摘要:
Dihydroxydiphenyl cycloalkanes corresponding to the formula ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl and C.sub.7 -C.sub.12 aralkyl,m is an integer of from 4 to 7,R.sup.3 and R.sup.4, individually selectable for each X, independently of one another represent hydrogen or C.sub.1 -C.sub.6 alkylandX represents carbon with the proviso that, at at least one atom X, both R.sup.3 and R.sup.4 are alkyl,a process for their production, their use for the production of high molecular weight polycarbonates, the polycarbonates made from dihydroxydiphenyl cycloalkane of formula (I) and films made from these polycarbonates.
摘要:
This invention relates to a process for the preparation of substituted cycloalkylidene bisphenols from phenols and special cycloalkanones in the presence of acid condensation catalysts and in the presence of water.
摘要:
Highly heat distortion resistant moulding compositions are disclosed comprising an aromatic polycarbonate having molecular weights Mw (weight average) of a least 10,000, containing bifunctional carbonate structural units corresponding to formula (Ia) ##STR1## wherein R.sup.1 and R.sup.2 denote, independently of one another, hydrogen, halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.12 -aralkyl,m stands for an integer from 4 to 7,R.sup.3 and R.sup.4, which are selected individually for each X, denote, independently of one another, hydrogen or C.sub.1 -C.sub.6 -alkyl, andX denotes carbonunder the condition that R.sup.3 and R.sup.4 are both alkyl on at least one X atom andas the only thermo stabilizer, from 0.001 to 1% by weight of a siloxane corresponding to formula (II) ##STR2## wherein R and R' denote, independently of one another, C.sub.1 -C.sub.4 -alkyl or -aryl andx and y stand for the numbers 1,2 or 3 and x+y always add up to 4.
摘要:
The invention relates to ternary thermoplastic mixtures of polycarbonates, polyurethanes and graft polymers and, optionally, standard additives and to processes for the production of these mixtures.
摘要:
Thermoplastic polydiorganosiloxane/polycarbonate block copolymers based on dihydroxydiphenylcycloalkanes corresponding to the following general formula (I): ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1 -C.sub.8 alkyl, C.sub.5 or C.sub.6 cycloalkyl, C.sub.5 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, in particular benzyl: m represents an integer of from 4 to 7, preferably 4 or 5;R.sup.3 and R.sup.4 may be chosen individually for each X and independently represent hydrogen or C.sub.1 -C.sub.12 alkyl; andX represents carbon; with the proviso that R.sup.3 and R.sup.4 both represent alkyl on at least one atom X,having an average molecular weight M.sub.w (weight average) of 10 000 to 300 000, a content of aromatic polycarbonate of 21 to 99.5% by weight and a content of polyorganosiloxane of 79 to 0.5% by weight.
摘要:
A process for the preparation of a phenol and solvent free polycarbonate resin is disclosed comprising(i) forming an oligomeric polycarbonate comprising structural units based on a diphenol corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently of one another denote a member selected from the group consisting of a hydrogen atom, a halogen atom, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aryl and C.sub.7-12 aralkyl radicals,m is an integer of from 4 to 7,X represents carbon andR.sup.3 and R.sup.4 are individually selected for each X and independently of one another represent a hydrogen atom or a C.sub.1-6 alkyl radical, with the proviso that for at least one X atom, both R.sup.3 and R.sup.4 are alkyl radicals, and(ii) condensing said oligomeric polycarbonate at a temperature in the range of of 140 to 350.degree. C.
摘要:
The invention relates to a thermoplastic molding composition comprising(A) from 10 to 98 parts by weight of a polydiorganosiloxane-polycarbonate block copolymer having a weight average molecular weight of from 10,000 to 200,000 and containing from 75 to 97.5 wt. % of aromatic carbonate structural units and from 25 to 2.5 wt. % of polydiorganosiloxane structural units;(B) from 2 to 90 parts by weight of a thermoplastic, aromatic polycarbonate having a weight average molecular weight of at least 10,000, andcontaining bifunctional carbonate structural units corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl;m represents an integer of from 4 to 7,R.sup.3 and R.sup.4, which may be selected individually for each X, independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andx represents carbon,with the proviso that, on at least one atom X, R.sup.3 and R.sup.4 both represent alkyl; and(C) from 0.5 to 30 parts by weight of a rubber having a glass transition temperature of less than -20.degree. C.The composition of the invention is useful for the preparation of injection molded articles having an excellent surface and a particularly good toughness at low temperatures.
摘要:
Copolycarbonates derived from known bisphenols and small quantities of dihydroxydiphenyl cycloalkanes corresponding to formula (I) ##STR1## wherein R.sup.1 and R.sup.2 denote, independently of one another, hydrogen, halogen, preferably chlorine or bromine, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl, preferably phenyl, and C.sub.7 -C.sub.12 aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, in particular benzyl,m denotes an integer with a value from 4 to 7, preferably 4 or 5,R.sup.3 and R.sup.4, which are selected independently for each X, denote, independently of one another, hydrogen or C.sub.1 to C.sub.6 alkyl, andX denotes carbon under the condition that R.sup.3 and R.sup.4 are both alkyl on at least one X atoms are disclosed. These copolycarbonates are characterized by their improved processing stability.
摘要:
Fire-retardant polycarbonates, polyester carbonates and polyesters based on dihydroxydiphenyl cycloalkanes ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl, preferably phenyl and C.sub.7 -C.sub.12 aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, more especially benzyl,m is an integer of 4 to 7, preferably 4 or 5, R.sup.3 and R.sup.4 may be individually selected for each X and, independently of one another, represent hydrogen or C.sub.1 -C.sub.6 alkyl andX is carbon,with the proviso that, at at least one atom X, R.sup.3 and R.sup.4 are both alkyl,the fire-retardant finish being provided by additives and/or comonomers.
摘要:
The present invention relates to a process for producing polymer blends from polycarbonate and mass-polymerized ABS by the condensation of oligocarbonate in the presence of mass-polymerized ABS.