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公开(公告)号：US4053388A
公开(公告)日：1977-10-11
申请号：US747863
申请日：1976-12-06
Applicant: Angus B. Bailey
Inventor： Angus B. Bailey
IPC: C10G69/08 , C07C1/00 , C07C5/373 , C07C15/02 , C07C15/08 , C07C67/00 , C10G50/00 , C10G59/02 , C10G23/00 , C10G34/00
Abstract: This invention is directed to producing a high yield of aromatics from naphtha by integrating a catalytic reformer and a thermal hydrocracking unit followed by fractionating the product stream to obtain the desired aromatic. In this process, after sulfur is removed, the naphtha is catalytically reformed under conditions adapted to provide the maximum aromatic content. The reformed stream is then thermally hydrocracked, preferably in a system containing multiple reactors. The process does not require an external source of hydrogen since the reforming and hydrocracking units are operated to maintain a hydrogen balance. The hydrocracked stream is fractionated in a series of columns to produce the desired mix of aromatics. In one example, the fractionation separates out (1) benzene, which is further purified, if necessary (2) a toluene stream and a C.sub.9 + aromatic stream which are charged to a transalkylation reactor to produce a composition containing mixed xylenes sent to recycle and (3) a mixed xylene stream from which paraxylene is separated by a liquid-solid adsorption technique and from which the remaining xylenes are isomerized to produce further paraxylene. A by-product stream of light hydrocarbons is also produced. This procedure can be readily modified to produce greater amounts of benzene and/or toluene and less xylene.
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公开(公告)号：US4053387A
公开(公告)日：1977-10-11
申请号：US693829
申请日：1976-06-08
Applicant: Robert F. Bridger , Costandi A. Audeh , El-Ahmadi I. Heiba
Inventor： Robert F. Bridger , Costandi A. Audeh , El-Ahmadi I. Heiba
CPC classification number: C10G17/095 , C10G29/00 , C10G2400/10
Abstract: A two-step process for preparing a stabilized lubricating oil resistant to oxidation and sludge formation upon exposure to a highly oxidative environment is provided. The first step of the present process comprises contacting a lubricating oil stock with elemental sulfur in the presence of a catalyst material selcted from the group consisting of alumina, silica, aluminosilicate, a metal of Groups II-A, II-B, VI-B or VIII of the Periodic Table of Elements, an oxide of a metal of Groups II-A, II-B, VI-B or VIII, a sulfide of a metal of Groups II-A, II-B, VI-B or VIII, clay, silica combined with an oxide of a metal of Groups II-A, III-A, IV-B or V-B, and combinations thereof in a flow reactor or under conditions comparable to those existing in a flow reactor. The second step of the present process comprises contacting the product of the first step with hydrogen in the presence of alumina impregnated with at least about 10 weight percent of MoO.sub.3 and at least about 2.5 weight percent of CoO, said impregnated alumina having at least 50 percent of its pores with a pore diameter of 50 Angstrom Units or more.
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公开(公告)号：US4006076A
公开(公告)日：1977-02-01
申请号：US583139
申请日：1975-06-02
Applicant: Robert I. Christensen , George D. Gould
Inventor： Robert I. Christensen , George D. Gould
CPC classification number: C10G67/0463 , B01J27/188 , B01J35/10 , B01J35/1042 , B01J35/1061 , C10G2300/107
Abstract: Hydrocarbon mixtures having low sulfur contents are obtained from sulfur-containing vacuum gas oils by hydrodesulfurizing the gas oils under mild hydrodesulfurizing conditions, including use of:1. a select high-activity hydrodesulfurization catalyst,2. a temperature in the range 550.degree.F. to 850.degree. F., and3. a hydrogen partial pressure in the range 300 to 800 psig.New and advantageous results are obtained by integrating the foregoing process with one or more other process steps including:1. hydrodesulfurization of sulfur-containing vacuum residuum,2. solvent deasphalting of vacuum residuum, or3. hydrodesulfurizing a vacuum residuum and delayed coking at least a portion of the product.
Abstract translation: 具有低硫含量的烃混合物通过在轻质加氢脱硫条件下加氢脱硫瓦斯油获得的含硫减压瓦斯油，包括使用：
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公开(公告)号：US3992285A
公开(公告)日：1976-11-16
申请号：US508119
申请日：1974-09-23
Applicant: LeRoi E. Hutchings
Inventor： LeRoi E. Hutchings
Abstract: A process for the conversion of a hydrocarbonaceous black oil, wherein the terminal heating of the black oil before conversion is performed by the admixture of said black oil with a gas comprising steam and having a temperature greater than the hydrocarbon conversion temperature.
Abstract translation: 一种烃黑色油的转化方法，其中转化前的黑色油的末端加热通过将黑油与包含蒸汽并且具有大于烃转化温度的温度混合的气体进行。
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25.发明授权
公开(公告)号：US3976557A
公开(公告)日：1976-08-24
申请号：US527943
申请日：1974-11-29
Applicant: John Shen , Michael C. Chervenak
Inventor： John Shen , Michael C. Chervenak
Abstract: The removal of particulate solids containing iron sulfides from hydrogenated coal liquids by magnetic separation is improved by pretreatment of the liquid with a gas mixture containing hydrogen and hydrogen sulfide. The coal-derived liquid is contacted with the gas mixture containing at least about 2 vol. % hydrogen sulfide, with the remainder of the gas mixture comprising principally hydrogen. Residue time for the liquid-gas contact should be at least about two minutes and temperature should be less than about 650.degree.F. The treated liquid is then passed through a magnetic field having strength of at least about 3000 gauss to achieve substantial removal of sulfur-containing solids from the liquid. The magnetic solids are then removed from the separator unit, e.g., by flushing using a light solvent oil, and the remaining liquid fraction carrying less-magnetic solids is passed on to further processing.
Abstract translation: 通过磁性分离从氢化煤液中除去含硫化铁的颗粒固体，通过用含有氢和硫化氢的气体混合物进行预处理来改进。 煤源液体与含有至少约2体积％的气体混合物接触。 ％硫化氢，其余气体混合物主要包含氢气。 液 - 气接触的残留时间应至少约两分钟，温度应小于约650°F。然后将处理过的液体通过强度至少约为3000高斯的磁场，以实质上除去硫 来自液体的固体。 然后将磁性固体从分离器单元中除去，例如通过使用轻质溶剂油冲洗，并将携带较少磁性固体的剩余液体馏分转移至进一步处理。
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Patent Agency Ranking
公开(公告)号：US4210526A
公开(公告)日：1980-07-01
申请号：US915905
申请日：1978-06-16
Applicant: Rollan Swanson
Inventor： Rollan Swanson
CPC classification number: C10G19/067 , C10G29/10
Abstract: Hydrated alkali metal sulfides used to remove sulfur from fossil fuels to form alkali metal polysulfides which are recycled to alkali metal sulfides and elemental sulfur by thermal or thermal reduced pressure decomposition of the alkali metal polysulfides or by conversion of the hydrolysis products entirely by H.sub.2 S.
Abstract translation: 用于从化石燃料中除去硫的水合碱金属硫化物以形成碱金属多硫化物，其通过碱金属多硫化物的热或热减压分解或通过完全由H 2 S转化水解产物而再循环至碱金属硫化物和元素硫。
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公开(公告)号：US4140618A
公开(公告)日：1979-02-20
申请号：US811334
申请日：1977-06-29
Applicant: Theodore C. Mead , Norman R. Odell
Inventor： Theodore C. Mead , Norman R. Odell
CPC classification number: C10G27/04 , C10G2400/12
Abstract: A transformer oil processing sequence is disclosed. The process comprises contacting a naphthenic based oil with an oxygen-containing gas in the presence of a free radical initiating catalyst under mild oxidation conditions of temperature and pressure, fractionally distilling the resultant product and then hydrogenating the oil.
Abstract translation: 公开了变压器油处理顺序。 该方法包括在温和和压力的温和氧化条件下，在自由基引发催化剂的存在下，使环烷基油与含氧气体接触，分馏出所得产物，然后使油氢化。
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公开(公告)号：US4082653A
公开(公告)日：1978-04-04
申请号：US742415
申请日：1976-11-17
Applicant: Richard Raymond DeGraff
Inventor： Richard Raymond DeGraff
Abstract: Heated hydrocarbon crude oil is passed into a first flash zone wherein it is separated into a first flash vapor and a first flash liquid. First flash vapor is water washed to remove soluble contaminants, and the resulting wash water and the first flash liquid are passed to a desalter. First flash liquid having substantial freedom from water soluble contaminants is passed from the desalter into a second flash zone wherein it is separated into a second flash vapor and a second flash liquid. The second flash liquid is passed into a conventional fractionation zone comprising a crude column and a vacuum column.
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29.发明授权
公开(公告)号：US4080397A
公开(公告)日：1978-03-21
申请号：US703719
申请日：1976-07-09
Applicant: Walter R. Derr , Joseph R. McClernon , Stephen J. McGovern , Fritz A. Smith
Inventor： Walter R. Derr , Joseph R. McClernon , Stephen J. McGovern , Fritz A. Smith
CPC classification number: C10G65/043 , C10G2400/02 , C10G2400/04 , Y10S208/95
Abstract: Upgrading of 350.degree. F plus product of Fischer-Tropsch Synthesis is accomplished by hydrotreating the Fischer-Tropsch Synthesis product and selective cracking the hydrotreated material boiling above about 600.degree. F. A product slate is recovered comprising LPG, gasoline, jet fuel, light and heavy oil fractions.
Abstract translation: 费 - 托合成的350°F加产物的升级通过加氢处理费 - 托合成产物并选择性地裂化沸点高于约600°F的加氢处理材料来实现。回收产品板岩，包括LPG，汽油，喷气燃料，光和 重油馏分。
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30.发明授权Process for treating sulfur-containing hydrocarbon feedstocks to produce high yield coke 失效用于处理含硫烃原料以生产高产率焦炭的方法
公开(公告)号：US4051014A
公开(公告)日：1977-09-27
申请号：US500439
申请日：1974-08-26
Applicant: George P. Masologites
Inventor： George P. Masologites
Abstract: A process for producing coke from sulfur-containing hydrocarbon feedstocks which involves contacting at least a portion of the feedstock with a peroxy oxidant in the presence of a metal-containing catalyst to preferentially oxidize a portion of the hydrocarbon feedstock, subjecting the feedstock to coking conditions to form coke and recovering a coke product. The present process can provide improved yields of coke having substantially reduced sulfur content.
Abstract translation: 一种从含硫烃原料生产焦炭的方法，其包括在含金属催化剂存在下使至少一部分原料与过氧化剂接触，以优先氧化一部分烃原料，使原料经受焦化条件 形成焦炭并回收焦炭产品。 本方法可以提供具有显着降低的硫含量的改善的焦炭产率。
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