Metal ion porphyrin-containing poly(imide)
    23.
    发明授权
    Metal ion porphyrin-containing poly(imide) 失效
    含金属离子卟啉的聚(酰亚胺)

    公开(公告)号:US5312896A

    公开(公告)日:1994-05-17

    申请号:US958916

    申请日:1992-10-09

    CPC classification number: C08G73/1085 C08G73/0672

    Abstract: The present invention relates to porphyrins and to metal ion-containing monomers and polymers. The monomer ##STR1## wherein A, R.sup.1,R.sup.2,R.sup.3, and R.sup.4 defined herein, is used with dianhydride to produce a porphyrin polymer or a metal ion containing porphyrin polymer. These polymers are useful as electrical conductors and as liquid crystal polymers, non-linear (NLO) materials, magnetic materials, electrochromic polymers photo-and electrocatalysts and advanced materials.

    Abstract translation: 本发明涉及卟啉和含金属离子的单体和聚合物。 将本文定义的A,R1,R2,R3和R4的单体与二酐一起使用以产生卟啉聚合物或含有卟啉聚合物的金属离子。 这些聚合物可用作电导体和液晶聚合物,非线性(NLO)材料,磁性材料,电致变色聚合物光电催化剂和先进材料。

    Novel solid polymer electrolytes
    25.
    发明授权
    Novel solid polymer electrolytes 失效
    新型固体聚合物电解质

    公开(公告)号:US5061581A

    公开(公告)日:1991-10-29

    申请号:US476270

    申请日:1990-02-07

    Abstract: An amorphous ionically conductive macromolecular solid is set forth having improved ambient temperature ionic conductivity. The solid comprises a solid solution of at least one positively charged ionic species dissolved in a macromolecular material, the macromolecular material comprising a polymer or copolymer having a polyether structure and having at least a portion of the ether oxygens thereof replaced with S or NR wherein R includes at least one basic site capable of associating with the positively charged ionic species and has 2 to 10 carbon atoms. Relatively high conductivity is a feature of the macromolecular solid of the invention.

    Abstract translation: 介绍了具有改善的环境温度离子电导率的非晶离子导电性高分子固体。 固体包含溶解在大分子材料中的至少一个带正电荷的离子物质的固溶体,该高分子材料包含具有聚醚结构的聚合物或共聚物,并且其至少一部分醚氧被S或NR取代,其中R 包括能够与带正电荷的离子物质缔合并具有2至10个碳原子的至少一个碱性位点。 相对高的电导率是本发明的大分子固体的特征。

    Method of forming patterned oxide superconducting films
    26.
    发明授权
    Method of forming patterned oxide superconducting films 失效
    形成图案化氧化物超导膜的方法

    公开(公告)号:US5021398A

    公开(公告)日:1991-06-04

    申请号:US428392

    申请日:1989-10-26

    Abstract: The present invention describes a method to produce a patterned superconducting solid preferably as a thin film. Unsaturated organic acid metal salts of suitable metals are dissolved in an organic solvent, mixed thoroughly and cast as a film on a substrate. The concentration of these organic carboxylate metal salts is adjusted such that a superconducting metal oxide ratio is obtained upon pyrolysis at temperatures up to 1000.degree. C. with subsequent slow cooling. A pattern (mask) is placed over the film and the film is irradiated to polymerize and crosslink the exposed portions. The unpolymerized and uncrosslinked portions are removed usually by using selective solvents or solvent mixtures. The solid remaining is heated in oxygen or air to about 1000.degree. C., which removes the organic portions and leaves metal oxide residue. The metal oxides are then cooled slowly and annealed to produce the patterned metal oxide superconducting materials. The articles of manufacture produced are useful in fabricating devices requiring superconducting thin films in addition to other uses.

    Abstract translation: 本发明描述了优选制成薄膜的图案化超导固体的方法。 将适当金属的不饱和有机酸金属盐溶解在有机溶剂中,充分混合并在基材上以膜的形式浇铸。 调节这些有机羧酸金属盐的浓度,使得在高达1000℃的温度下热解得到超导金属氧化物比,随后缓慢冷却。 将图案(掩模)放置在膜上并且膜被照射以聚合和交联暴露部分。 未聚合和未交联的部分通常通过使用选择性溶剂或溶剂混合物除去。 将剩余的固体在氧气或空气中加热至约1000℃,除去有机部分并留下金属氧化物残余物。 然后将金属氧化物缓慢冷却并退火以产生图案化的金属氧化物超导材料。 制造的制品在制造除了其它用途之外还需要超导薄膜的装置中是有用的。

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