公开(公告)号：US20090043072A1

公开(公告)日：2009-02-12

申请号：US12283943

申请日：2008-09-17

申请人： Lon-Tang Wilson Lin ,  William Jacobs, III

发明人： Lon-Tang Wilson Lin ,  William Jacobs, III

IPC分类号： C08G69/40

CPC分类号： C08G12/40 ,  C08G12/427 ,  C08L61/28

摘要： This invention relates to a crosslinking composition comprising and organic acid and a compound having the structure of Formula I: A′—NRA—RD where A′ is a moiety derived from the group consisting of triazines, linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof, or a moiety comprising the structure: where RA is RD, hydrogen, an alkyl of 1 to 20 carbon atoms, or taken together with A′ forms a cyclic compound; RD is —CHRCORB, wherein RB is hydrogen, alkyl, aryl, aralkyl or an alkaryl having from 1 to about 24 carbon atoms and RC is an alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; A is a moiety derived from the group consisting of linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof; B is a residue of a poly(alkylaldehyde) with n aldehyde groups; n is an integer of 2 to about 8; Ra is Rd, hydrogen, an alkyl of 1 to about 20 carbon atoms, or taken together with A forms a cyclic compound; where Rd is CHRcORb or where Rb is hydrogen, alkyl, aryl, aralkyl or an alkaryl having from 1 to about 24 carbon atoms and Rc is an alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; and where the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure. This invention also relates to a process for producing the crosslinking composition by reacting an amino compound containing amino groups; a mono(alkylaldehyde) and/or a poly(alkylaldehyde), and an alcohol; and adding an organic compound where said amino compound is selected from the group consisting of: triazines, linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof.

公开(公告)号：US06719931B2

公开(公告)日：2004-04-13

申请号：US10169092

申请日：2002-07-10

申请人： Dietrich Hoffman ,  Herbert Eisermann

发明人： Dietrich Hoffman ,  Herbert Eisermann

IPC分类号： B01J1302

CPC分类号： C08G12/32 ,  B01F17/0057 ,  B01J13/206 ,  B41M5/165 ,  C08G12/06 ,  C08G12/427 ,  C08L61/28 ,  C09D11/02 ,  D21H21/54

摘要： Described is a process for preparing a dispersion of microcapsules by condensing a partially methylated melamine-formaldehyde resin having a molar ratio of melamine:formaldehyde:methanol of from 1:3.0:2.0 to 1:6.0:4.0 in water in which the essentially water-insoluble material forming the capsule core is present in dispersion in the presence of an alkali metal salt of a homopolymer or copolymer of 2-acrylamido-2-methylpropanesulfonic acid as protective colloid at a pH of from 3 to 6.5 by preforming the microcapsules at a temperature of from 20 to 50° C. and then curing the capsule wall of the preformed microcapsules at >50 to 100° C., which comprises adding from 5 to 100% by weight of melamine, based on the melamine-formaldehyde resin, in the course of curing. The microcapsule dispersions are formaldehyde-reduced and of low viscosity.

摘要翻译： 描述了通过将具有1:3.0:2.0至1:6.0:4.0的三聚氰胺：甲醛：甲醇的摩尔比的部分甲基化的三聚氰胺 - 甲醛树脂在基本上水溶性的水中冷凝来制备微胶囊的分散体的方法， 形成胶囊核心的不溶性材料以分散体的形式存在于2-丙烯酰胺基-2-甲基丙烷磺酸的均聚物或共聚物的碱金属盐存在下，作为保护胶体，pH为3至6.5，通过在温度下预先形成微胶囊 20至50℃，然后在> 50至100℃下固化预成型微胶囊的胶囊壁，其包括以5-100重量％的基于三聚氰胺 - 甲醛树脂的三聚氰胺加入 治愈过程。 微胶囊分散体是甲醛降低的和低粘度的。

公开(公告)号：US20020000536A1

公开(公告)日：2002-01-03

申请号：US09783233

申请日：2001-02-14

发明人： George T. Spitz ,  George D. Vaughn ,  Patricia A. Ball

IPC分类号： C09K003/00

CPC分类号： C07D251/64 ,  C07D251/70 ,  C08G12/427

摘要： Crosslinker compositions consisting essentially of 50 to 95 weight percent monomeric C1 to C8 alkoxymethyl melamine derivatives containing not more than about 0.20 wt. % of imino (>NnullH) groups. Such compositions further comprise 5 to 50 weight percent oligomeric C1 to C8 alkoxymethyl melamine derivatives and are useful for low temperature curing of functional resins, e.g. with active hydroxyl groups, for wood, automotive, appliance, coil and other coatings.

摘要翻译： 基本上由50至95重量％的单体C1至C8烷氧基甲基三聚氰胺衍生物组成的交联剂组合物，其含量不超过约0.20重量％ ％的亚氨基（> N-H）基团。 这样的组合物还包含5至50重量％的低聚C1至C8烷氧基甲基三聚氰胺衍生物，并且可用于功能性树脂的低温固化，例如。 具有活性羟基，用于木材，汽车，家电，线圈等涂料。

公开(公告)号：US5047466A

公开(公告)日：1991-09-10

申请号：US476760

申请日：1990-02-08

申请人： Gerd Busse ,  Jakob Decher ,  Wolfgang Eisele ,  Edgar Haeussler ,  Otto Wittmann

发明人： Gerd Busse ,  Jakob Decher ,  Wolfgang Eisele ,  Edgar Haeussler ,  Otto Wittmann

IPC分类号： C08G12/32 ,  C08G12/42 ,  C08L61/32 ,  D21H27/12 ,  H05K1/03

CPC分类号： H05K1/0346 ,  C08G12/32 ,  C08G12/427 ,  C08L61/32

摘要： Amino resin solutions having an electrical conductivity of

摘要翻译： 具有导电率<100μS/ cm的浸渍纸的氨基树脂溶液可以通过以下步骤获得：A）三聚氰胺与甲醛水溶液在叔有机胺存在下摩尔比为1:2至1:5时的甲氧基化 pH为7至12，B）在未取代或取代的二羧酸和/或多元羧酸的存在下，在pH为3的条件下，基于羟甲基的摩尔过量醚化C1-C4-醇 至6，C）除了基于反应混合物的含水量<10重量％以外，通过蒸馏除去挥发性成分，除去反应混合物，并且D）添加C1-C4 醇，以固体含量为基准，以氨基树脂溶液为40-90重量％，并通过过滤除去不溶组分。

公开(公告)号：US4374164A

公开(公告)日：1983-02-15

申请号：US330422

申请日：1981-12-14

申请人： Werner J. Blank

发明人： Werner J. Blank

IPC分类号： C08L33/00 ,  B05D1/36 ,  C08G12/42 ,  C08L33/02 ,  C08L33/04 ,  C08L61/28 ,  C08L61/32 ,  C08L67/00 ,  C08L67/08 ,  C09D133/06 ,  C09D161/32 ,  C09D167/00 ,  B05D3/02

CPC分类号： C09D167/00 ,  C08G12/427 ,  C09D133/06 ,  C09D161/32 ,  B05D7/546 ,  C08L61/32 ,  C08L67/00

摘要： A high solids polymer resin coating composition cross-linked with alkylated melamine resins possessing improved intercoat adhesion in multiple coating applications. A mixed methylated isobutylated melamine resin as a cross-linking agent for the high solids polymer resin coating composition surprisingly substantially eliminates intercoat adhesion failure without any negative effects on overall coating properties and performance. The backbone polymer of the composition may advantageously be acrylic resin, a polyester resin or mixtures thereof while the mixed methylated isobutylated melamine resin cross-linking agent is advantageously predominantly monomeric poly(methoxy isobutoxymethyl) melamine resin with an average methoxy content of 1-5 and an average isobutoxy content of 5-1, per triazine.

摘要翻译： 与烷基化三聚氰胺树脂交联的高固含量聚合物树脂涂料组合物在多种涂料应用中具有改进的层间粘合性。 作为用于高固含量聚合物树脂涂料组合物的交联剂的混合甲基化异丁基三聚氰胺树脂令人惊奇地基本上消除了层间粘附破坏，而对整体涂料性能和性能没有任何负面影响。 组合物的主链聚合物可以有利地是丙烯酸树脂，聚酯树脂或其混合物，而混合的甲基化异丁基三聚氰胺树脂交联剂有利地主要是平均甲氧基含量为1-5的单体聚（甲氧基异丁氧基甲基）三聚氰胺树脂， 每三嗪的平均异丁氧基含量为5-1。

公开(公告)号：US4303561A

公开(公告)日：1981-12-01

申请号：US42976

申请日：1979-05-29

申请人： Steffen Piesch ,  Alfons Wolf

发明人： Steffen Piesch ,  Alfons Wolf

IPC分类号： C08G12/00 ,  C08G12/26 ,  C08G12/32 ,  C08G12/42 ,  C08K5/05 ,  C08L61/32 ,  C08G12/30 ,  C08L1/10

CPC分类号： C08G12/427 ,  C08G12/266 ,  C08L61/32

摘要： Partially etherified melamine-formaldehyde resins having a melamine: formaldehyde molar ratio of 1:(1.25 to 1) can be prepared by a condensation reaction under neutral or weakly alkaline conditions if the condensation reaction is carried out in the presence of a glycol monoether of the general formula IR (OCH.sub.2 CH.sub.2).sub.n OH (I)wherein R denotes alkyl having 1 to 4 C atoms and n denotes a number from 1 to 5. The partially etherified melamine-formaldehyde resins are suitable for the production of compression moulding compositions having a high flow and minimal processing shrinkage and after-shrinkage.

摘要翻译： 具有三聚氰胺：甲醛摩尔比为1：（1.25:1）的部分醚化蜜胺 - 甲醛树脂可以在中性或弱碱性条件下通过缩合反应制备，如果缩合反应在二醇单醚存在下进行 通式IR（OCH 2 CH 2）n OH（I）其中R表示具有1至4个C原子的烷基，n表示1至5的数。部分醚化的三聚氰胺 - 甲醛树脂适用于生产具有 高流动性和最小的加工收缩率和收缩后。

公开(公告)号：US4157994A

公开(公告)日：1979-06-12

申请号：US833770

申请日：1977-09-16

申请人： Stuart M. Totty ,  James A. Meier

发明人： Stuart M. Totty ,  James A. Meier

IPC分类号： C08F20/00 ,  C08F20/26 ,  C08F212/00 ,  C08G12/42 ,  C08L25/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L59/00 ,  C08L61/20 ,  C09D125/00 ,  C09D125/06 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/20 ,  C09D161/20

CPC分类号： C09D133/066 ,  C08G12/427 ,  C09D125/06 ,  C09D133/20 ,  C08L61/20

摘要： A water-reducible acrylic enamel coating composition capable of being substantially completely cured at a relatively low temperature, such as about 250.degree. F. and containing a water-miscible partially etherified melamine formaldehyde cross-linking agent and an acrylic copolymerization product of about 3% to about 8% of an unsaturated carboxylic acid, about 10% to 30% of a hydroxy functional monomer and about 62% to 87% of a nonfunctional monomer. The acrylic copolymer is further characterized as having a glass transition temperature of about -10.degree. C. to 45.degree. C. and a molecular weight of about 2,000 to about 100,000. The aminoplast resin preferably is only partially etherified and contains about 10% to about 30% by weight reactive methylol groups.

摘要翻译： 一种可水稀释的丙烯酸搪瓷涂料组合物，其能够在比较低的温度例如约250°F下基本上完全固化，并含有水混溶的部分醚化的三聚氰胺甲醛交联剂和约3％ 至约8％的不饱和羧酸，约10％至30％的羟基官能单体和约62％至87％的非官能单体。 丙烯酸共聚物的特征还在于具有约-10℃至45℃的玻璃化转变温度和约2,000至约100,000的分子量。 氨基塑料树脂优选仅部分醚化并且含有约10重量％至约30重量％的反应性羟甲基。

公开(公告)号：US4039493A

公开(公告)日：1977-08-02

申请号：US590215

申请日：1975-06-25

申请人： Manfred Schon ,  Helmut Durr ,  Dieter Plath ,  Karlfried Keller ,  Walter Michel

发明人： Manfred Schon ,  Helmut Durr ,  Dieter Plath ,  Karlfried Keller ,  Walter Michel

IPC分类号： C08G12/00 ,  C08G12/32 ,  C08G12/42 ,  C08L61/20 ,  C08L67/00 ,  C09D133/06 ,  C08K5/05 ,  C08L91/00

CPC分类号： C08L67/00 ,  C08G12/427 ,  C09D133/064 ,  C08L61/20

摘要： Low-viscosity high-solids-content melamine-formaldehyde condensates having high reactivity, low content of free formaldehyde and good compatibility, are prepared by effecting condensation in an alcohol having up to 3 carbons, then concentrating the condensate and heating the concentrate in a higher alcohol having from 3 to 18 carbons and again concentrating. The final product cures on heating to a hard glossy film and can be added to other uncured resins to improve the hardness of their films.

摘要翻译： 通过在具有最多3个碳的醇中进行缩合制备具有高反应性，低游离甲醛含量和良好相容性的低粘度高固含量三聚氰胺 - 甲醛缩合物，然后浓缩冷凝物并将浓缩物加热至更高 具有3至18个碳原子并再次浓缩的醇。 最终产品在加热至硬质光泽膜时固化，并可加入其他未固化的树脂中以提高其膜的硬度。

公开(公告)号：US3647755A

公开(公告)日：1972-03-07

申请号：US3647755D

申请日：1970-06-26

申请人： ALBERT AG CHEM WERKE

发明人： GILLER ARNOLD

IPC分类号： C08G12/42 ,  C08G9/30

CPC分类号： C08G12/427

摘要： A PROCESS FOR THE MANUFACTURE OF ETHERIFIED MELAMINE RESINS BY REACTING ONE MOL OF MELAMINE AT AN ELEVATED TEMPERATURE WITH LESS THAN 3 MOLS OF FORMALDEHYDE POLYMER AND AT LEAST 4 MOLS OF A MONOHYDRIC ALIPHATIC WATERIMMISCIBLE ALCOHOL IN THE PRESENCE OF A CATALYTIC QUANTITY OF AN ACID AND CONTINUOUSLY REMOVING WATER BY DESTILLATION, COATINGS AND AN IMPREGNATED MATERIAL CONTAINING THE PRODUCTS OF THE PROCESS.

公开(公告)号：US3594328A

公开(公告)日：1971-07-20

申请号：US3594328D

申请日：1969-12-09

申请人： CIBA LTD

发明人： SCHIBLER LUZIUS

IPC分类号： B01J13/02 ,  B01J13/08 ,  C08G12/42 ,  C08L61/32 ,  B44D1/02

CPC分类号： C08L61/32 ,  B01J13/02 ,  B01J13/08 ,  C08G12/422 ,  C08G12/427

摘要： AN ENCAPSULATION PROCESS IS PROVIDED WHEREIN THE SUBSTANCE TO BE ENCAPSULATED IS DISPERSED IN A LIQUID WITH WHICH IT IS SUBSTANTIALLY IMMISCIBLE IN THE PRESENCE OF A TENSIDE CAPABLE OF FORMING A COMPOUND THAT IS INSOLUBLE IN THE DISPERSING LIQUID AND THEREAFTER THE TENSIDE IN THE DISPERSION, WHICH IS IN ASSOCIATION WITH THE SUBSTANCE, IS CONVERTED INTO THE IRREVERSIBLY INSOLUBLE STATE TO ENCAPSULATE THE SUBSTANCE. PARTICULARLY SUITABLE A TENSIDES ARE THE SURFACE-ACTIVE, CROSS-LINKABLE AMINOPLASTS, PREFERABLY SURFACE-ACTIVE, ETHERIFIED METHYLOMELAMINES OR THE CORRESPONDING METHYLOLUREAS.