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21.
公开(公告)号:US20180327565A1
公开(公告)日:2018-11-15
申请号:US15975994
申请日:2018-05-10
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: KONSTANTINOS KONTOMARIS , TIM MCRAE
CPC classification number: C08J9/146 , C08F12/08 , C08J9/0066 , C08J9/36 , C08J2201/03 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2205/042 , C08J2205/044 , C08J2205/052 , C08J2325/06 , C08J2325/08 , C08J2325/12 , C08L25/06 , C08L25/12 , C08L2203/14
Abstract: A process is provided for preparing a thermoplastic polymer foam, comprising providing a foamable composition comprising a thermoplastic polymer and a blowing agent, wherein the blowing agent comprises from 10% to 60% by weight Z-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzz) and from 40% to 90% by weight 1,1-difluoroethane (HFC-152a), and wherein said thermoplastic polymer comprises polystyrene homopolymer, a polystyrene copolymer, styrene-acrylonitrile copolymer, or blends thereof expanding said foamable composition to produce a closed cell, smooth skin polymer foam, having a density of less than 42 kg/m2. Also disclosed is a thermoplastic polymer foam composition comprising a thermoplastic polymer selected from the group consisting of polystyrene homopolymer, a polystyrene copolymer, styrene-acrylonitrile copolymer, or blends thereof, defining a plurality of cells having an average cell size, and a blowing agent comprising from 10% to 60% by weight Z-1,1,1,4,4,4-hexafluoro-2-butene (Z-HFO-1336mzz) and from 40% to 90% by weight 1,1-difluoroethane (HFC-152a), having a density of less than 42 kg/m2, according to ISO method 845-85, wherein the thermoplastic polymer has a melt flow rate of less than 25 g/10 min.
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公开(公告)号:US20180002506A1
公开(公告)日:2018-01-04
申请号:US15546000
申请日:2016-02-03
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: MARIO JOSEPH NAPPA , XUEHUI SUN , IVAN SERGEYEVICH BALDYCHEV , SHENG PENG , KONSTANTINOS KONTOMARIS , BARBARA HAVILAND MINOR , JOSEPH ANTHONY CREAZZO
CPC classification number: C08J9/143 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C09K3/30 , C09K5/045 , C09K2205/12 , C09K2205/122 , C09K2205/126 , C09K2205/22 , C09K2205/40
Abstract: The present disclosure relates to compositions comprising Z-1,1,1,4,4,4-hexafluoro-2-butene and additional compounds that may be useful as refrigerants, heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, power cycle working fluids, extinguishing agents, and fire suppression agents in liquid or vapor form.
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公开(公告)号:US20170306205A1
公开(公告)日:2017-10-26
申请号:US15517866
申请日:2015-10-09
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: KONSTANTINOS KONTOMARIS , ROBERT DANIEL LOUSENBERG
CPC classification number: C09K5/045 , C09K5/04 , C09K2205/126 , F01K7/32 , F01K25/00 , F25B21/02 , Y02E10/46
Abstract: A method is provided for converting heat from a heat source to mechanical energy. The method comprises heating a working fluid using heat supplied from the heat source; and expanding the heated working fluid to lower pressure of the working fluid and generating mechanical energy as the pressure of the working fluid is lowered. The method is characterized by using a working fluid comprising (2E)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene (HFO-153-10mzzy). Also provided is a power cycle apparatus. The apparatus is characterized by containing a working fluid comprising HFO-153-10mzzy.
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24.
公开(公告)号:US20170275514A1
公开(公告)日:2017-09-28
申请号:US15506639
申请日:2015-09-03
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: KONSTANTINOS KONTOMARIS , ROBERT DANIEL LOUSENBERG
CPC classification number: C09K5/04 , C07C21/18 , C09K5/045 , C09K2205/126 , C09K2205/24 , F04D17/12 , F25B30/02 , F28D15/02 , Y02B30/52 , Y02P20/124
Abstract: A method for producing heating in a high temperature heat pump having a heat exchanger is provided. The method comprises extracting heat from a working fluid, thereby producing a cooled working fluid wherein said working fluid comprises (2E)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene (“HFO-153-10mzzy”). Also, a high temperature heat pump apparatus is provided containing a working fluid comprising HFO-153-10mzzy. Also a composition is provided comprising (i) a working fluid consisting essentially of HFO-153-10mzzy; and (ii) a stabilizer to prevent degradation at temperatures of 55° C. or above, or (iii) a lubricant suitable for use at 55° C. or above, or both (ii) and (iii).
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25.
公开(公告)号:US20240299793A1
公开(公告)日:2024-09-12
申请号:US18662270
申请日:2024-05-13
Applicant: THE CHEMOURS COMPANY FC,LLC
Inventor: MARK L. ROBIN , KONSTANTINOS KONTOMARIS
IPC: A62D1/00 , A01N29/00 , A62D1/02 , B01D11/02 , C08J9/14 , C09K3/30 , C09K5/00 , C09K5/04 , C10M105/04 , C10M105/52 , C11D7/50 , H01B3/24 , H01B3/56 , H05F3/04
CPC classification number: A62D1/0057 , A01N29/00 , A62D1/0071 , A62D1/0092 , B01D11/0288 , C08J9/144 , C08J9/146 , C09K3/30 , C09K5/00 , C09K5/044 , C09K5/045 , C09K5/048 , C10M105/04 , C10M105/52 , C11D7/5018 , H01B3/24 , H01B3/56 , H05F3/04 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C08J2367/00 , C09K2205/12 , C09K2205/126 , C09K2205/24 , C09K2205/32 , C10M2203/045 , C10M2211/0225
Abstract: Disclosed is a mixture comprising the compound trans-1,1,1,4,4,4-hexafluoro-2-butene and 1,1-difluoroethane (R-152a). Also disclosed are methods of using and products of using the above compositions as blowing agents, solvents, heat transfer compositions, aerosol propellant compositions, fire extinguishing and suppressant compositions.
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26.
公开(公告)号:US20240158597A1
公开(公告)日:2024-05-16
申请号:US18282069
申请日:2022-06-09
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: KONSTANTINOS KONTOMARIS
IPC: C08J9/14
CPC classification number: C08J9/149 , C08J9/142 , C08J9/146 , C08J2201/03 , C08J2203/12 , C08J2203/142 , C08J2203/162 , C08J2203/202 , C08J2205/044 , C08J2205/052 , C08J2323/06 , C08J2323/12 , C08J2325/06
Abstract: Disclosed is a process for preparing a thermoplastic polymer foam. The process includes providing a molten foamable composition including a thermoplastic polymer and a blowing agent. The blowing agent includes from about 2.0 to about 7.0 parts by weight per hundred resin of the thermoplastic polymer (phr) of 1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzz) and from about 0.73 to about 15.37 phr of methyl formate. At least 50%, by weight, of the HFO-1336mzz is E-1,1,1,4,4,4-hexafluoro-2-butene (E-HFO-1336mzz). The thermoplastic polymer is a polystyrene homopolymer, a polystyrene copolymer, a styrene-acrylonitrile copolymer, a polyethylene, a polypropylene, or a blend thereof. The process also includes extruding the molten foamable composition to produce the thermoplastic polymer foam. The thermoplastic polymer foam has a plurality of cells with at least 80% of the cells being closed cells. The thermoplastic polymer foam is essentially free of structural defects. A thermoplastic polymer foam includes a thermoplastic polymer and a blowing agent.
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公开(公告)号:US20220235192A1
公开(公告)日:2022-07-28
申请号:US17613975
申请日:2020-05-29
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: KONSTANTINOS KONTOMARIS
Abstract: This invention relates to the use of HFO-1336mzz-Z/cyclopentane blends as blowing agents for thermoplastic polymers (e.g., polystyrene).
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公开(公告)号:US20220203149A1
公开(公告)日:2022-06-30
申请号:US17698447
申请日:2022-03-18
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: MARK L. ROBIN , KONSTANTINOS KONTOMARIS
IPC: A62D1/00 , C08J9/14 , C09K5/04 , C09K3/30 , C10M105/52 , C10M105/04 , A01N29/00 , C11D7/50 , H01B3/56 , H05F3/04 , B01D11/02 , A62D1/02 , C09K5/00 , H01B3/24
Abstract: Disclosed is a mixture comprising the compound trans-1,1,1,4,4,4-hexafluoro-2-butene and at least one additional compound selected from the group consisting of HFOs, HFCs, HFEs, CFCs, CO2, olefins, organic acids, alcohols, hydrocarbons, ethers, aldehydes, ketones, and others such as methyl formate, formic acid, trans-1,2 dichloroethylene, carbon dioxide, cis-HFO-1234ze+HFO-1225yez, mixtures of these plus water; mixtures of these plus CO2; mixtures of these trans 1,2-dichloroethylene (DCE); mixtures of these plus methyl formate; mixtures with cis-HFO-1234ze+CO2, mixtures with cis-HFO-1234ze+HFO-1225yez+CO2, and mixtures with cis-HFO-1234ze+HFC-245fa. Also disclosed are methods of using and products of using the above compositions as blowing agents, solvents, heat transfer compositions, aerosol propellant compositions, fire extinguishing and suppressant compositions.
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29.
公开(公告)号:US20210340421A1
公开(公告)日:2021-11-04
申请号:US17279622
申请日:2019-10-03
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: LUKE DAVID SIMONI , BARBARA HAVILAND MINOR , KONSTANTINOS KONTOMARIS , VIACHESLAV A PETROV
Abstract: This invention relates to compositions comprising 1,2-dichloro-1,2-difluoroethylene (i.e., CFO-1112) and an additional component. The compositions described herein may be useful, for example, in heat transfer applications.
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公开(公告)号:US20180002507A1
公开(公告)日:2018-01-04
申请号:US15546001
申请日:2016-02-03
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: MARIO JOSEPH NAPPA , XUEHUI SUN , IVAN SERGEYEVICH BALDYCHEV , SHENG PENG , KONSTANTINOS KONTOMARIS , BARBARA HAVILAND MINOR , JOSEPH ANTHONY CREAZZO
Abstract: The present disclosure relates to compositions comprising E-1,1,1,4,4,4-hexafluoro-2-butene and additional compounds that may be useful as refrigerants, heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, power cycle working fluids, extinguishing agents, and fire suppression agents in liquid or vapor form, and in methods for detecting leaks.
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