active material made of metallic lithium or a lithium alloy; and an electrolyte made of a mixture of a aprotic solvent and a lithium salt. The battery is a small-sized and light-weight secondary battery having a high energy density and being improved in charge-discharge cycle lifetime.

摘要翻译： 一种锂电池，其主要由主要由V 2 O 5组成的无定形正极活性材料组成，并通过添加至少一种选自P 2 O 5，TeO 2，GeO 2，Sb 2 O 3，Bi 2 O 3和B 2 O 3的第一添加剂和/或至少一种第二添加剂 选自MoO 3和WO 3，加热熔融混合物，然后淬火熔融混合物; 由金属锂或锂合金制成的负极活性材料; 以及由非质子溶剂和锂盐的混合物制成的电解质。 电池是具有高能量密度并且充放电循环寿命得到改善的小尺寸和重量轻的二次电池。

公开(公告)号：US10305145B2

公开(公告)日：2019-05-28

申请号：US15124220

申请日：2015-01-19

申请人： Hirofumi Nakamoto ,  Zempachi Ogumi ,  Jun-ichi Yamaki

发明人： Hirofumi Nakamoto ,  Zempachi Ogumi ,  Jun-ichi Yamaki

IPC分类号： H01M10/0568 ,  H01M10/05 ,  H01M10/0569 ,  H01M6/16 ,  H01M4/58 ,  H01M4/583

摘要： The problem to be solved is to provide a liquid electrolyte for a fluoride ion battery which allows a larger capacity of the battery. Solving the problem by providing a liquid electrolyte for a fluoride ion battery including a fluoride salt and a solvent to dissolve the fluoride salt, characterized in that the solvent is an aromatic material having an aromatic cation and an anion, and a molar ratio of the aromatic cation to a fluoride ion is more than 1.

公开(公告)号：US5368958A

公开(公告)日：1994-11-29

申请号：US932593

申请日：1992-08-20

申请人： Toshiro Hirai ,  Jun-ichi Yamaki

发明人： Toshiro Hirai ,  Jun-ichi Yamaki

IPC分类号： H01M2/26 ,  H01M4/134 ,  H01M4/66 ,  H01M6/10 ,  H01M10/05 ,  H01M4/02 ,  H01M4/58

CPC分类号： H01M10/05 ,  H01M2/26 ,  H01M4/134 ,  H01M4/66 ,  H01M6/10

摘要： Lithium based electrical cells having a new anode electrode construction are described. The cells have a sandwich construction of lithium sheet, conductive foil and lithium sheet, wherein the anode tab is welded directly onto the conductive foil not onto the lithium. Alternatively, the tab is connected onto the lithium in an area where the lithium does not dissolve during discharge, so that the tab will not become disconnected from the anode sheet.

摘要翻译： 描述了具有新的阳极电极结构的锂基电池。 电池具有锂片，导电箔和锂片的夹层结构，其中阳极片直接焊接到导电箔上而不是锂上。 或者，在放电期间，锂在锂不溶解的区域中连接到锂上，使得突片不会与阳极片断开。

公开(公告)号：US4737424A

公开(公告)日：1988-04-12

申请号：US925379

申请日：1986-10-31

申请人： Shin-ichi Tobishima ,  Masayasu Arakawa ,  Toshiro Hirai ,  Jun-ichi Yamaki

发明人： Shin-ichi Tobishima ,  Masayasu Arakawa ,  Toshiro Hirai ,  Jun-ichi Yamaki

IPC分类号： H01M4/131 ,  H01M4/48 ,  H01M4/485 ,  H01M4/58 ,  H01M4/60 ,  H01M6/16 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/36

CPC分类号： H01M4/485 ,  H01M10/052 ,  H01M10/0569 ,  H01M4/5815 ,  H01M10/0568 ,  H01M2300/0037 ,  H01M4/131 ,  H01M4/581

摘要： The present invention provides an electrolyte for use on a secondary lithium battery comprising amorphous V.sub.2 O.sub.5 base cathode active material, a metallic lithium base active material, and an electrolytic solution lithium salt dissolved in a mixed organic solvent. The organic solvent is ethylene carbonate mixed with one organic solvent of 2-methyltetrahydrofuran, 2,5-dimethyltetrahydrofuran, 1,3-dioxalan, 4-methyl-1,3-dioxalan, 1,2-dimethoxyethane, etc. The mixed ratio of ethylene carbonate ranges within 10 to 50%, and water content of the electrolytic solution ranges within 400 to 5 ppm, and the content of impurities other than water ranges within 1000 to 10 ppm. The resultant secondary lithium battery is excellent in charge-discharge cycle life.

摘要翻译： 本发明提供了一种用于二次锂电池的电解质，其包含非晶体V 2 O 5基底阴极活性材料，金属锂基活性材料和溶解在混合有机溶剂中的电解液锂盐。 有机溶剂是与2-甲基四氢呋喃，2,5-二甲基四氢呋喃，1,3-二氧杂环戊烷，4-甲基-1,3-二氧杂环戊烷，1,2-二甲氧基乙烷等的一种有机溶剂混合的碳酸亚乙酯。 碳酸亚乙酯的范围为10〜50％，电解液的含水量为400〜5ppm，水以外的杂质含量为1000〜10ppm以下。 所得二次锂电池的充放电循环寿命优异。