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    QUICK-START SYSTEM FOR PREPARING HYDROGEN VIA AQUEOUS METHANOL AND HYDROGEN PREPARATION METHOD
    24.
    发明申请
    QUICK-START SYSTEM FOR PREPARING HYDROGEN VIA AQUEOUS METHANOL AND HYDROGEN PREPARATION METHOD 审中-公开
    通过甲醇制备氢气和氢气制备方法的快速启动系统

    公开(公告)号：US20160272491A1

    公开(公告)日：2016-09-22

    申请号：US15036810

    申请日：2014-11-14

    Applicant: SHANGHAI HYDROGEN MOBILE REFRMER INSTRUMENT CO. LTD.

    Inventor： HUA XIANG ,  DEFU XIANG ,  JINGJING SUN

    IPC: C01B3/32 ,  C01B3/56 ,  B01J7/02

    CPC classification number: C01B3/323 ,  B01J7/02 ,  B01J8/0403 ,  B01J19/242 ,  B01J19/243 ,  B01J2208/00141 ,  B01J2208/00415 ,  B01J2208/00716 ,  B01J2219/00083 ,  B01J2219/00135 ,  B01J2219/1944 ,  C01B3/505 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0405 ,  C01B2203/0475 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/1223 ,  C01B2203/1288 ,  C01B2203/1604 ,  Y02P20/128 ,  Y02P30/30

    Abstract: Disclosed are a quick-start system for preparing hydrogen via aqueous methanol, and hydrogen preparation method. The system comprises a liquid storage container, a raw material feeding device, a quick-start device, a hydrogen preparation equipment and a membrane separation device; the quick-start device comprises a first start device and a second start device; the first start device comprises a first heating mechanism and a first gasification pipeline, the first gasification pipeline is wound around the first heating mechanism; one end of the first gasification pipeline is connected to the liquid storage container, and methanol is fed into the first gasification pipeline via the raw material feeding device, for the first heating mechanism to heat and gasify; the hydrogen preparation equipment comprises a reforming chamber; the second start device comprises a second gasification pipeline, a main body of the second gasification pipeline is disposed in the reforming chamber; the methanol output by the first gasification pipeline and/or the second gasification pipeline heats the second gasification pipeline while heating the reforming chamber, to gasify the methanol in the second gasification pipeline. The present invention can be quickly started, while having less energy consumption and good practicability.

    Abstract translation: 公开了一种通过甲醇水溶液制备氢气的快速启动系统，以及氢气制备方法。 该系统包括液体储存容器，原料供给装置，快速启动装置，氢气制备装置和膜分离装置; 快速启动装置包括第一启动装置和第二启动装置; 第一启动装置包括第一加热机构和第一气化管道，第一气化管道围绕第一加热机构缠绕; 第一气化管道的一端与储液容器连接，经由原料供给装置将甲醇送入第一气化管路，第一加热机构进行加热气化; 氢气制备设备包括重整室; 第二启动装置包括第二气化管道，第二气化管道的主体设置在重整室中; 由第一气化管道和/或第二气化管道输出的甲醇在加热重整室的同时加热第二气化管道，使第二气化管道中的甲醇气化。 本发明可以快速启动，同时具有较少的能量消耗和良好的实用性。

    Method for the production of formaldehyde
    25.
    发明授权
    Method for the production of formaldehyde 有权
    甲醛生产方法

    公开(公告)号：US07109382B2

    公开(公告)日：2006-09-19

    申请号：US10312520

    申请日：2001-06-12

    Applicant: Giancarlo Sioli

    Inventor： Giancarlo Sioli

    IPC: C07C45/29

    CPC classification number: B01J8/067 ,  B01J8/0403 ,  B01J8/0419 ,  B01J8/0446 ,  C07C45/38 ,  C07C47/04

    Abstract: A method for formaldehyde production through catalytic oxidation of methanol, comprising the steps of feeding to a first oxidation catalytic bed (2) a gas flow comprising methanol and oxygen at a predetermined crossing linear flow rate, obtaining at the outlet of said first catalytic bed (2) a flow of gaseous reaction products comprising unreacted methanol, and feeding the flow of gaseous products to a second oxidation catalytic bed (6) is distinguished by the fact that the flow of gaseous reaction products comprising unreacted methanol is fed to the second catalytic bed (6) with a crossing linear flow rate substantially equal to said predetermined first catalytic bed (2) feeding flow rate.

    Abstract translation: 一种通过甲醇的催化氧化生产甲醛的方法，包括以下步骤：以预定的交联线性流速向第一氧化催化床（2）供给包含甲醇和氧气的气流，在所述第一催化床的出口 2）包含未反应的甲醇的气态反应产物流并将气态产物流送入第二氧化催化剂床（6）的特征在于将包含未反应的甲醇的气态反应产物的流量送入第二催化床 （6），其交叉线性流速基本上等于所述预定的第一催化床（2）进料流量。

    Use of steam eductor to supply oxygen for oxidative reheating in dehydrogenation of C.sub.3 + hydrocarbons
    29.
    发明授权
    Use of steam eductor to supply oxygen for oxidative reheating in dehydrogenation of C.sub.3 + hydrocarbons 失效
    使用蒸汽喷射器在C3 +烃脱氢中提供氧气进行氧化再加热

    公开(公告)号：US5043500A

    公开(公告)日：1991-08-27

    申请号：US453899

    申请日：1989-12-20

    Applicant: Constante P. Tagamolila

    Inventor： Constante P. Tagamolila

    IPC: B01J8/04 ,  C07C5/32 ,  C07C5/333

    CPC classification number: C07C5/321 ,  B01J8/0403 ,  B01J8/0415 ,  C07C5/333

    Abstract: A dehydrogenation process, where a hydrocarbon feed is dehydrogenated in a dehydrogenation zone and then oxidatively reheated by the combustion of hydrogen in an oxidation zone containing an oxidation catalyst, is improved by using a stream of dilution steam as an educing fluid to draw oxygen into contact with the effluent from the dehydrogenation zone ahead of the oxidation zone. A stream of dilution steam is often combined with the dehydrogenation zone effluent in order to control the oxygen concentration ahead of the oxidation zone and to lower the hydrogen partial pressure. Educing the oxygen-containing gas for the oxidation zone into the process by using the dilution steam an an educing fluid eliminates the need for compression of the oxygen-containing gas and prevents oxygen from contacting the dehydrogenation zone effluent before the dilution steam is admixed therewith. This process is particularly beneficial in the dehydrogenation of ethylbenzene to produce styrene.

    Abstract translation: 通过使用稀释蒸汽流作为教导流体将氧吸入到接触中，其中烃进料在脱氢区中脱氢然后通过在含有氧化催化剂的氧化区中的氢气的燃烧而被再加热的脱氢方法得到改善 来自脱氢区的污水在氧化区之前。 稀释蒸汽流通常与脱氢区流出物组合以控制氧化区之前的氧浓度并降低氢分压。 通过使用稀释蒸汽将氧化区的含氧气体引入该过程，教育流体消除了对含氧气体的压缩的需要，并且在稀释蒸汽混合之前防止氧气与脱氢区流出物接触。 该方法特别有利于乙苯的脱氢生产苯乙烯。

    Reaction method and reactor therefor
    30.
    发明授权
    Reaction method and reactor therefor 失效
    反应方法及其反应器

    公开(公告)号：US4594227A

    公开(公告)日：1986-06-10

    申请号：US530298

    申请日：1983-09-08

    Applicant: Kozo Ohsaki ,  Jun Zanma ,  Hiroshi Watanabe

    Inventor： Kozo Ohsaki ,  Jun Zanma ,  Hiroshi Watanabe

    IPC: C07C27/06 ,  B01J8/02 ,  B01J8/04 ,  B01J8/06 ,  B01J19/24 ,  C01C1/04 ,  C07C27/00 ,  C07C29/15 ,  C07C29/152 ,  C07C31/02 ,  C07C67/00 ,  F28D7/00

    CPC classification number: C01C1/0417 ,  B01J8/0285 ,  B01J8/0403 ,  B01J2208/00132 ,  Y02P20/52

    Abstract: An apparatus for carrying out a catalytic chemical reaction in the presence of a granular catalyst under conditions such that both the reactants and the reaction product are gaseous at the temperature and pressure of the reaction. According to the present invention, a vertically extending, annular, intercylinder space, defined between a cylindrical outer catalyst retainer and a cylinder inner catalyst retainer, is divided by radially extending vertical partition walls into a plurality of chambers. Heat-exchanging tubes are disposed vertically in at least one of the chambers. A granular catalyst is packed in at least two of said chambers to form at least two reaction chambers. A feed gas is caused to flow successively and in radial directions through these reaction chambers. Since the invention reactor achieves an improved linear gas flow velocity and a greater overall heat-transfer coefficient, the reactor of the invention requires fewer heat-exchanging tubes and can thus be made smaller. The optimum temperature distribution for the reaction can be attained in each reaction chamber.

    Abstract translation: 在粒状催化剂存在下进行催化化学反应的装置，使反应物和反应产物在反应的温度和压力下都是气态的。 根据本发明，限定在圆柱形外部催化剂保持器和气缸内部催化剂保持器之间的垂直延伸的环形间隙空间被径向延伸的垂直分隔壁分成多个室。 热交换管垂直设置在至少一个室中。 将颗粒状催化剂填充在至少两个所述室中以形成至少两个反应室。 使进料气体依次流过这些反应室并沿径向流动。 由于本发明反应器实现了改进的线性气体流速和更大的总传热系数，所以本发明的反应器需要更少的热交换管，并且因此可以使其更小。 反应的最佳温度分布可以在每个反应室中实现。

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